Chemical Basis of Life
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Questions and Answers

What is the leading explanation for the origin of life on Earth?

Chemical evolution

What are the four types of atoms that make up 96% of the matter in organisms?

Hydrogen, carbon, nitrogen, and oxygen

What are the physical structures of hydrogen, carbon, nitrogen, and oxygen atoms?

They are all composed of a nucleus containing protons and neutrons, surrounded by orbiting electrons.

What are the structures of simple molecules like water, carbon dioxide, etc., that served as building blocks of chemical evolution?

<p>They are composed of two or more atoms held together by covalent bonds, where electrons are shared between atoms.</p> Signup and view all the answers

What is the basic atomic structure?

<p>A nucleus made up of protons and neutrons surrounded by orbiting electrons.</p> Signup and view all the answers

What is an element?

<p>It consists entirely of a single type of atom and is represented by a unique symbol on the periodic table.</p> Signup and view all the answers

What is the atomic number?

<p>It is the characteristic number of protons in the nucleus of an atom.</p> Signup and view all the answers

What is the mass number?

<p>It is the sum of the number of protons and neutrons in an atom.</p> Signup and view all the answers

How do we weigh atoms, which are incredibly tiny?

<p>Atoms are weighed in daltons (Da), where each proton and neutron has a mass of one dalton.</p> Signup and view all the answers

The number of protons in an element can vary.

<p>False (B)</p> Signup and view all the answers

What is an isotope?

<p>It is an atom of the same element that has a different number of neutrons, resulting in a different atomic mass.</p> Signup and view all the answers

How is the atomic weight of an element determined?

<p>It is the average of all masses of naturally occurring isotopes of that element, taking into account their relative abundance.</p> Signup and view all the answers

What is the atomic number of carbon, and what does it tell us?

<p>The atomic number of carbon is 6. This indicates that carbon atoms always have 6 protons, making them a distinct element.</p> Signup and view all the answers

What are radioactive isotopes?

<p>They are unstable isotopes that decay over time, emiting radiation such as alpha particles, beta particles, or gamma rays.</p> Signup and view all the answers

What does a 'mole' refer to?

<p>It refers to a specific number of atoms, molecules, or other particles, which is equal to 6.022 x 10^23.</p> Signup and view all the answers

The mass of one mole of an atom is the same as its atomic weight expressed in grams.

<p>True (A)</p> Signup and view all the answers

What is the molecular weight of a molecule?

<p>It is the mass of one mole of that molecule.</p> Signup and view all the answers

How are electrons arranged around the nucleus?

<p>They are arranged in specific regions called orbitals, which are grouped into levels called electron shells.</p> Signup and view all the answers

What is the valence shell?

<p>It is the outermost electron shell of an atom, and the electrons in this shell are called valence electrons.</p> Signup and view all the answers

Why do atoms become more stable by making covalent bonds?

<p>By sharing electrons to fill their valence shells, atoms achieve a more stable electron configuration and lower their overall energy.</p> Signup and view all the answers

What is a nonpolar covalent bond?

<p>It is a type of covalent bond in which electrons are shared equally between two atoms of similar electronegativity.</p> Signup and view all the answers

What does electronegativity represent?

<p>It measures the strength with which an atom attracts electrons towards itself in a chemical bond.</p> Signup and view all the answers

What is a compound?

<p>It is a molecule formed by the chemical bonding of two or more atoms of different elements.</p> Signup and view all the answers

What is an ionic bond?

<p>It is a type of bond where electrons are completely transferred from one atom to another, creating ions with opposite charges that attract each other.</p> Signup and view all the answers

What is an anion?

<p>It is an ion that carries a negative charge, formed when an atom gains one or more electrons.</p> Signup and view all the answers

What is the electron-sharing continuum?

<p>It represents a range of chemical bonds, from nonpolar covalent bonds (equal sharing of electrons) to ionic bonds (complete transfer of electrons), with polar covalent bonds falling in between.</p> Signup and view all the answers

How can unpaired electrons in the valence shell participate in chemical bonding?

