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Questions and Answers
What is the atomic number of carbon?
What is the atomic number of carbon?
Which particle has a positive charge?
Which particle has a positive charge?
Which of the following is NOT a characteristic of an element?
Which of the following is NOT a characteristic of an element?
What is the mass number of an atom with 8 protons and 10 neutrons?
What is the mass number of an atom with 8 protons and 10 neutrons?
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Which statement is TRUE regarding isotopes?
Which statement is TRUE regarding isotopes?
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Which statement best describes the relationship between an atom's atomic number and its mass number?
Which statement best describes the relationship between an atom's atomic number and its mass number?
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Based on the atomic weight of carbon (12.01), which carbon isotope is the most abundant?
Based on the atomic weight of carbon (12.01), which carbon isotope is the most abundant?
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What is the primary difference between chemical evolution and biological evolution?
What is the primary difference between chemical evolution and biological evolution?
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Which of these elements makes up the largest percentage of atoms in the human body?
Which of these elements makes up the largest percentage of atoms in the human body?
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What is the key difference between a covalent bond and an ionic bond?
What is the key difference between a covalent bond and an ionic bond?
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Which of the following best describes the relationship between electronegativity and bond polarity?
Which of the following best describes the relationship between electronegativity and bond polarity?
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Which of these properties of water is directly related to its ability to dissolve many substances?
Which of these properties of water is directly related to its ability to dissolve many substances?
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In a covalent bond, why do atoms become more stable by sharing electrons?
In a covalent bond, why do atoms become more stable by sharing electrons?
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What is an example of an atom gaining an electron to form an anion?
What is an example of an atom gaining an electron to form an anion?
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Which of the following molecules has a tetrahedral shape?
Which of the following molecules has a tetrahedral shape?
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Which of the following statements accurately describes electronegativity?
Which of the following statements accurately describes electronegativity?
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What is the difference between a polar covalent bond and a nonpolar covalent bond?
What is the difference between a polar covalent bond and a nonpolar covalent bond?
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Which of the following statements is NOT true regarding the atomic structure of the first 18 elements?
Which of the following statements is NOT true regarding the atomic structure of the first 18 elements?
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What explains water's high specific heat?
What explains water's high specific heat?
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Which of the following substances would likely have a specific heat value closest to that of water?
Which of the following substances would likely have a specific heat value closest to that of water?
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What is the significance of the statement "Chemical reactions are written as equations" in the context of the provided text?
What is the significance of the statement "Chemical reactions are written as equations" in the context of the provided text?
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If a solution has a pH of 9, what does this indicate about the solution?
If a solution has a pH of 9, what does this indicate about the solution?
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What is the role of buffers in maintaining homeostasis in organisms?
What is the role of buffers in maintaining homeostasis in organisms?
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Which of the following correctly describes an exothermic reaction?
Which of the following correctly describes an exothermic reaction?
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Which of the following scenarios would lead to the formation of hydronium ions (H3O+)?
Which of the following scenarios would lead to the formation of hydronium ions (H3O+)?
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Which of the following statements about chemical energy is NOT true?
Which of the following statements about chemical energy is NOT true?
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What is the relationship between temperature and molecular motion?
What is the relationship between temperature and molecular motion?
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Which of the following is NOT a consequence of the second law of thermodynamics?
Which of the following is NOT a consequence of the second law of thermodynamics?
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What is the key requirement for a chemical reaction to be spontaneous?
What is the key requirement for a chemical reaction to be spontaneous?
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Which of the following statements about the first law of thermodynamics is true?
Which of the following statements about the first law of thermodynamics is true?
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What was the main objective of Stanley Miller's spark-discharge experiment?
What was the main objective of Stanley Miller's spark-discharge experiment?
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What is the role of entropy in chemical reactions?
What is the role of entropy in chemical reactions?
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Which of the following factors contributes to the spontaneous nature of a chemical reaction?
Which of the following factors contributes to the spontaneous nature of a chemical reaction?
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Which of the following statements correctly describes the interactions between water molecules?
Which of the following statements correctly describes the interactions between water molecules?
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What is the primary reason why hydrophobic molecules do not dissolve in water?
What is the primary reason why hydrophobic molecules do not dissolve in water?
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Which property of water allows it to move from the roots of plants to their leaves against gravity?
Which property of water allows it to move from the roots of plants to their leaves against gravity?
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Which of the following is NOT a consequence of the bent geometry of water molecules?
Which of the following is NOT a consequence of the bent geometry of water molecules?
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Why is ice less dense than liquid water?
Why is ice less dense than liquid water?
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Which of the following statements accurately describes the relationship between cohesion and adhesion in water?
