Organic Chemistry (CHM 221) Chapter 3
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Questions and Answers

What are hydrocarbons composed of?

Carbon and hydrogen

What are the three subgroups of aliphatic hydrocarbons?

  • Aldehydes, ketones, and carboxylic acids
  • Alcohols, esters, and amides
  • Alkanes, alkenes, and alkynes (correct)
  • Ethers, amines, and thiols
  • Aromatic hydrocarbons are cyclic, planar, and contain resonance bonds.

    True

    What is the simplest aromatic hydrocarbon?

    <p>Benzene</p> Signup and view all the answers

    What is a functional group?

    <p>An atom or group of atoms responsible for the characteristic chemical and physical properties of an organic molecule</p> Signup and view all the answers

    Which of these are structural features of a functional group?

    <p>Both A and B</p> Signup and view all the answers

    Which of the following is NOT a type of intermolecular force?

    <p>Ionic bonding</p> Signup and view all the answers

    The strongest intermolecular force is hydrogen bonding.

    <p>True</p> Signup and view all the answers

    What is the relationship between intermolecular forces and boiling point?

    <p>The stronger the intermolecular forces, the higher the boiling point.</p> Signup and view all the answers

    The melting point of a compound is influenced by the same factors as its boiling point.

    <p>True</p> Signup and view all the answers

    What is the general rule regarding solubility?

    <p>Like dissolves like.</p> Signup and view all the answers

    A large organic molecule with a polar functional group is likely to be water soluble.

    <p>False</p> Signup and view all the answers

    What is the term used to describe the nonpolar part of a molecule that is not attracted to water?

    <p>Hydrophobic</p> Signup and view all the answers

    What are the two distinct parts of a soap molecule?

    <p>A hydrophilic head and a hydrophobic tail</p> Signup and view all the answers

    A fatty acid is water-soluble.

    <p>False</p> Signup and view all the answers

    What are ionophores?

    <p>Molecules that complex cations</p> Signup and view all the answers

    Study Notes

    Chapter 3: Organic Molecules & Functional Groups

    • This chapter covers organic molecules and their functional groups.
    • Organic molecules contain carbon and hydrogen.
    • Aliphatic hydrocarbons can be alkanes, alkenes, or alkynes.
    • Aromatic hydrocarbons are cyclic and planar, exhibiting resonance stability.
    • Benzene is the simplest aromatic hydrocarbon (C₆H₆).
    • Functional groups are atoms or groups of atoms with unique chemical and physical properties attached to the carbon backbone of organic molecules.
    • Heteroatoms are atoms other than carbon or hydrogen.
    • Functional groups affect the molecule's geometry, physical properties, reactivity, and solubility characteristics.
    • Functional groups with C=O bonds are important and include aldehydes, ketones, carboxylic acids, esters, and amides.
    • Multi-functional molecules have multiple functional groups.
    • The strength of intermolecular forces correlates with boiling and melting points. Molecules with stronger intermolecular forces have higher boiling and melting points.
    • The type of intermolecular forces (van der Waals, dipole-dipole, and hydrogen bonding) depends on the structure and functional groups in a compound.
    • Compounds such as butane will have a lower boiling point compared to butanol or other molecules with stronger bonds. Compounds with larger surface areas will exhibit stronger intermolecular forces and the bonds affect the solubility of compounds in water.
    • Organic molecules are soluble in water if they possess a polar functional group and/or a minimal number of carbon atoms. Compounds with only a small number of carbon atoms and higher concentrations of polar functional groups such as hydroxyl or carboxyl are soluble in water.
    • Solubility is affected by the "like dissolves like" principle. Polar substances tend to dissolve in polar solvents, and nonpolar substances dissolve in nonpolar solvents.
    • Hydrophobic portions of molecules are insoluble in water, whereas hydrophilic portions are soluble.
    • The size and shape of an organic molecule affect solubility characteristics and melting point characteristics. The more compact and symmetrical shape of a molecule tends to exhibit higher melting points and other solubility traits compared to those with more surface area or more chaotic structures.
    • Functional groups determine the reactivity of organic molecules. Electrons in molecules are attracted to electron-poor/electrophilic areas in a molecule.
    • Electrophilic sites have lower electron density.

    Homework Problems

    • Some homework problems are included in the chapter. Specifically, problems 3.12, 3.13, 3.15, 3.19, 3.20, 3.39, 3.50, 3.53, 3.57, and 3.58

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    Description

    Explore the fascinating world of organic molecules and their functional groups in this chapter. Learn about hydrocarbons, aromatic compounds, and the impact of functional groups on molecular properties. Understand how heteroatoms and intermolecular forces play a role in the characteristics of organic substances.

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