<p>They can form double and triple covalent bonds.</p> Signup and view all the answers

How does the shape of a molecule impact its behavior?

<p>The shape of a simple molecule is determined by the geometry of its bonds, which influence its interactions with other molecules and its overall properties.</p> Signup and view all the answers

What are the different ways to represent molecules?

<p>Molecules can be represented in different ways, including molecular formulas, structural formulas, ball-and-stick models, and space-filling models.</p> Signup and view all the answers

How important is water to life?

<p>Water is essential for life, making up approximately 75% of a cell's volume and playing a crucial role in numerous biological processes.</p> Signup and view all the answers

Substances are more likely to react when they are dissolved in a solvent.

<p>True (A)</p> Signup and view all the answers

What makes water a polar molecule?

<p>Water is a polar molecule because the oxygen atom has a partial negative charge due to its higher electronegativity, while the hydrogen atoms have partial positive charges.</p> Signup and view all the answers

What is a hydrogen bond?

<p>It is a weak electrical attraction between a partially positive hydrogen atom in one molecule and a partially negative atom (usually oxygen or nitrogen) in another molecule.</p> Signup and view all the answers

Why are hydrogen bonds important for water's properties?

<p>They contribute to water's high cohesiveness, its ability to act as an excellent solvent, and its high heat capacity.</p> Signup and view all the answers

What is a hydrophilic molecule?

<p>It is a molecule that is attracted to water, typically due to its polar nature or the presence of charged groups.</p> Signup and view all the answers

How do hydrogen bonds contribute to water's dissolving properties?

<p>They allow water to interact with polar molecules, disrupting the bonds holding them together and enabling them to dissolve in water.</p> Signup and view all the answers

Why is water cohesive?

<p>Water is cohesive because its molecules are held together by hydrogen bonds, which provide a strong attraction between water molecules.</p> Signup and view all the answers

What is surface tension?

<p>It is a cohesive force that arises from the attraction between molecules at the surface of a liquid, causing the surface to act like an elastic membrane.</p> Signup and view all the answers

Water expands as it freezes.

<p>True (A)</p> Signup and view all the answers

Why is the ability of ice to float important for life on Earth?

<p>It provides a layer of insulation on water bodies, preventing them from freezing solid and protecting aquatic life from extreme temperatures.</p> Signup and view all the answers

What is the specific heat of a substance?

<p>It is the amount of energy required to raise the temperature of 1 gram of that substance by 1°C.</p> Signup and view all the answers

Why does water have a high specific heat?

<p>The strong hydrogen bonds between water molecules require a significant amount of energy to break, leading to a high heat capacity.</p> Signup and view all the answers

How do hydrogen bonds contribute to water's high specific heat?

<p>They absorb a significant amount of energy to break, making it difficult to raise the temperature of water.</p> Signup and view all the answers

What happens during a chemical reaction?

<p>Substances are broken down into new substances, or combine to form new substances, with the breaking and forming of chemical bonds.</p> Signup and view all the answers

What are reactants?

<p>They are the starting materials in a chemical reaction.</p> Signup and view all the answers

What are products?

<p>They are the substances formed as a result of a chemical reaction.</p> Signup and view all the answers

Water molecules can dissociate, forming a hydrogen ion (H+) and a hydroxide ion (OH-).

<p>True (A)</p> Signup and view all the answers

What is chemical equilibrium?

<p>It is a state in a reversible chemical reaction where the rates of the forward and reverse reactions are equal, resulting in no net change in the concentrations of reactants and products.</p> Signup and view all the answers

Why are hydronium ions (H3O+) formed?

<p>Protons (H+) are highly reactive and do not exist independently in solution, so they readily combine with water molecules to form hydronium ions, which is how acidic solutions are represented and measured.</p> Signup and view all the answers

What is molarity (M)?

<p>It represents the concentration of a substance in a solution, specifically the number of moles of solute present per liter of solution.</p> Signup and view all the answers

What are acids?

