Chemistry 2210 Exam 1 Summer 2023
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Chemistry 2210 Exam 1 Summer 2023

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Questions and Answers

What is the formal charge of nitrogen in a given molecular structure if it has 5 valence electrons and is bonded to three hydrogen atoms?

  • +2
  • 0 (correct)
  • -1
  • +1
  • Identify which of the following is not a plausible resonance structure for a given compound.

  • Structure C
  • Structure A (correct)
  • Structure B
  • Structure D
  • Determine the hybridization of an atom with four electron groups surrounding it.

  • sp
  • sp2
  • sp2d2
  • sp3 (correct)
  • Which option best represents the correct Lewis structure for a complex organic compound with both single and double bonds?

    <p>Structure B</p> Signup and view all the answers

    Is the indicated functional group in a molecular structure classified as primary, secondary, or tertiary?

    <p>secondary</p> Signup and view all the answers

    What type of functional group is found at a specific location in a molecular structure?

    <p>ester</p> Signup and view all the answers

    Which of the underlined atoms does not abide by the octet rule?

    <p>Boron in B(CH3)3</p> Signup and view all the answers

    Identify which of the following compounds contains an ionic bond.

    <p>NaCl</p> Signup and view all the answers

    Which of the following compounds contains the strongest acid?

    <p>CF3CO2H (pKa = 0)</p> Signup and view all the answers

    Which of the following is NOT a valid acid-conjugate base pair?

    <p>CH3CH2OH, CH3CH2O–</p> Signup and view all the answers

    What is the hybridization of the nitrogen atom in N+?

    <p>sp2</p> Signup and view all the answers

    How many pi bonds are present in the compound NO2?

    <p>1</p> Signup and view all the answers

    Which of the following compounds is classified as a ketone?

    <p>O=C(CH3)CH2CH3</p> Signup and view all the answers

    Which statement about Lewis acids and bases is NOT true?

    <p>All Lewis acids contain an acid hydrogen.</p> Signup and view all the answers

    Which compound contains the functional group that is NOT present in cortisone?

    <p>carboxylic acid</p> Signup and view all the answers

    Which of the following orbitals overlap forms the C4-C5 carbon-carbon bond?

    <p>sp2–sp2</p> Signup and view all the answers

    Study Notes

    Exam Overview

    • Chemistry 2210 Exam 1, Summer 2023 consists of multiple-choice questions.
    • Total of 20 questions, each worth 5 points, equating to 100 points.
    • Students must sign a pledge confirming integrity in completing the exam.

    Exam Instructions

    • Present Panther ID to submit the exam.
    • Failure to sign the pledge results in an automatic zero for the exam grade.

    Key Topics Covered

    • Formal Charge: Understand how to calculate formal charges in molecular structures.
    • Resonance Structures: Identify plausible resonance structures for compounds.
    • Hybridization: Determine hybridization states (sp3, sp2, sp) of indicated atoms within structures.
    • Lewis Structures: Correctly draw and recognize the best Lewis structure for a compound.
    • Functional Groups: Classify functional groups as primary, secondary, or tertiary; answer questions about specific group types (aldehyde, ketone, ester, etc.).
    • Octet Rule: Recognize atoms that do not obey the octet rule in various compounds.
    • Ionic Bonds: Identify compounds containing ionic bonds by evaluating electronegativity differences.
    • Pi Bonds: Count the number of pi bonds present in molecular structures.
    • Orbital Overlap: Know which orbitals are involved in specific carbon-carbon bond formations.
    • Acid-Base Chemistry: Understand concepts around acid-conjugate base pairs and identify true and false statements regarding Bronsted-Lowry and Lewis definitions.
    • Acidity Strength: Compare the strength of organic compounds as acids using pKa values.
    • Conjugate Bases: Determine the most reactive conjugate bases from given organic compounds.
    • Functional Groups: Identify specific functional groups present or absent in chemical structures (e.g., ketones, alcohols).

    Example Questions

    • Formal charge of nitrogen can be derived from charge calculation.
    • Identifying the strongest acid and its conjugate base can require comparing pKa values.
    • Recognizing ketones and their structures is crucial.
    • Clarifying the presence of functional groups in specific compounds (like cortisone).
    • Understanding tertiary amines and their structural characters.

    Important Definitions

    • Lewis Structure: Diagram that shows the bonding between atoms in a molecule, as well as the lone pairs of electrons.
    • Hybridization: Concept in chemistry that describes the formation of new hybrid orbitals used for bonding.
    • Conjugate Base: The species that remains after an acid has donated a proton.

    Tips for Exam Success

    • Familiarize yourself with chemical structures and functional groups.
    • Practice calculating formal charges and hybridizations regularly.
    • Review acid-base theory and pKa comparisons to enhance understanding.
    • Understand resonance and its significance in molecular stability.
    • Cross-reference multiple-choice questions against your knowledge for accuracy before selecting answers.

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    Description

    Prepare for your Chemistry 2210 Exam 1 with this assessment designed to evaluate your understanding of key concepts covered during the summer semester. Ensure you are familiar with the course material and adhere to academic integrity while taking the test.

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