Podcast
Questions and Answers
What was stated in Dalton's atomic theory? (4)
What was stated in Dalton's atomic theory? (4)
Atoms are tiny particles made of elements. Atoms cannot be divided. All the atoms in an element are the same. Atoms of one element are different to those of other elements.
What did Thompson discover about electrons? (3)
What did Thompson discover about electrons? (3)
Electrons have a negative charge. Electrons can be deflected by electromagnetic fields. Electrons have very small mass.
Explain the current model of the atom.
Explain the current model of the atom.
Protons and neutrons are found in the nucleus. Electrons orbit the nucleus in shells. The nucleus is tiny compared to the total volume of the atom. Most of the atom's mass is in the nucleus. Most of the atom is empty space between the nucleus and the electrons.
What is the charge of a proton and an electron?
What is the charge of a proton and an electron?
Signup and view all the answers
Which particle has the same mass as a proton?
Which particle has the same mass as a proton?
Signup and view all the answers
Which two particles make up most of an atom's mass?
Which two particles make up most of an atom's mass?
Signup and view all the answers
What does the atomic number show about an element?
What does the atomic number show about an element?
Signup and view all the answers
How is mass number calculated?
How is mass number calculated?
Signup and view all the answers
How to calculate the number of neutrons?
How to calculate the number of neutrons?
Signup and view all the answers
Define the term, isotope.
Define the term, isotope.
Signup and view all the answers
Why do different isotopes of the same element react in the same way? (2)
Why do different isotopes of the same element react in the same way? (2)
Signup and view all the answers
Define relative atomic mass.
Define relative atomic mass.
Signup and view all the answers
The relative isotopic mass is the same as which number?
The relative isotopic mass is the same as which number?
Signup and view all the answers
What two assumptions are made when calculating mass number?
What two assumptions are made when calculating mass number?
Signup and view all the answers
How to calculate the relative molecular mass and relative formula mass?
How to calculate the relative molecular mass and relative formula mass?
Signup and view all the answers
What are the uses of mass spectrometry? (3)
What are the uses of mass spectrometry? (3)
Signup and view all the answers
What is the m/z value of the M+ ion?
What is the m/z value of the M+ ion?
Signup and view all the answers
The mass spectrum of a sample of tellurium is shown in ______ 1.
The mass spectrum of a sample of tellurium is shown in ______ 1.
Signup and view all the answers
Use Figure 1 to calculate the relative atomic mass of this sample of tellurium. Give your answer to one decimal place.
Use Figure 1 to calculate the relative atomic mass of this sample of tellurium. Give your answer to one decimal place.
Signup and view all the answers
What does the principal quantum number indicate?
What does the principal quantum number indicate?
Signup and view all the answers
What is a shell?
What is a shell?
Signup and view all the answers
How many electrons can the 1st shell hold?
How many electrons can the 1st shell hold?
Signup and view all the answers
What is an orbital?
What is an orbital?
Signup and view all the answers
How many electrons can an orbital hold?
How many electrons can an orbital hold?
Signup and view all the answers
What are the 4 types of orbitals?
What are the 4 types of orbitals?
Signup and view all the answers
What is the shape of a s-orbital?
What is the shape of a s-orbital?
Signup and view all the answers
How many orbitals are found in a S subshell?
How many orbitals are found in a S subshell?
Signup and view all the answers
How many electrons can be held in a S subshell?
How many electrons can be held in a S subshell?
Signup and view all the answers
How many orbitals does P subshell have?
How many orbitals does P subshell have?
Signup and view all the answers
How many orbitals are present in a D subshell?
How many orbitals are present in a D subshell?
Signup and view all the answers
How many electrons can fill F subshell?
How many electrons can fill F subshell?
Signup and view all the answers
When using ‘electrons in box’ representation, what shape is used to represent the electrons?
When using ‘electrons in box’ representation, what shape is used to represent the electrons?
Signup and view all the answers
What letter used to represent shell number?