<p>They are substances that donate protons (H+) during chemical reactions, increasing the hydronium ion (H3O+) concentration of a solution.</p> Signup and view all the answers

What is pH?

<p>It is a logarithmic measure of the hydrogen ion concentration in a solution, indicating its acidity or basicity.</p> Signup and view all the answers

What do buffers do?

<p>They are substances that help to minimize changes in pH by resisting shifts in acidity or basicity, maintaining a relatively stable pH level.</p> Signup and view all the answers

What is homeostasis?

<p>It refers to the ability of an organism to maintain a stable internal environment despite external fluctuations.</p> Signup and view all the answers

What is thermal energy?

<p>It is the kinetic energy of molecules due to their motion.</p> Signup and view all the answers

What is the first law of thermodynamics?

<p>It states that energy cannot be created or destroyed, only transferred or transformed from one form to another.</p> Signup and view all the answers

What is the second law of thermodynamics?

<p>It states that the entropy of a closed system always increases over time, meaning that systems tend to move towards a more disordered state.</p> Signup and view all the answers

What is entropy?

<p>It is a measure of disorder or randomness in a system.</p> Signup and view all the answers

What makes a chemical reaction spontaneous?

<p>A chemical reaction is spontaneous if it proceeds on its own without continuous external influence and does not require added energy.</p> Signup and view all the answers

What are two factors that determine if a reaction will proceed spontaneously?

<ol> <li>The products of the reaction have lower potential energy than the reactants, and 2. The products are less ordered than the reactants, meaning there is higher entropy in the products.</li> </ol> Signup and view all the answers

What is chemical evolution?

<p>The process of forming increasingly complex carbon-containing molecules from simple molecules, potentially leading to the origin of life.</p> Signup and view all the answers

What did Stanley Miller's spark-discharge experiment demonstrate?

<p>It demonstrated that complex organic molecules, including amino acids, could be formed from simple molecules like methane, ammonia, hydrogen, and water, under conditions simulating a possible primitive Earth environment.</p> Signup and view all the answers

What are the two main factors that determine if a chemical reaction will proceed spontaneously?

<ol> <li>Lower potential energy in products: The products of the reaction have less potential energy than the reactants. 2. Higher entropy: The products have a less ordered structure than the reactants.</li> </ol> Signup and view all the answers

What is a monomer?

<p>A small molecule that can bind to other identical or similar molecules to form a larger molecule, called a polymer, by a process known as polymerization.</p> Signup and view all the answers

What is polymerization?

<p>The process of joining monomers together, usually through a condensation reaction, to form a polymer.</p> Signup and view all the answers

What is a condensation reaction?

<p>It is a reaction in which two or more molecules combine to form a larger molecule, with the removal of a small molecule, typically water, as a byproduct.</p> Signup and view all the answers

What is hydrolysis?

<p>It is a reaction in which a polymer is broken down into its constituent monomers by the addition of water molecules.</p> Signup and view all the answers

Hydrolysis is a process that increases entropy.

<p>True (A)</p> Signup and view all the answers

Why does hydrolysis dominate?

<p>It is more energetically favorable, meaning that it requires less energy to happen naturally than the reverse reaction of polymerization.</p> Signup and view all the answers

What is the significance of the early polymerization of macromolecules?

<p>It is believed to have played a crucial role in the origin of life, as the formation of complex molecules from simple monomers is essential for the development of biological systems.</p> Signup and view all the answers

What is a functional group?

<p>A group of atoms within a molecule that has a characteristic structure and function, often influencing the molecule's chemical reactivity and overall properties.</p> Signup and view all the answers

What is the significance of carbon in life?

<p>Carbon is the fundamental building block of life, forming the backbone of all organic molecules, due to its ability to form four covalent bonds with other atoms.</p> Signup and view all the answers

Carbon atoms can form chains or rings.

<p>True (A)</p> Signup and view all the answers

What is the significance of functional groups in organic molecules?

