Organic Chemistry (CHM 221) Chapter 3
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Questions and Answers

What are hydrocarbons composed of?

Carbon and hydrogen

What are the three subgroups of aliphatic hydrocarbons?

  • Aldehydes, ketones, and carboxylic acids
  • Alcohols, esters, and amides
  • Alkanes, alkenes, and alkynes (correct)
  • Ethers, amines, and thiols
  • Aromatic hydrocarbons are cyclic, planar, and contain resonance bonds.

    True (A)

    What is the simplest aromatic hydrocarbon?

    <p>Benzene</p> Signup and view all the answers

    What is a functional group?

    <p>An atom or group of atoms responsible for the characteristic chemical and physical properties of an organic molecule</p> Signup and view all the answers

    Which of these are structural features of a functional group?

    <p>Both A and B (C)</p> Signup and view all the answers

    Which of the following is NOT a type of intermolecular force?

    <p>Ionic bonding (A)</p> Signup and view all the answers

    The strongest intermolecular force is hydrogen bonding.

    <p>True (A)</p> Signup and view all the answers

    What is the relationship between intermolecular forces and boiling point?

    <p>The stronger the intermolecular forces, the higher the boiling point.</p> Signup and view all the answers

    The melting point of a compound is influenced by the same factors as its boiling point.

    <p>True (A)</p> Signup and view all the answers

    What is the general rule regarding solubility?

    <p>Like dissolves like.</p> Signup and view all the answers

    A large organic molecule with a polar functional group is likely to be water soluble.

    <p>False (B)</p> Signup and view all the answers

    What is the term used to describe the nonpolar part of a molecule that is not attracted to water?

    <p>Hydrophobic</p> Signup and view all the answers

    What are the two distinct parts of a soap molecule?

    <p>A hydrophilic head and a hydrophobic tail</p> Signup and view all the answers

    A fatty acid is water-soluble.

    <p>False (B)</p> Signup and view all the answers

    What are ionophores?

    <p>Molecules that complex cations</p> Signup and view all the answers

    Flashcards

    Hydrocarbons

    Compounds containing only carbon and hydrogen atoms.

    Carbon to Carbon bonds

    A chain of carbon atoms can be straight, branched, or cyclic.

    Primary (1o) carbon

    A carbon atom bonded to one other carbon atom.

    Secondary (2o) carbon

    A carbon atom bonded to two other carbon atoms.

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    Tertiary (3o) carbon

    A carbon atom bonded to three other carbon atoms.

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    Quaternary (4o) carbon

    A carbon atom bonded to four other carbon atoms.

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    Aliphatic Hydrocarbons

    Aliphatic hydrocarbons are chains or rings that are not aromatic.

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    Alkanes

    Hydrocarbons with only single bonds between carbon atoms. (e.g., methane, ethane, propane)

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    Alkenes

    Hydrocarbons with at least one double bond between carbon atoms. (e.g., ethene, propene)

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    Alkynes

    Hydrocarbons with at least one triple bond between carbon atoms. (e.g., ethyne, propyne)

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    Aromatic Hydrocarbons

    Cyclic, planar compounds with resonance bonds, making them more stable. (e.g., benzene)

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    Functional Group

    A specific group of atoms within a molecule responsible for its chemical and physical properties.

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    Heteroatoms

    Atoms other than carbon or hydrogen in an organic molecule.

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    Aliphatic or Aromatic

    Functional groups can be attached to both straight chains and rings.

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    Functional group differences

    Functional groups determine the geometry, physical properties, and reactivity of a molecule.

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    Reactivity of Functional Groups

    Heteroatoms create electron-deficient sites on carbon, while polar bonds can break easily.

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    Nucleophile

    Species that donate an electron pair.

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    Electrophile

    Species that accept an electron pair.

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    R Group

    A shorthand notation for a part of a molecule.

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    Ethane

    A simple molecule with no functional group, making it very unreactive.

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    Hydroxy group

    The hydroxyl group (OH) attached to a carbon chain.

