CHEM 102 Final Flashcards
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Questions and Answers

What is matter?

Anything occupying space and having mass.

Which of the following are forms of matter? (Select all that apply)

  • Mixture (correct)
  • Element (correct)
  • Atom (correct)
  • Compound (correct)
  • What is a physical change?

    A change that doesn't alter the formula of compounds or elements.

    What is a chemical change?

    <p>A process that separates a compound into elements and involves making or breaking chemical bonds.</p> Signup and view all the answers

    What are measurements in chemistry?

    <p>SI units and metric prefixes.</p> Signup and view all the answers

    What does uncertainty in measurements refer to?

    <p>All measurements have uncertainty, usually ±1 in the last digit.</p> Signup and view all the answers

    What is precision in the context of measurements?

    <p>Closeness of measurements to each other and reproducibility.</p> Signup and view all the answers

    What is accuracy in measurements?

    <p>Closeness of a measurement to the accepted or true value.</p> Signup and view all the answers

    What are significant figures?

    <p>All solid numbers are significant, with specific rules regarding zeros.</p> Signup and view all the answers

    What are the addition rules for significant figures?

    <p>The answer has the same number of decimal places as the term with the least number of decimal places.</p> Signup and view all the answers

    What are the multiplication and division rules for significant figures?

    <p>The answer has the same number of significant figures as the term with the least number of significant figures.</p> Signup and view all the answers

    What is dimensional analysis?

    <p>Using units and conversion factors to obtain the correct answer.</p> Signup and view all the answers

    What is percent error?

    <p>The formula is |true result - experimental| / true result x 100.</p> Signup and view all the answers

    What is Dalton's atomic theory?

    <ol> <li>Each element is made up of atoms. 2) Atoms of the same element are alike. 3) Compounds form when atoms of 2 or more elements combine. 4) The law of conservation of mass states that atoms are rearranged, not created or destroyed.</li> </ol> Signup and view all the answers

    What did JJ Thomson discover?

    <p>Particles are charged and have mass, and negatively charged particles are fundamental to atoms.</p> Signup and view all the answers

    What did Rutherford's gold foil experiment reveal?

    <p>Atoms are mostly empty space, with protons in a dense nucleus that repels alpha particles.</p> Signup and view all the answers

    What are subatomic particles?

    <p>Protons (positive charge), neutrons (neutral), and electrons (negative charge).</p> Signup and view all the answers

    What is the atomic number?

    <h1>of protons in an atom.</h1> Signup and view all the answers

    What is the mass number?

    <h1>of protons + # of neutrons.</h1> Signup and view all the answers

    What differentiates a neutral atom from an ion?

    <p>A neutral atom has equal numbers of electrons and protons, while an ion is formed by the gain or loss of electrons.</p> Signup and view all the answers

    What are isotopes?

    <p>Atoms of the same element with different numbers of neutrons.</p> Signup and view all the answers

    What is a cation?

    <p>A positively charged ion formed when electrons are lost.</p> Signup and view all the answers

    What is an anion?

    <p>A negatively charged ion formed when electrons are gained.</p> Signup and view all the answers

    What does a chemical formula indicate?

    <p>Subscripts tell how many of each kind of atom are present.</p> Signup and view all the answers

    What is an ionic compound?

    <p>Made up of cations and anions held together by attraction.</p> Signup and view all the answers

    What is a covalent compound?

    <p>Made up entirely of nonmetals, held together by sharing electrons.</p> Signup and view all the answers

    What are the rules for naming ionic compounds?

    <p>Cation first, then anion; use base names and roman numerals for transition metals.</p> Signup and view all the answers

    What are the rules for naming covalent compounds?

    <p>Base name for first element, anion naming like a regular anion, and use prefixes for numbers.</p> Signup and view all the answers

    What is Avogadro's number?

    <p>6.0223 x 10²³ moles.</p> Signup and view all the answers

    How do you calculate an average atomic mass?