<p>They define the chemical behavior of organic molecules, influencing their reactivity, polarity, solubility, and overall properties.</p> Signup and view all the answers

What is the significance of the early Earth's environment in the context of chemical evolution?

<p>The early Earth's environment, likely rich in simple molecules and subject to significant sources of energy, provided a favorable environment for the emergence and formation of complex organic molecules.</p> Signup and view all the answers

Study Notes

Chemical Basis of Life

  • Chemical evolution is the leading explanation for the origin of life on Earth
  • Complex carbon-containing substances formed, leading to self-replicating molecules
  • This transitioned from chemical to biological evolution
  • Evolution through natural selection then took over, with the original molecule multiplying
  • Descendants became metabolically active and acquired membranes
  • Five characteristics of life were fulfilled

Building Blocks of Chemical Evolution

  • Four main types of atoms (hydrogen, carbon, nitrogen, and oxygen) make up 96% of matter in organisms
  • How did simple substances evolve into complex living structures?
  • The physical structures of hydrogen, carbon, nitrogen, and oxygen atoms are essential
  • The structures of simple molecules (water, carbon dioxide, etc.) are building blocks of chemical evolution

Basic Atomic Structure

  • A nucleus comprised of protons (positive charge) and neutrons (neutral charge).
  • Orbiting electrons (negative charge).
  • Atoms have an equal number of protons and electrons, resulting in an electrically neutral charge.

Understanding Elements

  • Elements consist entirely of a single type of atom
  • Atomic number: the characteristic number of protons in the nucleus of an atom
  • Mass number: the sum of protons and neutrons in an atom.

Weighing Atoms

  • Dalton (Da): the mass unit for protons and neutrons, each having a mass of one dalton
  • The mass of an electron is negligible and can be ignored.
  • Mass number is essentially equal to the mass of an atom
  • Neutrons in an element may vary, forming elements called isotopes
  • Isotopes have different masses and atomic weights; an element's atomic weight is the average mass of its naturally occurring isotopes.

Weight of Molecules in Grams

  • A Mole represents 6.022 x 1023
  • The mass of one mole of an atom is equivalent to its atomic weight in grams.
  • Molecular weight: the mass of one mole of a molecule, calculated as the sum of the atomic weights of all atoms in the molecule.

The Atomic Structure of the First 18 Elements

  • The elements highlighted in the periodic table (H, C, N, O, P, and S) collectively make up over 99% of all atoms in the body.
  • Each element has a specific electron shell arrangement.

Atomic Structure and Electron Shells

  • Electrons orbit the atomic nucleus in specific regions referred to as orbitals.
  • Orbitals are grouped into electron shells, with each shell having a unique number. Increasingly higher numbered shells are further away from the nucleus and have higher energy
  • Electron shells fill in order, starting with the innermost shells

Covalent Bonding

  • Atoms become more stable by forming covalent bonds, where they share electrons
    • Hydrogen, an example where two hydrogen atoms share electrons to fill their outer shell.
  • Whether or not bonds are equal is important:
    • Nonpolar covalent bonds share electrons equally
    • Polar covalent bonds share electrons unequally, leading to partial charges.

Electronegativity

  • The strength with which an atom attracts electrons towards itself.
  • Electronegativity increases as you move up and to the right of the periodic table. (O>N>S>C>H)

Polar Bonds

  • Polar covalent bonds occur when electrons are shared unequally between atoms due to differing electronegativities.
  • This results in partial charges (δ+ and δ−) on the atoms.

Ionic Bonding

  • Atoms transfer electrons rather than sharing them, creating ions (charged atoms)
  • Cations are positively charged and lose electrons.
  • Anions are negatively charged and gain electrons.
  • Ionic bonds form in compounds where there's a complete transfer of electrons between atoms.

The Electron-Sharing Continuum

  • This continuum ranges from equal electron sharing (nonpolar covalent) to complete electron transfer (ionic).

Unpaired Electrons in Covalent Bonds

  • Unpaired electrons allow atoms to form double and triple bonds by sharing more than one pair of electrons.

