Chapter 3: Carbonyl Chemistry Aldehydes and Ketones
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Questions and Answers

How can aldehydes be prepared?

Oxidize primary alcohols using pyridinium chlorochromate

What reagent can be used to reduce an ester to form an aldehyde?

diisobutylaluminum hydride (DIBAH)

How can ketones be prepared?

Oxidize a 2° alcohol

What does the ozonolysis of alkenes yield if one of the unsaturated carbon atoms is disubstituted?

<p>Ketones</p> Signup and view all the answers

What functional group is used as a substituent with the suffix -yl?

<p>Acyl group (R-C=O)</p> Signup and view all the answers

What is the prefix used when a ketone has other functional groups present?

<p>oxo-</p> Signup and view all the answers

What is the product of the Wolff-Kishner reaction when treating an aldehyde or ketone with hydrazine and KOH?

<p>Alkane</p> Signup and view all the answers

How do Grignard reagents typically react due to the strong polarization of the carbon-magnesium bond?

<p>As R : - MgX +</p> Signup and view all the answers

What type of compounds can be used to characterize liquid ketones or aldehydes by their melting points?

<p>Imines and hydrazones</p> Signup and view all the answers

What is formed when amines add to C=O, resulting in R2C=NR (after loss of HOH)?

<p>Imines</p> Signup and view all the answers

What is the product of the Cannizzaro reaction involving an aldehyde and OH-?

<p>Simultaneous oxidation and reduction (disproportionation)</p> Signup and view all the answers

What type of compounds are formed when two equivalents of ROH add to C=O in the presence of an acid catalyst?

<p>Acetals (R2C(OR')2)</p> Signup and view all the answers

What reagent can efficiently oxidize aldehydes to carboxylic acids?

<p>CrO3 in aqueous acid</p> Signup and view all the answers

Which reagent, known as Tollens' reagent, can oxidize aldehydes to carboxylic acids and metallic silver?

<p>Silver oxide, Ag2O, in aqueous ammonia</p> Signup and view all the answers

What happens when ketones undergo slow cleavage with hot, alkaline KMnO4?

<p>C–C bond next to C=O is broken to give carboxylic acids</p> Signup and view all the answers

In what type of ketones is the reaction practical for cleaving symmetrical ketones?

<p>symmetrical ketones</p> Signup and view all the answers

What kind of intermediate is produced in nucleophilic addition reactions of aldehydes and ketones?

<p>tetrahedral alkoxide ion intermediate</p> Signup and view all the answers

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