Which of the following statements accurately describes the relationship between cohesion and adhesion in water?
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Surface tension is a phenomenon that results from:
Surface tension is a phenomenon that results from:
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Which of the following statements accurately describes the role of carbon in the formation of organic molecules?
Which of the following statements accurately describes the role of carbon in the formation of organic molecules?
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What is the significance of functional groups in organic molecules?
What is the significance of functional groups in organic molecules?
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How does the process of polymerization contribute to the formation of macromolecules?
How does the process of polymerization contribute to the formation of macromolecules?
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Which of the following statements accurately describes the relationship between hydrolysis and condensation reactions?
Which of the following statements accurately describes the relationship between hydrolysis and condensation reactions?
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Why does equilibrium favor free monomers over polymers in biological systems?
Why does equilibrium favor free monomers over polymers in biological systems?
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What was the primary conclusion of Miller's experiment?
What was the primary conclusion of Miller's experiment?
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How did Miller's experiment simulate conditions on early Earth?
How did Miller's experiment simulate conditions on early Earth?
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What is the significance of Miller’s experiment in the context of chemical evolution?
What is the significance of Miller’s experiment in the context of chemical evolution?
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Flashcards
Chemical evolution
Chemical evolution
Leading explanation for the origin of life involving complex carbon structures.
Five characteristics of life
Five characteristics of life
Essential traits that living organisms exhibit, including metabolism and reproduction.
Atoms
Atoms
Basic units of matter, consisting of protons, neutrons, and electrons.
Mass number
Mass number
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Isotopes
Isotopes
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Atomic weight
Atomic weight
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Dalton (Da)
Dalton (Da)
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Atomic number
Atomic number
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Water's Polarity
Water's Polarity
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Hydrogen Bonds
Hydrogen Bonds
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Hydrophilic Molecules
Hydrophilic Molecules
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Hydrophobic Molecules
Hydrophobic Molecules
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Cohesion
Cohesion
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Adhesion
Adhesion
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Surface Tension
Surface Tension
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Density of Water
Density of Water
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Energy
Energy
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Potential Energy
Potential Energy
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Chemical Energy
Chemical Energy
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Kinetic Energy
Kinetic Energy
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Temperature
Temperature
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First Law of Thermodynamics
First Law of Thermodynamics
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Second Law of Thermodynamics
Second Law of Thermodynamics
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Spontaneous Reaction
Spontaneous Reaction
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Miller’s apparatus
Miller’s apparatus
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Organic compounds
Organic compounds
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Covalent bonds
Covalent bonds
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Macromolecules
Macromolecules
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Polymerization
Polymerization
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Condensation reaction
Condensation reaction
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Hydrolysis
Hydrolysis
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Entropy
Entropy
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Radioactive isotopes
Radioactive isotopes
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Mole
Mole
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Molecular weight
Molecular weight
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Electron shells
Electron shells
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Valence electrons
Valence electrons
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Covalent bonding
Covalent bonding
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Polar covalent bond
Polar covalent bond
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Electronegativity
Electronegativity
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Ionic bonding
Ionic bonding
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Molecule shape
Molecule shape
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Specific Heat
Specific Heat
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Hydrogen Bonding
Hydrogen Bonding
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Chemical Equilibrium
Chemical Equilibrium
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Molarity (M)
Molarity (M)
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Acids
Acids
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Bases
Bases
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pH Scale
pH Scale
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Buffers
Buffers
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Endothermic Reactions
Endothermic Reactions
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Study Notes
Chapter 2: Water and Carbon: The Chemical Basis of Life
- Life on Earth is primarily based on chemical evolution
- Chemical evolution is the leading explanation for the origin of life
- Complex carbon-containing substances formed
- Replicating molecules emerged, leading to biological evolution
- Natural selection took over, eventually fulfilling all five characteristics of life
Link Between Chemistry and Biology
- Chemical evolution is the process of increasingly complex carbon-containing substances forming
- This resulted in molecules that could replicate themselves
- The switch marked the transition from chemical to biological evolution
- The original molecules multiplied and descendants developed metabolic functions and membranes
- This fulfilled the five main characteristics of life
Atoms, Ions, and Molecules: The Building Blocks of Chemical Evolution
- 96% of all matter in organisms is composed of four elements: hydrogen, carbon, nitrogen, and oxygen
- Simple substances evolved into complex structures in living cells
- Understanding the physical structures of the atoms (hydrogen, carbon, nitrogen, oxygen) is essential
- The structures of simple molecules (water, carbon dioxide) played fundamental roles in chemical evolution
Basic Atomic Structure
- Atoms have a nucleus consisting of protons and neutrons
- Protons have a positive charge (+1)
- Neutrons have no charge
- Orbiting electrons carry a negative charge (-1)
- Atoms exist in a state of charge balance and are electrically neutral when the number of protons equals the number of electrons
Understanding Elements
- Elements consist of only one type of atom.