What letter used to represent shell number?
Signup and view all the answers
From which shell onwards is S orbital present?
From which shell onwards is S orbital present?
Signup and view all the answers
What are the rules by which electrons are arranged in the shell? (5)
What are the rules by which electrons are arranged in the shell? (5)
Signup and view all the answers
Why does 4s orbital fill before 3d orbital?
Why does 4s orbital fill before 3d orbital?
Signup and view all the answers
What is the electron configuration of krypton?
What is the electron configuration of krypton?
Signup and view all the answers
How can the electron configuration be written in short?
How can the electron configuration be written in short?
Signup and view all the answers
How are the elements arranged in a periodic table?
How are the elements arranged in a periodic table?
Signup and view all the answers
How is the group number related to the number of electrons?
How is the group number related to the number of electrons?
Signup and view all the answers
What is a period on a periodic table?
What is a period on a periodic table?
Signup and view all the answers
Does the group number indicate horizontal or vertical columns in the periodic table?
Does the group number indicate horizontal or vertical columns in the periodic table?
Signup and view all the answers
What is meant by periodicity?
What is meant by periodicity?
Signup and view all the answers
What change happens across each period?
What change happens across each period?
Signup and view all the answers
Define first ionisation energy.
Define first ionisation energy.
Signup and view all the answers
Write an equation for the first ionisation energy of magnesium.
Write an equation for the first ionisation energy of magnesium.
Signup and view all the answers
What are the factors that affect ionisation energy?
What are the factors that affect ionisation energy?
Signup and view all the answers
Explain the trend on this graph.
Explain the trend on this graph.
Signup and view all the answers
Why does first ionisation energy decrease between group 2 to 3?
Why does first ionisation energy decrease between group 2 to 3?
Signup and view all the answers
Does first ionisation increase or decrease between the end of one period and the start of next? Why?
Does first ionisation increase or decrease between the end of one period and the start of next? Why?
Signup and view all the answers
Does first ionisation increase or decrease down a group? Why?
Does first ionisation increase or decrease down a group? Why?
Signup and view all the answers
Describe the structure, forces and bonding in every element across period 2.
Describe the structure, forces and bonding in every element across period 2.
Signup and view all the answers
Flashcards
Dalton's Atomic Theory
Dalton's Atomic Theory
Atoms are tiny particles, indivisible, and identical within elements.
Thompson's Electron Discovery
Thompson's Electron Discovery
Electrons have a negative charge, can be deflected, and are very light.
Current Atomic Model
Current Atomic Model
Nucleus contains protons and neutrons; electrons orbit in shells.
Charge of Proton and Electron
Charge of Proton and Electron
Signup and view all the flashcards
Mass Comparison
Mass Comparison
Signup and view all the flashcards
Atom's Mass Composition
Atom's Mass Composition
Signup and view all the flashcards
Atomic Number
Atomic Number
Signup and view all the flashcards
Mass Number Calculation
Mass Number Calculation
Signup and view all the flashcards
Neutron Count
Neutron Count
Signup and view all the flashcards
Isotope Definition
Isotope Definition
Signup and view all the flashcards
Reactivity of Isotopes
Reactivity of Isotopes
Signup and view all the flashcards
Relative Atomic Mass
Relative Atomic Mass
Signup and view all the flashcards
Relative Isotopic Mass
Relative Isotopic Mass
Signup and view all the flashcards
Mass Number vs Isotopic Mass
Mass Number vs Isotopic Mass
Signup and view all the flashcards
Calculating Mass Number Assumptions
Calculating Mass Number Assumptions
Signup and view all the flashcards
Relative Molecular Mass Calculation
Relative Molecular Mass Calculation
