Chemical Engineering Safety and Processes Quiz
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Questions and Answers

What effect do smaller granulator screens have on the amperage?

  • They decrease the amps significantly.
  • They cause high amps to occur. (correct)
  • They stabilize the amperage output.
  • They have no effect on amps.
  • Which type of pump is used to transport aqueous phase solution to the reactors?

  • Diaphragm pump
  • Gear pump
  • Centrifugal pump (correct)
  • Peristaltic pump
  • What additive is required for product 934 SH?

  • TCE
  • BVE (correct)
  • SAF
  • DLP
  • What happens to the temperature when caustic is charged into a dissolution tank?

    <p>The temperature increases. (A)</p> Signup and view all the answers

    What is the purpose of the Kason in the system?

    <p>To transport powder through piping. (A)</p> Signup and view all the answers

    In what form is acrylamide most dangerous?

    <p>Crystallization (solid) form (B)</p> Signup and view all the answers

    Is it acceptable to use homemade tools to clear a clog in equipment?

    <p>No, it is not acceptable (C)</p> Signup and view all the answers

    What type of environmental impact does the finished product have?

    <p>The finished product can damage forest health (A), The finished product is harmful to marine life (B)</p> Signup and view all the answers

    Which statement about MEHQ is accurate?

    <p>MEHQ is considered a known carcinogen (B)</p> Signup and view all the answers

    Which inhibitors are used in the production of acrylamide?

    <p>Acrylic acid and caustic (A)</p> Signup and view all the answers

    When is the thermal catalyst typically added to the reactor?

    <p>After the addition of TBP (C)</p> Signup and view all the answers

    What is the maximum amount of catalyst approved to be in the plant at any given time?

    <p>48 hours' worth (D)</p> Signup and view all the answers

    What by-product is generated in the process of making post hydro?

    <p>Carbon dioxide (C)</p> Signup and view all the answers

    What is a hazard associated with the use of nitrogen?

    <p>It is a flammable gas (C)</p> Signup and view all the answers

    What does free monomer refer to?

    <p>Unreacted or un-polymerized monomers used in gels (A)</p> Signup and view all the answers

    What does BVE create more of in the dissolution tank?

    <p>Foam (A)</p> Signup and view all the answers

    What type of charge do anionic products have?

    <p>Negative (B)</p> Signup and view all the answers

    When are dissolution tank samples discarded?

    <p>After confirming a corresponding reactor sample to QC silo blend (D)</p> Signup and view all the answers

    When should you take a gel sample?

    <p>When any kind of QC result fails and the product becomes non-conformed (B)</p> Signup and view all the answers

    Where is the dryer pressure transmitter located?

    <p>In the top side of the dryer shell (C)</p> Signup and view all the answers

    What is the main function of the dryer cyclones?

    <p>To allow the dryer air to vent out through the ducts and stack, while returning the product to the dryers. (A)</p> Signup and view all the answers

    What happens when the amount of redox catalyst is increased?

    <p>It will result in a faster kinetic reaction. (B)</p> Signup and view all the answers

    If product is observed emitting from the stack, which situation could contribute to this problem?

    <p>All of the above. (D)</p> Signup and view all the answers

    What is an important reason for monitoring dryer moistures?

    <p>To assure that all rotors are compatible. (C)</p> Signup and view all the answers

    What components cause the kason to vibrate?

    <p>Air flow from the dryer cyclones and the center spiral gasket. (B)</p> Signup and view all the answers

    What personal protective equipment is needed to handle caustic soda?

    <p>All of the above (D)</p> Signup and view all the answers

    What does a reactor pressure test primarily prevent?

    <p>Leaks (A)</p> Signup and view all the answers

    What could occur if too little hypo is added to any reaction?

    <p>Slower reaction curve (A)</p> Signup and view all the answers

    What are the steps of reaction curve polymerization?

    <p>Initiation, propagation, and termination (D)</p> Signup and view all the answers

    Why do we set the dissolution tanks to -2 degrees C when polymerizing at 0 degrees C?

    <p>To prevent auto-polymerization and ensure product consistency (A)</p> Signup and view all the answers

    What is the purpose of adding acetic acid, caustic, and 50% acrylic acid during production?

    <p>To adjust the pH of the solution (C)</p> Signup and view all the answers

    What is the consequence of over drying products in the production process?

    <p>It can lead to filter ratio failure (D)</p> Signup and view all the answers

    What does hydrolysis refer to in the context of chemical processes?

    <p>Chemical breakdown due to reaction with water (A)</p> Signup and view all the answers

    During which step is reverse osmosis water added to the catalyst pitchers?

    <p>Both during and after the drawdown process (D)</p> Signup and view all the answers

    What is the primary reason for oiling reactors in the production process?

    <p>To assist with draining out the gel (A)</p> Signup and view all the answers

    What could potentially cause the finished product to test high?

    <p>Acrylamide leaking by an actuator valve (D)</p> Signup and view all the answers

    Which action should be taken first if oversize particles are found coming out of the dryer?

    <p>Check the granulator screen (A)</p> Signup and view all the answers

    What could be a consequence of not having enough oil flow in the granulator?