    <p>Iso 1 mass(abundance) + (Iso 2 mass)(abundance) + ... = average atomic mass.</p> Signup and view all the answers

    What is a molecular formula?

    <p>Gives the actual number and kinds of atoms in a compound.</p> Signup and view all the answers

    What is an empirical formula?

    <p>The simplest whole number ratio of atoms in a compound.</p> Signup and view all the answers

    What does percent mass indicate?

    <p>Mass of X = mass of X / total mass x 100.</p> Signup and view all the answers

    What is combustion analysis?

    <p>Starts with C∧H∧O∧ -&gt; CO₂ + H₂O.</p> Signup and view all the answers

    What do chemical reactions entail?

    <p>Breaking and making chemical bonds, atoms are conserved.</p> Signup and view all the answers

    What are diatomic elements?

    <p>HONClBrIF.</p> Signup and view all the answers

    What are the types of reactions?

    <p>Synthesis, decomposition, single displacement, double displacement, and combustion.</p> Signup and view all the answers

    What is a limiting reactant?

    <p>The reactant that produces less of the product.</p> Signup and view all the answers

    What is percent yield?

    <p>Actual yield / theoretical yield x 100.</p> Signup and view all the answers

    What is a solution?

    <p>A homogeneous mixture.</p> Signup and view all the answers

    What is a solvent?

    <p>The dissolving medium present in the greatest amount.</p> Signup and view all the answers

    What is a solute?

    <p>The substance dissolved in a solution.</p> Signup and view all the answers

    What is the role of water as a solvent?

    <p>Water is a polar covalent compound that dissolves other polar and ionic solutes.</p> Signup and view all the answers

    What are strong electrolytes?

    <p>Compounds that are 100% ionized or dissociated.</p> Signup and view all the answers

    What are weak electrolytes?

    <p>Only some ions are present, conducts electricity but only slightly.</p> Signup and view all the answers

    What are exothermic reactions?

    <p>Reactions that release heat; ∆H is negative.</p> Signup and view all the answers

    What is electron affinity?

    <p>Energy released or absorbed when an atom gains an electron.</p> Signup and view all the answers

    What does isoelectronic mean?

    <p>Having the same number of electrons.</p> Signup and view all the answers

    What are the three most electronegative elements?

    <p>Fluorine, Oxygen, and Nitrogen.</p> Signup and view all the answers

    How do ionic bonds form?

    <p>By transferring valence electrons between atoms.</p> Signup and view all the answers

    What is a nonpolar covalent bond?

    <p>Electrons are shared equally between atoms.</p> Signup and view all the answers

    What is a polar covalent bond?

    <p>Electrons are not shared equally, resulting in a dipole.</p> Signup and view all the answers

    What are Lewis structures?

    <p>Diagrams that show the arrangement of valence electrons in a compound.</p> Signup and view all the answers

    What does the Valence Shell Electron Pair Repulsion (VSEPR) model state?

    <p>Electrons repel each other, resulting in specific molecular geometries.</p> Signup and view all the answers

    What are sigma bonds?

    <p>Bonds formed by the end-to-end overlap of atomic orbitals.</p> Signup and view all the answers

    What are pi bonds?

    <p>Bonds formed by the side-to-side overlap of parallel p orbitals.</p> Signup and view all the answers

    How are sigma and pi bonds related in multiple bonds?

    <p>A single bond consists of 1 sigma bond; a double bond consists of 1 sigma and 1 pi bond; a triple bond consists of 1 sigma and 2 pi bonds.</p> Signup and view all the answers

    What are intermolecular forces?

    <p>The attraction between neighboring molecules.</p> Signup and view all the answers

    Study Notes

    Matter and Its Forms

    • Matter is defined as anything that occupies space and possesses mass.
    • Forms of matter range from simplest (atoms) to complex (mixtures):
      • Atoms consist of neutrons, protons, and electrons.
      • Elements are collections of the same type of atoms.
      • Compounds are combinations of different elements forming constant compositions through chemical bonds.
      • Mixtures can be homogeneous (uniform composition) or heterogeneous (non-uniform composition).