Signup and view all the flashcards
Uses of Mass Spectrometry
Uses of Mass Spectrometry
Signup and view all the flashcards
Principal Quantum Number
Principal Quantum Number
Signup and view all the flashcards
Shells in Atoms
Shells in Atoms
Signup and view all the flashcards
First Shell Electron Capacity
First Shell Electron Capacity
Signup and view all the flashcards
Second Shell Electron Capacity
Second Shell Electron Capacity
Signup and view all the flashcards
Third Shell Electron Capacity
Third Shell Electron Capacity
Signup and view all the flashcards
Orbital Definition
Orbital Definition
Signup and view all the flashcards
Types of Orbitals
Types of Orbitals
Signup and view all the flashcards
Electron Configuration Abbreviation
Electron Configuration Abbreviation
Signup and view all the flashcards
Periodic Table Arrangement
Periodic Table Arrangement
Signup and view all the flashcards
Group Number Significance
Group Number Significance
Signup and view all the flashcards
Study Notes
Dalton's Atomic Theory
- Atoms are tiny particles made of elements
- Atoms cannot be divided
- All atoms in an element are the same
- Atoms of one element are different to those of other elements
Thomson's Discoveries about Electrons
- Electrons have a negative charge
- Electrons can be deflected by electromagnetic fields
- Electrons have very small mass
Current Atomic Model
- Protons and neutrons are found in the nucleus
- Electrons orbit the nucleus in shells
- The nucleus is tiny compared to the total volume of the atom
- Most of an atom's mass is in the nucleus
- Most of the atom is empty space between the nucleus and the electrons
Charge of Proton and Electron
- Proton = +1
- Electron = -1
Particle with Same Mass as Proton
- Neutron
Particles Making up Most of an Atom's Mass
- Protons and neutrons
Atomic Number
- Atomic number = number of protons in an atom
Mass Number Calculation
- Mass number = number of protons + number of neutrons
Calculating Number of Neutrons
- Number of neutrons = mass number - atomic number
Isotope Definition
- Atoms of the same element with different numbers of neutrons and therefore different mass numbers
Isotope Reactivity
- Neutrons have no impact on chemical reactivity
- Reactions involve electrons; isotopes have the same number of electrons in the same arrangement
Relative Atomic Mass Definition
- The weighted mean mass of an atom of an element compared with one twelfth of the mass of an atom of carbon-12
Relative Isotopic Mass Definition
- The mass of an atom of an isotope compared with one twelfth of the mass of an atom of carbon-12
Relative Isotopic Mass and Mass Number
- Relative isotopic mass is the same as the mass number
Assumptions in Mass Number Calculation
- Contribution of the electron is neglected
- Mass of both proton and neutron is taken as 1.0 u
Relative Molecular/Formula Mass Calculation
- Both are calculated by adding the relative atomic masses of each atom making up the molecule or the formula
Mass Spectrometry Uses
- Identify unknown compounds
- Find relative abundance of each isotope of an element
- Determine structural information
M+ Ion m/z Value
- The m/z value of the M+ ion is the value of the last peak - 72
Calculation of Relative Atomic Mass from a Mass Spectrum
- Example calculation provided using data from a given mass spectrum
Principal Quantum Number
- The principal quantum number indicates the shell occupied by the electrons
Shell Definition
- A group of orbitals with the same principal quantum number
Number of Electrons in 1st Shell
- 2
Number of Electrons in 2nd Shell
- 8
Number of Electrons in 3rd Shell
- 18
Number of Electrons in 4th Shell
- 32
Orbital Definition
- A region around the nucleus that can hold up to two electrons with opposite spins
Number of Electrons per Orbital
- 2
Types of Orbitals
- s orbital
- p orbital
- d orbital
- f orbital
Shape of s Orbital
- Spherical
Shape of p Orbital
- Dumb-bell shape
Number of Orbitals in an s Subshell
- 1
Number of Electrons in an s Subshell
- 2
Number of Orbitals in a p Subshell
- 3
Number of Electrons in a p Subshell
- 6
Number of Orbitals in a d Subshell
- 5
Number of Electrons in a d Subshell
- 10
Number of Orbitals in an f Subshell