- Atomic number is the characteristic number of protons in an atom's nucleus. It is written as a subscript left of the element's symbol.
- Mass number is the sum of protons and neutrons in an atom. It is also the atom's mass number.
Atoms are Tiny, so How Do We Weigh Them?
- Dalton (Da) is the unit of measurement for the mass of a proton and a neutron.
- The mass of an electron is negligible
- An atom's mass is essentially equal to its mass number
- Isotopes of an element have different numbers of neutrons but the same number of protons
- The atomic weight of an element is the average mass of the naturally occurring isotopes, weighted by their relative abundance
Weight of Molecules in Grams
- A mole is 6.022 x 1023 atoms or molecules.
- Mass of one mole of an atom (or molecule) equals its atomic (or molecular) weight in grams.
- Molecular weight is the sum of the atomic weights of all atoms in a molecule
The Atomic Structure of the First 18 Elements
- Carbon, hydrogen, oxygen, nitrogen, phosphorus, and sulfur make up over 99% of the atoms in any organism.
- The elements highlighted in blue in the chart are the most abundant elements found in organisms.
Atomic Structure and Electron Shells
- Electrons orbit the nucleus in specific regions called orbitals.
- Orbitals combine to form electron shells
- Electron shells are numbered (e.g., 1, 2, 3...), with lower numbers closer to the nucleus
- Each electron shell holds a specific number of electrons
- Electrons fill the inner shells first, then the outer shells.
- Valence electrons are the electrons in the outermost shell
Covalent Bonding Hold Molecules Together by Sharing Electrons
- Sharing electrons in a covalent bond allows atoms to become more stable by completing valence shells
- If two hydrogen atoms share electrons, for instance, their outer shells are filled and thus become stable.
Electrons in Covalent Bonds Are Not Always Shared Equally (Polar bonds)
- Covalent bonds can be nonpolar (electrons shared equally) or polar (electrons shared unequally).
- Polar bonds arise from differences in electronegativity between atoms in a covalent bond;
- Water is an example of a molecule with polar covalent bonds, creating partial charges on the atoms
Nonpolar vs Polar Covalent Bonds
- Nonpolar covalent bonds involve equal electron sharing, producing no charge.
- Polar covalent bonds involve unequal electron sharing, producing partial positive and negative charges on the atoms.
- The difference in electron negativity determines the polarity or non polarity of the bond
Electronegativity: Strength with which atoms pull electrons toward themselves
- Atom's electronegativity is determined by the number of protons and the distance of the valence shell from the nucleus.
- Electronegativity increases as you move up and to the right on the periodic table.
Polar Bonds Produce Partial Charges on Atoms
- Polar covalent bonds occur when atoms with differing electronegativities share electrons unequally.
- In a water molecule (H₂O), oxygen is more electronegative than hydrogen, resulting in a partial negative charge on oxygen and partial positive charges on hydrogen.
- These partial charges are symbolized using delta symbols (δ).
Ionic Bonding
- Ionic bonds form when one atom transfers an electron to another, resulting in a full valence shell for both atoms.
- The electron's transfer produces ions.
- Cations are positively charged ions formed when an atom loses an electron
- Anions are negatively charged ions formed when an atom gains an electron
The Electron-Sharing Continuum
- Polar covalent bonds involve unequal sharing of electrons.
- Ionic bonds involve complete electron transfer
- Covalent bonds with equal sharing of electrons are nonpolar.
- Examples were listed including Hydrogen, Methane, Ammonia, Water and Sodium Chloride
Unpaired Electrons in the Valence Shell Can Participate in Double and Triple Covalent Bonds
- The number of unpaired electrons in an atom's valence shell determines the number of bonds that atom can form.
Molecule's Shape Often Dictates its Behavior
- The shape of molecules is determined by the geometry of their bonds.
- Repulsive forces between electrons in molecules have been determined
- The shapes of methane and water molecules have been explained.
Molecules Can Be Represented Several Ways
- Molecular formulas, structural formulas, ball-and-stick models, and space-filling models represent molecules in various ways.
Properties of Water and the Early Oceans
- Water is an excellent solvent due to its polar nature, allowing substances to dissolve and interact readily
- Solute dissolves into solvent to create a solution
- Certain substances react more strongly when they're dissolved in water or other solvents.
- The properties of water correlate directly with its structure.
A Water Can Interact with other Water Molecules
- Water is a polar molecule with partial positive charges on hydrogen and a partial negative charge on oxygen.