    Changes in Matter

    • Physical changes do not alter the chemical formulas of compounds or elements (e.g., phase changes).
    • Chemical changes involve breaking down compounds into their constituent elements and entail making and breaking chemical bonds.

    Measurements and Uncertainty

    • SI units and metric prefixes are essential in scientific measurements.
    • All measurements have inherent uncertainty, typically assumed to be ±1 in the last digit.
    • Precision refers to the consistency of measurements, while accuracy denotes how close a measurement is to the true value.

    Significant Figures and Calculation Rules

    • Significant figures include all solid numbers, with specific rules applied to zeros based on their position.
    • In addition, calculations ensure answers reflect the least number of decimal places for addition and least significant figures for multiplication/division.
    • Dimensional analysis employs units and conversion factors to derive correct answers.

    Atomic Structure and Theories

    • Dalton's Atomic Theory posits that elements are composed of atoms, with atoms of the same element being identical, compounds having constant compositions, and mass conservation during chemical reactions.
    • JJ Thomson demonstrated that particles carry charge and possess mass, indicating the existence of negatively charged fundamental atomic particles.
    • Rutherford's experiments revealed that atoms are primarily empty space with a dense nucleus containing protons.

    Subatomic Particles

    • Protons are positively charged and located in the nucleus, while neutrons are neutral and also found in the nucleus. Electrons are negatively charged and occupy the electron cloud.
    • The atomic number (lower left corner) indicates the number of protons, while the mass number (upper left corner) is the total of protons and neutrons.

    Ions and Isotopes

    • Neutral atoms have equal numbers of electrons and protons. Ions result from the gain or loss of electrons.
    • Isotopes represent atoms of the same element with differing neutron counts.

    Ionic and Covalent Compounds

    • Cations (positively charged) result from electron loss; anions (negatively charged) arise from electron gain.
    • Naming conventions:
      • Ionic compounds prioritize cations followed by anions, utilizing base names and Roman numerals for transition metals.
      • Covalent compounds consist of nonmetals, named using prefixes to denote quantities and root modifications for anions.

    Chemical Measurements and Calculations

    • Avogadro's number is 6.0223 x 10²³ moles.
    • Average atomic mass can be calculated based on isotope mass and abundance.
    • Molecular formulas provide actual atom quantities in a compound, while empirical formulas reflect the simplest whole number ratios.

    Reactions and Limiting Reactants

    • Chemical reactions involve bond breaking and forming, adhering to the law of conservation of mass and demonstrating mole relationships between reactants and products.
    • Limiting reactants identify the component that yields the lesser amount of product, while percent yield compares actual and theoretical yields.

    Solutions and Electrolytes

    • A solution is a homogeneous mixture composed of solutes (substances dissolved) and solvents (the dissolving medium).
    • Strong electrolytes are ionic compounds that ionize completely, while weak electrolytes only partially dissociate.

    Energy Changes in Reactions

    • Exothermic reactions release energy, often indicated by a positive ∆H value.
    • Electron affinity refers to the energy change during electron gain by an atom and shows erratic trends.

    Bonding and Molecular Geometry

    • Electrons bond either through ionic (transfer) or covalent (sharing) interactions, affecting electronegativity and bond properties.
    • VSEPR theory explains molecular geometry based on electron repulsion, determining shapes like linear, tetrahedral, and octahedral formations.
    • Sigma bonds involve head-to-head orbital overlap, while pi bonds result from side-to-side overlap; the bonds determine rotational behavior within molecules.

    Intermolecular Forces

    • Intermolecular forces are attractions between neighboring molecules that influence their physical states and properties.

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    Test your knowledge of essential chemistry concepts with these flashcards designed for CHEM 102 at UIUC. Covering definitions and classifications of matter, these cards will help reinforce your understanding in preparation for the final exam.

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