- 7
Number of Electrons that can Fill an f Subshell
- 14
Electron Representation in Box Diagrams
- Arrows are used to represent electrons
Letter Representing Shell Number
- n
Shell Where s Orbital is Present
- n=1
Shell Where p Orbital is Present
- n=2
Shell Where d Orbital is Present
- n=3
Shell Where f Orbital is Present
- n=4
Electron Arrangement Rules
- Electrons are added one at a time
- Lowest available energy level is filled first
- Each energy level must be filled before the next one can be filled
- Each orbital is filled singly before pairing
- 4s is filled before 3d
Why 4s Orbital Fills Before 3d Orbital
- 4s orbital has a lower energy than 3d orbital before it is filled
Electron Configuration of Krypton
- 1s22s22p63s23p64s23d104p6
Shortening Electron Configuration
- The noble gas before the element is used to abbreviate
Periodic Table Arrangement of Elements
- Elements are arranged in the increasing order of atomic numbers
Group Number Relationship to Outer Shell Electrons
- Group number = number of electrons in the outer shell
Period Definition
- The horizontal rows
Group Definition
- The vertical columns
Periodicity Definition
- Repeating trends in chemical and physical properties
Change Across Each Period
- Elements change from metals to non-metals
First Ionisation Energy Definition
- The energy required to remove a mole of electrons from a mole of gaseous atoms to form one mole of gaseous 1+ ions under standard conditions
First Ionisation Energy Equation for Magnesium
- Mg(g) → Mg+(g) + e-
Factors Affecting Ionisation Energy
- Atomic radius
- Nuclear charge
- Electron shielding/screening
Trend in Ionisation Energy Across Period 3
- First ionisation energy increases across period 3 because of increased nuclear charge and decreased atomic radius
- Same electron shielding is needed to remove the first electron
- Dips at Al because the outer electron is in a 3p orbital, higher energy than 3s orbital
- Dips at S because one 3p orbital contains two electrons causing repulsion between paired electrons, requiring less energy to remove one
Ionisation Energy Decrease Between Group 2 and 3
- Decreases between 2 and 3 because in group 3 the outermost electrons are in p orbitals; whereas in group 2 they are in s orbitals, so the electrons are easier to be removed
Ionisation Energy Decrease Between Group 5 and 6
- Decrease between 5 and 6 because group 5 electrons in p orbitals are single electrons
- In group 6, outermost electrons are spin paired, exhibiting some repulsion
- Therefore electrons are slightly easier to remove
Ionisation Energy Between Periods
- Decreases between the end of one period and the start of the next; due to:
- Increase in atomic radius
- Increase in electron shielding
Ionisation Energy Down a Group
- Decreases down a group; due to:
- Shielding increases, resulting in weaker attraction
- Atomic radius increases, increasing distance between outer electrons and nucleus, which gives weaker attraction
- Increase the number of protons is outweighed by increased distance and shielding
Structure, Forces, and Bonding Across Period 2
- Li and Be are giant metallic with strong attraction between positive ions and delocalized electrons (metallic bonding).
- B and C are giant covalent with strong forces between atoms (covalent).
- N2, O2, F2, and Ne are simple molecular with weak intermolecular forces between molecules and covalent bonding within the molecules.
Structure, Forces, and Bonding Across Period 3
- Na, Mg, and Al are giant metallic with strong attraction between positive ions and delocalized electrons (metallic bonding).
- Si is giant covalent with strong forces between atoms (covalent).
- P4, S8, Cl2, and Ar are simple molecular with weak intermolecular forces and covalent bonding within the molecules.
Studying That Suits You
Use AI to generate personalized quizzes and flashcards to suit your learning preferences.
Related Documents
Description
Test your knowledge on Dalton's Atomic Theory, Thomson's discoveries, and the current atomic model. Explore fundamental concepts such as atomic number, mass number, and particle charges. Perfect for students studying chemistry and physics.