    <p>Granulator high amps (B)</p> Signup and view all the answers

    What should be done to ensure proper draw-down temperature in reactors and dissolution tanks?

    <p>Close manual valves (B)</p> Signup and view all the answers

    What does flocculation refer to in this context?

    <p>Separation of a solution to remove sediment (B)</p> Signup and view all the answers

    What type of reactors are used at SNT Flopa?

    <p>Tube reactors (B)</p> Signup and view all the answers

    What could cause high moisture levels coming out of dryer 1?

    <p>Operator could be using the wrong drying conditions (D)</p> Signup and view all the answers

    What does a brownish gel color typically signify?

    <p>Insufficient catalyst in the reaction (B)</p> Signup and view all the answers

    What might prevent a burner flame from lighting?

    <p>Photo eye needs to be replaced (C)</p> Signup and view all the answers

    Why is it important not to mix catalyst too long?

    <p>Mixing too long can cause chemicals to lose potency (D)</p> Signup and view all the answers

    What problem could occur if the pressure is too low in the dryer?

    <p>Too much moisture in the product (C), Obstruction in the product exit (D)</p> Signup and view all the answers

    What could be a reason for low readings on the dryer pressure transmitter?

    <p>The pressure transmitter may be malfunctioning (A)</p> Signup and view all the answers

    What does the abbreviation VHM represent?

    <p>Very high molecular weight (C)</p> Signup and view all the answers

    Which inhibitors are commonly used in the production of acrylic acid?

    <p>MEHQ and oxygen (D)</p> Signup and view all the answers

    Why is TBHP stored in the flammable cabinet of the process lab?

    <p>It can ignite easily when in contact with certain substances (B)</p> Signup and view all the answers

    Flashcards

    Granulator Screens and Amps

    Using smaller screens in a granulator can lead to higher electrical current (amps) due to increased resistance from finer material.

    Aqueous Phase Transport

    Centrifugal pumps are commonly used to move liquids, like aqueous solutions, to reactors. The impeller spins, creating pressure to move the fluid.

    Product 934 SH and Additive

    Product 934 SH requires the addition of BVE (an ingredient or additive) during its manufacturing process.

    Caustic and Temperature

    Caustic materials, when added to a dissolution tank, can cause a rise in temperature due to an exothermic reaction.

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    Aqueous Solution Containment

    Aqueous solutions should be kept within designated areas like dikes as they pose potential hazards and require proper disposal methods.

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    What is free monomer?

    Unreacted monomers, molecules used to create polyacrylamide gel, that remain in the final product.

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    When should thermal catalyst be added to the reactor?

    The act of adding a catalyst to a reaction, typically at a specific point during the process, to accelerate or initiate the reaction.

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    What is the U. test?

    The liquid that drains out from a sample of polyacrylamide during a specific test, often used to measure the quality or consistency of the product.

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    What piece of equipment measures the amount of product transferred to the reactor?

    A device used to measure the volume of product that is transferred to a reactor, often used to control and accurately monitor the reaction process.

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    What by-product comes from making post hydro?

    An undesired substance or compound that is formed during a chemical reaction, often as a byproduct of the main product.

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    Acrylamide Danger

    Acrylamide is most dangerous in its solid form, not in its liquid form.

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    Homemade Tools

    Using homemade tools to clear equipment clogs is unsafe and can cause further damage or unexpected reactions.

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    MEHQ carcinogen

    MEHQ is used in the polymerization process and has been proven to be a known carcinogen.

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    Catalyst Storage

    Only 48 hours worth of catalyst is allowed to be stored in the plant at any given time.

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    Nitrogen Hazard

    Nitrogen, though not flammable, can suffocate in enclosed spaces.

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    What is BVE?

    A substance added to the dissolution tank to reduce the amount of foam produced during processing.

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    What type of charge do anionic products have?

    Anionic products possess a negative charge due to the presence of negatively charged ions or molecules.

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    When are dissolution tank samples discarded?

    Dissolution tank samples are discarded once a corresponding reactor sample from the QC silo blend is confirmed to ensure the product quality is consistent across all stages.

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    When should you take a gel sample?

    A gel sample should be taken when QC results indicate that the product might not meet standards, leading to a potential nonconformity.

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    Where is the dryer pressure transmitter located?

    The pressure transmitter in the dryer is located near the exit screw, where the dried product is discharged from the dryer.

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    Hydrolysis

    The chemical breakdown of a compound due to reaction with water.

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    Caustic and Charge in Products

    Caustic materials contribute to the charge of the product.

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    Over-Drying and Filter Ratio

    Over-drying products can hinder the flow of the product through a filter, causing it to fail.

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    Production Sheet and Catalyst

    The production sheet provides instructions for the amount of catalyst needed for each batch.

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    Reverse Osmosis Water in Catalysts

    Reverse osmosis water is used to dilute the catalyst in the pitchers, ensuring consistency.

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    What is the purpose of dryer cyclones?

    The cyclones in a dryer separate product from the dryer air, allowing the air to vent out while the product returns to the dryer.

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    How does increasing redox catalyst affect a reaction?

