Biochemistry 2 - Carbohydrate Biochemistry
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Questions and Answers

What are the most abundant biomolecules in nature?

Carbohydrates

What is the general formula for simple monosaccharides?

(CH2O)n

What is the function group of aldoses?

  • Ketone
  • Carboxylic acid
  • Aldehyde (correct)
  • Amine
  • What is the function group of ketoses?

    <p>Ketone</p> Signup and view all the answers

    What is the name of the bond that joins monosaccharides together in oligosaccharides?

    <p>Glycosidic bond</p> Signup and view all the answers

    Polysaccharides are large polymers composed of many monosaccharides joined together by glycosidic bonds.

    <p>True</p> Signup and view all the answers

    What is the chemical formula for cellulose?

    <p>(C6H10O5)n</p> Signup and view all the answers

    What is the chemical formula for glycogen?

    <p>(C6H10O5)n</p> Signup and view all the answers

    What is the chemical formula for starch?

    <p>(C6H10O5)n</p> Signup and view all the answers

    What is the name of the carbohydrate that transports energy in plants?

    <p>Sucrose</p> Signup and view all the answers

    What is the name of the protein that is found in red blood cells and is responsible for carrying oxygen?

    <p>Hemoglobin</p> Signup and view all the answers

    The oxygen-hemoglobin dissociation curve shifts to the right when the affinity of hemoglobin for oxygen decreases.

    <p>True</p> Signup and view all the answers

    What are the three levels of protein organization?

    <p>Primary, secondary, tertiary</p> Signup and view all the answers

    What type of bond links amino acids together to form a polypeptide chain?

    <p>Peptide bond</p> Signup and view all the answers

    Which of the following is NOT a function of carbohydrates?

    <p>Genetic information storage</p> Signup and view all the answers

    Which of the following is a structural polysaccharide found in plant cell walls?

    <p>Cellulose</p> Signup and view all the answers

    Which of the following is a storage polysaccharide found in animals?

    <p>Glycogen</p> Signup and view all the answers

    What is the name of the molecule that is produced when an aldehyde or ketone reacts with an alcohol?

    <p>Hemiacetal or Hemiketal</p> Signup and view all the answers

    What is the name of the molecule that is formed when an amine reacts with a sugar?

    <p>Amino sugar</p> Signup and view all the answers

    What are the two main types of polysaccharides?

    <p>Homopolysaccharides and Heteropolysaccharides</p> Signup and view all the answers

    What is the name of the polysaccharide that is found in the exoskeletons of arthropods?

    <p>Chitin</p> Signup and view all the answers

    All monosaccharides have at least one chiral center.

    <p>False</p> Signup and view all the answers

    What is the name of the type of isomer that is a non-superimposable mirror image of another?

    <p>Enantiomer</p> Signup and view all the answers

    What is the name of the convention used to designate the absolute configuration of chiral centers in carbohydrates?

    <p>D/L system</p> Signup and view all the answers

    Most of the hexoses in living organisms are L-isomers.

    <p>False</p> Signup and view all the answers

    What is the name of the process by which monomers are joined together to form polymers?

    <p>Polymerization</p> Signup and view all the answers

    What is the name of the bond that joins amino acids together to form a polypeptide chain?

    <p>Peptide bond</p> Signup and view all the answers

    What is the name of the type of protein that is composed of a single polypeptide chain?

    <p>Monomeric protein</p> Signup and view all the answers

    What is the name of the type of protein that is composed of multiple polypeptide chains?

    <p>Multimeric protein</p> Signup and view all the answers

    What is the name of the type of protein that has a globular shape?

    <p>Globular protein</p> Signup and view all the answers

    What is the name of the type of protein that has a fibrous shape?

    <p>Fibrous protein</p> Signup and view all the answers

    What is the name of the type of enzyme that follows Michaelis-Menten kinetics?

    <p>Simple enzyme</p> Signup and view all the answers

    What is the name of the type of enzyme that does not exhibit Michaelis-Menten kinetics and has multiple binding sites?

    <p>Allosteric enzyme</p> Signup and view all the answers

    What does the Michaelis constant (Km) represent?

    <p>The substrate concentration at which the reaction velocity is half of the maximum velocity (Vmax)</p> Signup and view all the answers

    Allosteric enzymes can be activated or inhibited by allosteric effectors.

    <p>True</p> Signup and view all the answers

    What is the name of the type of molecule that is made up of a sugar and a non-sugar molecule?

    <p>Glycoconjugate</p> Signup and view all the answers

    What is the name of the type of glycoconjugate that is composed of an oligosaccharide linked to a lipid?

