Chemistry: Bonding and Antibonding Orbitals
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Questions and Answers

Which type of bond always exist with σ bonds?

  • δ bonds
  • π bonds (correct)
  • ω bonds
  • φ bonds
  • When are π bonds formed?

  • Before σ bonds are formed
  • When atomic orbitals intersect in a sideways positive direction (correct)
  • When atomic orbitals intersect in a parallel direction
  • After δ bonds are formed
  • In molecular orbital formation, what does the stability of the resulting molecule depend on?

  • The overlap of atomic orbitals
  • The number of electrons occupying lower energy orbitals compared to higher energy orbitals (correct)
  • The number of nodal planes
  • The shape of the molecular wavefunction
  • How many nodal planes do π*-orbitals have?

    <p>Two</p> Signup and view all the answers

    Which type of atomic orbitals generate σ2𝑃𝒛 molecular orbitals?

    <p>2𝑃z atomic orbitals</p> Signup and view all the answers

    Which type of orbital takes part in the formation of chemical bond by in-phase combination of atomic orbitals?

    <p>Bonding Orbitals</p> Signup and view all the answers

    In which type of molecular orbitals is the electron density higher and the energy lower?

    <p>Bonding Molecular Orbitals</p> Signup and view all the answers

    What distinguishes the σ and π bonds from each other?

    <p>The head-to-head overlapping of orbitals forms σ bonds, whereas the lateral overlap forms π bonds.</p> Signup and view all the answers

    Which type of combination of atomic orbitals may form a σ bond?

    <p>S-S and S-P orbitals</p> Signup and view all the answers

    Which type of covalent bond is formed by the lateral overlap of orbitals?

    <p>π Bond</p> Signup and view all the answers

    Study Notes

    Bonding Types and Molecular Orbitals

    • π bonds always exist with σ bonds, as they are formed perpendicular to the σ bond.
    • π bonds are formed when parallel p-orbitals overlap sideways.
    • The stability of the resulting molecule in molecular orbital formation depends on the energy of the molecular orbitals.
    • π*-orbitals have one nodal plane.
    • px and pz atomic orbitals generate σ2p molecular orbitals.
    • Atomic orbitals that take part in the formation of chemical bonds by in-phase combination are σ-orbitals.
    • In σ molecular orbitals, the electron density is higher and the energy is lower.
    • σ and π bonds are distinguished by their orientation relative to the bond axis, with σ bonds being parallel and π bonds being perpendicular.
    • The in-phase combination of atomic orbitals may form a σ bond.
    • A π covalent bond is formed by the lateral overlap of orbitals.

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    Description

    Test your knowledge of bonding and antibonding orbitals in chemistry with this quiz. Learn about the differences between the two types of orbitals, their roles in chemical bonding, and their effects on the shape of molecules.

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