Molecule's Shape

  • The geometry of a molecule is determined by the arrangement of its bonds due to electron repulsions
  • The shape of a molecule influences its behavior.

Representing Molecules

  • Molecules can be represented in several ways, such as through molecular formulas, structural formulas, ball-and-stick models, and space-filling models.

Properties of Water

  • Water is a polar molecule with partial positive charges on hydrogen atoms and a partial negative charge on the oxygen atom.
  • Its polarity enables water to act as a good solvent, facilitating interactions with other polar molecules.

Water as a Solvent

  • Substances dissolved into a solvent form a solution.
  • Water dissolves charged and polar molecules readily due to hydrogen bonding.

Hydrophobic Molecules

  • Nonpolar molecules (uncharged compounds) do not dissolve readily in water.
  • Hydrophobic molecules cluster together in water solutions through van der Waals interactions

Cohesion and Adhesion

  • Cohesion describes the attraction between like molecules (water molecules)
  • Adhesion describes the attraction between unlike molecules (water molecules and other polar molecules).
  • Cohesion and adhesion play critical roles in various biological processes, like water transport in plants.

Surface Tension

  • Cohesion causes surface tension, which is the resistance of a liquid to spreading out.
  • The molecules at the surface experience a net inward force due to the bonds with surrounding molecules

Water Density

  • Unusual characteristic of water is that when it freezes, the molecules form a lattice structure that makes ice less dense than liquid water.

Water's Heat Capacity

  • Water has a high specific heat, meaning it can absorb a large amount of energy without a significant change in temperature.
  • These properties are due to hydrogen bonding impacting the ability of water to store heat in molecules.

The Role of Water in Chemical Reactions

  • Chemical reactions occur when substances combine, break down into other substances, or form new bonds.
  • Water plays an essential role in acid-base chemistry, including dissociation into protons and hydroxide ions.

Measuring Concentration

  • Mole (6.022 x 10²³): a unit of measurement for the amount of a substance, relating to mass in grams.
  • Molarity (M): the concentration of a substance in solution, represented as moles of solute per liter of solution.

Acids and Bases

  • Acids release protons, increasing the hydronium ion concentration in a solution (H3O+).
  • Bases accept protons, decreasing the hydronium ion concentration.

pH

  • pH is a measure of the hydrogen ion concentration in a solution, expressed on a logarithmic scale.
  • The pH scale ranges from 0 to 14 and provides a measure of the acidity (pH<7) or basicity (pH>7) of a solution.
  • Water has a neutral pH of 7.

Buffers

  • Buffers minimize changes in pH in a solution, maintaining a relatively constant pH.

Chemical Reactions

  • Chemical equations show balanced reactions.
  • A System is a group of components that interact.
  • There are endothermic (absorb heat) and exothermic (release heat) reactions

What Makes a Chemical Reaction Spontaneous

  • Spontaneous reactions occur without continuous external influence
  • Two key factors are:
    • Products have lower potential energy than reactants
    • Products are less ordered than reactants (higher entropy)

Stanley Miller's Experiment

  • Demonstrated how complex organic molecules can be produced from simple molecules in conditions resembling early Earth, including heat and electrical charges, creating building blocks of life such as amino acids.

Life is Carbon Based

  • Carbon is the foundation of life.
  • Carbon atoms have unique bonding properties, forming chains and rings, which allows diverse organic molecules to exist.

Functional Groups

  • Functional groups are specific groups of atoms within molecules that confer particular chemical properties to the molecule

Macromolecules

  • Large complex molecules are made up of repeating smaller monomers that connect together via polymerization.

Polymerization

  • Process of linking monomers to form polymers
    • Condensation reactions lead to the formation of polymers and release of water molecules
    • Hydrolysis reactions break down polymers into monomers and require water molecules.

End of Chapter Questions to Practice

  • Specific questions for review are listed.

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Description

Explore the origins of life on Earth through chemical evolution and understand the transition from simple substances to complex living structures. This quiz covers the building blocks of life, atomic structures, and the characteristics that define living organisms.

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