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Questions and Answers
What are hydrocarbons composed of?
What are hydrocarbons composed of?
Carbon and hydrogen
What are the three subgroups of aliphatic hydrocarbons?
What are the three subgroups of aliphatic hydrocarbons?
Aromatic hydrocarbons are cyclic, planar, and contain resonance bonds.
Aromatic hydrocarbons are cyclic, planar, and contain resonance bonds.
True (A)
What is the simplest aromatic hydrocarbon?
What is the simplest aromatic hydrocarbon?
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What is a functional group?
What is a functional group?
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Which of these are structural features of a functional group?
Which of these are structural features of a functional group?
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Which of the following is NOT a type of intermolecular force?
Which of the following is NOT a type of intermolecular force?
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The strongest intermolecular force is hydrogen bonding.
The strongest intermolecular force is hydrogen bonding.
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What is the relationship between intermolecular forces and boiling point?
What is the relationship between intermolecular forces and boiling point?
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The melting point of a compound is influenced by the same factors as its boiling point.
The melting point of a compound is influenced by the same factors as its boiling point.
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What is the general rule regarding solubility?
What is the general rule regarding solubility?
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A large organic molecule with a polar functional group is likely to be water soluble.
A large organic molecule with a polar functional group is likely to be water soluble.
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What is the term used to describe the nonpolar part of a molecule that is not attracted to water?
What is the term used to describe the nonpolar part of a molecule that is not attracted to water?
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What are the two distinct parts of a soap molecule?
What are the two distinct parts of a soap molecule?
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A fatty acid is water-soluble.
A fatty acid is water-soluble.
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What are ionophores?
What are ionophores?
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Flashcards
Hydrocarbons
Hydrocarbons
Compounds containing only carbon and hydrogen atoms.
Carbon to Carbon bonds
Carbon to Carbon bonds
A chain of carbon atoms can be straight, branched, or cyclic.
Primary (1o) carbon
Primary (1o) carbon
A carbon atom bonded to one other carbon atom.
Secondary (2o) carbon
Secondary (2o) carbon
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Tertiary (3o) carbon
Tertiary (3o) carbon
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Quaternary (4o) carbon
Quaternary (4o) carbon
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Aliphatic Hydrocarbons
Aliphatic Hydrocarbons
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Alkanes
Alkanes
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Alkenes
Alkenes
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Alkynes
Alkynes
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Aromatic Hydrocarbons
Aromatic Hydrocarbons
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Functional Group
Functional Group
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Heteroatoms
Heteroatoms
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Aliphatic or Aromatic
Aliphatic or Aromatic
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Functional group differences
Functional group differences
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Reactivity of Functional Groups
Reactivity of Functional Groups
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Nucleophile
Nucleophile
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Electrophile
Electrophile
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R Group
R Group
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Ethane
Ethane
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Hydroxy group
Hydroxy group
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C-Z bonds
C-Z bonds
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Carbonyl group
Carbonyl group
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Multi-functional molecule
Multi-functional molecule
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Intermolecular forces
Intermolecular forces
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Van der Waals forces
Van der Waals forces
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Dipole-Dipole interactions
Dipole-Dipole interactions
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Hydrogen Bonding
Hydrogen Bonding
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Boiling Point
Boiling Point
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Melting Point
Melting Point
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Solubility
Solubility
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Like dissolves like
Like dissolves like
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Hydrophobic
Hydrophobic
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Hydrophilic
Hydrophilic
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Soap molecules
Soap molecules
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Crown Ethers
Crown Ethers
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Study Notes
Chapter 3: Organic Molecules & Functional Groups
- This chapter covers organic molecules and their functional groups.
- Organic molecules contain carbon and hydrogen.
- Aliphatic hydrocarbons can be alkanes, alkenes, or alkynes.
- Aromatic hydrocarbons are cyclic and planar, exhibiting resonance stability.
- Benzene is the simplest aromatic hydrocarbon (C₆H₆).
- Functional groups are atoms or groups of atoms with unique chemical and physical properties attached to the carbon backbone of organic molecules.
- Heteroatoms are atoms other than carbon or hydrogen.
- Functional groups affect the molecule's geometry, physical properties, reactivity, and solubility characteristics.
- Functional groups with C=O bonds are important and include aldehydes, ketones, carboxylic acids, esters, and amides.
- Multi-functional molecules have multiple functional groups.
- The strength of intermolecular forces correlates with boiling and melting points. Molecules with stronger intermolecular forces have higher boiling and melting points.
- The type of intermolecular forces (van der Waals, dipole-dipole, and hydrogen bonding) depends on the structure and functional groups in a compound.
- Compounds such as butane will have a lower boiling point compared to butanol or other molecules with stronger bonds. Compounds with larger surface areas will exhibit stronger intermolecular forces and the bonds affect the solubility of compounds in water.
- Organic molecules are soluble in water if they possess a polar functional group and/or a minimal number of carbon atoms. Compounds with only a small number of carbon atoms and higher concentrations of polar functional groups such as hydroxyl or carboxyl are soluble in water.
- Solubility is affected by the "like dissolves like" principle. Polar substances tend to dissolve in polar solvents, and nonpolar substances dissolve in nonpolar solvents.
- Hydrophobic portions of molecules are insoluble in water, whereas hydrophilic portions are soluble.
- The size and shape of an organic molecule affect solubility characteristics and melting point characteristics. The more compact and symmetrical shape of a molecule tends to exhibit higher melting points and other solubility traits compared to those with more surface area or more chaotic structures.
- Functional groups determine the reactivity of organic molecules. Electrons in molecules are attracted to electron-poor/electrophilic areas in a molecule.
- Electrophilic sites have lower electron density.
Homework Problems
- Some homework problems are included in the chapter. Specifically, problems 3.12, 3.13, 3.15, 3.19, 3.20, 3.39, 3.50, 3.53, 3.57, and 3.58
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Description
Explore the fascinating world of organic molecules and their functional groups in this chapter. Learn about hydrocarbons, aromatic compounds, and the impact of functional groups on molecular properties. Understand how heteroatoms and intermolecular forces play a role in the characteristics of organic substances.