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    C-Z bonds

    Bonds between a carbon atom and a highly electronegative heteroatom.

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    Carbonyl group

    A carbon atom double-bonded to an oxygen atom.

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    Multi-functional molecule

    A molecule with multiple functional groups, potentially making it more complex.

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    Intermolecular forces

    Intermolecular forces are attractive forces between molecules.

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    Van der Waals forces

    The weakest type of intermolecular force, caused by temporary dipoles.

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    Dipole-Dipole interactions

    Attractive forces between permanent dipoles of polar molecules.

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    Hydrogen Bonding

    The strongest type of intermolecular force involving a hydrogen atom bonded to O, N, or F.

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    Boiling Point

    The temperature at which a liquid changes into a gas.

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    Melting Point

    The temperature at which a solid changes into a liquid.

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    Solubility

    The extent to which a substance dissolves in a solvent.

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    Like dissolves like

    Polar compounds dissolve in polar solvents, while nonpolar compounds dissolve in nonpolar solvents.

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    Hydrophobic

    A molecule with nonpolar parts that repel water.

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    Hydrophilic

    A molecule with polar parts that attract water.

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    Soap molecules

    Molecules with a polar head and a nonpolar tail, used in cleaning products.

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    Crown Ethers

    Cyclic ethers that can bind specific cations based on their cavity size.

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    Study Notes

    Chapter 3: Organic Molecules & Functional Groups

    • This chapter covers organic molecules and their functional groups.
    • Organic molecules contain carbon and hydrogen.
    • Aliphatic hydrocarbons can be alkanes, alkenes, or alkynes.
    • Aromatic hydrocarbons are cyclic and planar, exhibiting resonance stability.
    • Benzene is the simplest aromatic hydrocarbon (C₆H₆).
    • Functional groups are atoms or groups of atoms with unique chemical and physical properties attached to the carbon backbone of organic molecules.
    • Heteroatoms are atoms other than carbon or hydrogen.
    • Functional groups affect the molecule's geometry, physical properties, reactivity, and solubility characteristics.
    • Functional groups with C=O bonds are important and include aldehydes, ketones, carboxylic acids, esters, and amides.
    • Multi-functional molecules have multiple functional groups.
    • The strength of intermolecular forces correlates with boiling and melting points. Molecules with stronger intermolecular forces have higher boiling and melting points.
    • The type of intermolecular forces (van der Waals, dipole-dipole, and hydrogen bonding) depends on the structure and functional groups in a compound.
    • Compounds such as butane will have a lower boiling point compared to butanol or other molecules with stronger bonds. Compounds with larger surface areas will exhibit stronger intermolecular forces and the bonds affect the solubility of compounds in water.
    • Organic molecules are soluble in water if they possess a polar functional group and/or a minimal number of carbon atoms. Compounds with only a small number of carbon atoms and higher concentrations of polar functional groups such as hydroxyl or carboxyl are soluble in water.
    • Solubility is affected by the "like dissolves like" principle. Polar substances tend to dissolve in polar solvents, and nonpolar substances dissolve in nonpolar solvents.
    • Hydrophobic portions of molecules are insoluble in water, whereas hydrophilic portions are soluble.
    • The size and shape of an organic molecule affect solubility characteristics and melting point characteristics. The more compact and symmetrical shape of a molecule tends to exhibit higher melting points and other solubility traits compared to those with more surface area or more chaotic structures.
    • Functional groups determine the reactivity of organic molecules. Electrons in molecules are attracted to electron-poor/electrophilic areas in a molecule.
    • Electrophilic sites have lower electron density.

    Homework Problems

    • Some homework problems are included in the chapter. Specifically, problems 3.12, 3.13, 3.15, 3.19, 3.20, 3.39, 3.50, 3.53, 3.57, and 3.58

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    Description

    Explore the fascinating world of organic molecules and their functional groups in this chapter. Learn about hydrocarbons, aromatic compounds, and the impact of functional groups on molecular properties. Understand how heteroatoms and intermolecular forces play a role in the characteristics of organic substances.

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