    Adding more redox catalyst to a reaction speeds up the chemical process, making it happen faster.

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    What could cause product to escape from the dryer stack?

    Product escaping from the dryer stack indicates a problem, such as a blocked cyclone, clogged ducts, or excessive pressure during loading or unloading.

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    Why are dryer moistures important?

    Moisture levels in a dryer are important to maintain consistent product quality and prevent off-specification material. They also help control the time the product spends inside the dryer.

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    What makes a Kason vibrate?

    The vibrations in a Kason come from air flow through the dryer cyclones and a special spiral gasket in the center.

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    What are the dangers of caustic soda?

    Caustic soda, also known as sodium hydroxide, is a corrosive and highly reactive chemical. It can cause severe chemical burns and damage to skin, eyes, and respiratory systems.

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    What happens if you over sparge?

    Over-sparging, a technique used in polymerization, refers to adding an excessive amount of gas to a reaction mixture. This can lead to poor catalyst mixing, erratic curves, and ultimately, an off-spec product.

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    What are the three steps of the polymerization process?

    Initiation, propagation, and termination are the basic steps involved in polymerization, a chemical reaction that forms large chains of molecules. Initiation starts the chain reaction, propagation adds more monomers to the chain, and termination stops the chain growth.

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    Why is acetic acid used in post hydro?

    Acetic acid, a mild organic acid, is used to adjust pH on post hydro products because it does not negatively affect their anionicity. Anionicity measures the ability of a substance to attract anions, and maintaining its stability is critical for product performance.

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    What does the reactor pressure test prevent?

    The reactor pressure test is crucial in preventing leaks in the reactor. Leaks can lead to safety hazards, product contamination, and loss of pressure, which drastically impacts the polymerization process.

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    Catalyst Bag Disposal

    Empty catalyst bags should be disposed of properly, not simply discarded.

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    Dissolution Tank Samples

    Dissolution tank samples are collected for quality control and process monitoring, not just during upsets or issues.

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    Valve Importance in Temperature Control

    Closing manual valves on reactors and dissolution tanks helps ensure that the correct draw-down temperature is achieved and maintained.

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    Acrylamide Leak Impact

    A leak of acrylamide from an actuator valve could result in higher than expected acrylamide levels in the finished product.

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    Oversize Particles: Granulator or Dryer?

    If oversize particles are coming out of the dryer, the problem is more likely in the granulator, not the dryer screen.

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    Tube reactor

    A reactor designed for continuous-flow processes where substances pass through a tube, ideal for consistent and controlled reactions.

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    What type of reactors are used to make polyacrylamide gel?

    A reactor used in the production of polyacrylamide gel. It involves mixing monomers and additives, controlling conditions like temperature and pH, and activating polymerization processes.

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    Why would high moisture be coming from dryer 1?

    This could occur due to faulty dryer settings, leading to insufficient drying and a higher moisture content in the product.

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    What can cause a brownish gel color?

    A brownish gel color can indicate a glycol leak from the exchanger, potentially contaminating the product.

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    Why should catalyst not be mixed too long?

    Prolonged mixing of catalyst can reduce its effectiveness, impacting the polymerization process. This can result in lower product quality.

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    Low Dryer Pressure

    Low pressure in the dryer can lead to problems with the product exiting the dryer properly, potentially resulting in moisture issues.

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    Low Dryer Pressure Reading

    If the pressure transmitter in the dryer reads low, it could be due to a clog in the transmitter itself, a slower production rate, or a clogged granulator fan.

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    What does VHM signify?

    VHM stands for Very High Molecular Weight, indicating a polymer with very large molecules.

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    Acrylic Acid Inhibitors

    Acrylic acid is stabilized with inhibitors such as MEHQ (Monomethyl Ether Hydroquinone) and oxygen to prevent polymerization during storage.

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    Why a Batch Won't Start

    A batch may not start due to several factors, including missing thermo-catalyst, excessive foam in the dissolution tank, or an incorrect pH level.

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    Study Notes

    Safety and Procedures

    • Smaller granulator screens can cause high amps to occur. (True/False)
    • Centrifugal is the type of pump we use to transport aqueous phase solution to the reactors. (True/False)
    • Product 934 SH requires the additive BVE. (True/False)
    • Caustic causes temperature to increase when charging a dissolution tank. (True/False)
    • Aqueous solution should never be allowed outside of the dike so it can be contained and disposed of properly. (True/False)
    • The granulator hopper measure weight by the use of a flow meter. (True/False)
    • Hypo is used as a chain-transfer agent but has a reducer properties. (True/False)
    • The purpose of the Kason is to help transport powder through piping. (True/False)
    • Diffusion is the type of drying done in dryer 1. (True/False)
    • Evaporative is the type of drying done in dryer 2. (True/False)
    • Only powders shift supervisors are authorized to work in solenoid control panels. (True/False)

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    Test your knowledge on essential chemical engineering processes, safety protocols, and equipment used in production. This quiz covers topics such as pump types, additive requirements, and environmental impacts relating to chemical manufacturing. Assess your understanding of the various hazards and operational considerations in the field.

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