- Partial charges on hydrogen attract the partial negative charges on oxygen in another water molecule
- These interactions are called hydrogen bonds.
Water Is an Efficient Solvent
- Hydrogen bonds form between water molecules and polar solutes
- Hydrophilic molecules interact with water, allowing them to dissolve
Not everything dissolves in water
- Hydrophobic molecules do not interact with water, and therefore do not dissolve.
- Hydrophobic substances interact with each other due to hydrophobic interactions which improve the stability of clustered hydrophobic molecules.
- This is an example of why clustering often occurs with non-polar molecules
Cohesion and Adhesion
- Cohesion describes attraction between like molecules.
- Adhesion describes attraction between unlike molecules.
- Water molecules demonstrate strong cohesive forces due to hydrogen bonding.
- In plant systems, water molecules adhere to surfaces, like those found in plant roots and stems.
Surface Tension
- Surface tension is a phenomenon due to the cohesive forces in the surface layer of a liquid
- Cohesive forces at the surface of water molecules create resistance to increasing surface area
- Water molecules demonstrates elastic properties at its surface
Water Is Denser as a Liquid than as a Solid
- Most substances become denser as they solidify
- Water expands when it freezes
- Frozen water forms an open crystal structure, reducing density
- This is why ice floats on water
Water Has a High Capacity for Absorbing Energy (Specific Heat)
- Specific heat is the amount of energy needed to raise the temperature of 1 gram of a substance by 1°C
- Water has a remarkably high specific heat due to extensive hydrogen bonding
- Many hydrogen bonds must be broken to increase water's temperature
The Role of Water in Acid-Base Chemical Reactions
- Chemical reactions involve the breaking and formation of chemical bonds.
- Water molecules dissociate into hydrogen ions (H+) and hydroxide ions (OH-)
- Chemical equilibrium describes a reaction where the forward and reverse reaction rates are equal
Measuring the Concentration of Protons
- A mole (mol) is a way to measure large quantities of molecules (6.022 x 1023)
- Molecular weight is the sum of atomic weights of atoms in a molecule
- Molarity is the number of moles of solute in one liter of solution (M).
The Role of Water in Acid-Base Chemical Reactions
- Acids are substance that release protons (H+)
- Bases are substances that accept protons (H+)
- Water acts as both an acid and a base in chemical reactions
The pH of a Solution Reveals Whether It Is Acidic or Basic
- pH measures the concentration of hydrogen ions (H+) on a logarithmic scale
- Acids have lower pH (less than 7)
- Bases have higher pH (greater than 7)
- pH of water is 7 and a neutral pH
- Buffers maintain a relatively constant pH in living organisms
Chemical Reactions
- Chemical reactions involve breaking and forming chemical bonds.
- Chemical reactions can be balanced to maintain equal numbers of atoms on both sides of the reaction
- Exothermic reactions releases heat energy
- Endothermic reactions require energy to proceed
What Makes a Chemical Reaction Spontaneous?
- Spontaneous reactions proceed without continuous external energy input
- Products of spontaneous reactions often have lower potential energy and increased entropy than reactants.
- Many factors influence if a reaction will proceed spontaneously
Stanley Miller's Spark-Discharge Experiment in 1953
- Simulating early Earth conditions, the experiment demonstrated that simple molecules could produce complex molecules (such as amino acids).
- Heat and electrical charges in the experiment produced complex organic compounds
- The experiment suggested early Earth conditions could create molecules essential for life.
Life is Carbon-Based
- Carbon is a central element in life's molecules.
- Carbon atoms can form long chains or rings, forming the structural foundation for complex organic compounds like octane and glucose.
Functional Groups Define the Chemical Behavior of Organic Molecules
- Functional groups are specific groups of atoms attached to a carbon skeleton that give a molecule its unique properties.
- Examples of functional groups include hydroxyl, carboxyl, carbonyl, amino, sulfhydryl, and phosphate groups.
- Each type of functional group has distinctive chemical characteristics.
Small Organic Molecules Can Assemble into Large Molecules
- This is necessary to build complex molecules of life.
- Monomers combine to form polymers via condensation reactions, producing water
- The reverse reaction (hydrolysis) breaks apart polymers
End of Chapter Questions and Review
- Questions 1, 2, 3, 5, 8, 12, 16 are provided for further review and practice
- A review chapter summarizes the concepts in the main chapter.
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Description
Test your understanding of fundamental chemistry concepts such as atomic structure, bonding, and the characteristics of elements. This quiz covers topics related to atomic numbers, isotopes, chemical and biological evolution, and more. Perfect for beginners looking to solidify their knowledge in chemistry!