    <p>Glycolipid</p> Signup and view all the answers

    What is the name of the type of glycoconjugate that is composed of an oligosaccharide linked to a protein?

    <p>Glycoprotein</p> Signup and view all the answers

    What is the name of the type of molecule that is composed of a protein and a glycosaminoglycan?

    <p>Proteoglycan</p> Signup and view all the answers

    What is the name of the type of molecule that is composed of a sugar and a phosphate group?

    <p>Nucleotide</p> Signup and view all the answers

    The head of a phospholipid molecule is hydrophilic.

    <p>True</p> Signup and view all the answers

    The tail of a phospholipid molecule is hydrophilic.

    <p>False</p> Signup and view all the answers

    What is the name of the type of protein that spans the entire cell membrane?

    <p>Integral membrane protein</p> Signup and view all the answers

    What is the name of the type of protein that is attached to the surface of the cell membrane?

    <p>Peripheral membrane protein</p> Signup and view all the answers

    What is the name of the type of molecule that is composed of an oligosaccharide linked to a protein or lipid?

    <p>Glycoconjugate</p> Signup and view all the answers

    The glycosidic bond is a covalent bond that joins two monosaccharides together.

    <p>True</p> Signup and view all the answers

    What is the name of the type of molecule that is composed of a protein and a glycosaminoglycan?

    <p>Proteoglycan</p> Signup and view all the answers

    Glycosaminoglycans are highly negatively charged due to the presence of sulfate groups.

    <p>True</p> Signup and view all the answers

    Study Notes

    Biochemistry 2 - Carbohydrate Biochemistry

    • Carbohydrates (CHO) are the most abundant biomolecules in nature.
    • CHO are the product of photosynthesis: nCO2 + H2O → (CH2O)n + nO2 (light)
    • Originally thought to have the formula (CH2O)n, but only simple monosaccharides obey this rule.
    • Carbohydrates are polyhydroxy aldehydes or ketones or larger molecules that can be hydrolyzed to polyhydroxy aldehydes or ketones.

    Carbohydrate Objectives

    • Recognize the features and functions of different classes of carbohydrates.
    • Understand the concept of asymmetric carbons and other diastereoisomers, epimers, enantiomers, and anomers.
    • Recognize the structure of glucose and its relationship with other monosaccharides.
    • Understand the different reactions of monosaccharides.
    • Understand the nature of the glycosidic bond and recognize the structure of common disaccharides.
    • Recognize different types and classes of polysaccharides.
    • Understand the basic differences between amylose and cellulose.

    Functions of Carbohydrates

    • Energy source for plants and animals.
    • Source of carbon in metabolic processes.
    • Storage form of energy (starch, glycogen).
    • Structural elements of cells and tissues (cellulose).
    • Participate in recognition and adhesion between cells, mediating intercellular communication.

    Classification of Carbohydrates

    • Monosaccharides: single polyhydroxy aldehyde or ketone unit (e.g., glucose, most abundant).
    • Oligosaccharides: short chains of 2-20 monosaccharides joined by glycosidic bonds (e.g., sucrose).
    • Polysaccharides: chains of 20+ monosaccharides (linear or branched).
      • Storage polysaccharides (starch, glycogen).
      • Structural polysaccharides (cellulose, chitin).

    Monosaccharides

    • Backbone: unbranched carbon chains.
    • Colorless, crystalline, solid, soluble in water, insoluble in organic solvents.
    • Ketose: most oxidized functional group is a ketone.
    • Aldose: most oxidized functional group is an aldehyde.
    • Classified by the number of carbon atoms (triose, tetrose, pentose, hexose, etc.).
    • Simplest monosaccharides are 3 carbons; common monosaccharides are 6 carbons.
    • All monosaccharides (except dihydroxyacetone) have one or more asymmetric carbons.

    Stereoisomers and Enantiomers

    • Stereoisomers are non-superimposable mirror images.
    • Enantiomers are stereoisomers that are non-superimposable mirror images of each other.
    • By convention, one enantiomer is designated as the D-isomer, the other is the L-isomer, based on the configuration of the chiral center farthest from the carbonyl carbon.
    • In general, a molecule with n chiral centers can have 2^n stereoisomers.
    • Most hexoses in living organisms are D-isomers.

    Series of D-Ketoses

    • Have one less chiral center than aldoses.
    • C-4 and C-5 ketoses are designated by adding "ulose" to the name of their corresponding aldose. (e.g., D-ribulose is a ketopentose corresponding to D-ribose).

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    Test your knowledge on the structure, functions, and classifications of carbohydrates in this quiz. Explore important concepts such as asymmetric carbons, glycosidic bonds, and the relationships between different monosaccharides. Perfect for students studying biochemistry or related fields!

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