Atomic Theory and Structure Quiz
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Questions and Answers

What was stated in Dalton's atomic theory? (4)

Atoms are tiny particles made of elements. Atoms cannot be divided. All the atoms in an element are the same. Atoms of one element are different to those of other elements.

What did Thompson discover about electrons? (3)

Electrons have a negative charge. Electrons can be deflected by electromagnetic fields. Electrons have very small mass.

Explain the current model of the atom.

Protons and neutrons are found in the nucleus. Electrons orbit the nucleus in shells. The nucleus is tiny compared to the total volume of the atom. Most of the atom's mass is in the nucleus. Most of the atom is empty space between the nucleus and the electrons.

What is the charge of a proton and an electron?

<p>Proton = +1, Electron = -1</p> Signup and view all the answers

Which particle has the same mass as a proton?

<p>Neutron</p> Signup and view all the answers

Which two particles make up most of an atom's mass?

<p>Protons and neutrons</p> Signup and view all the answers

What does the atomic number show about an element?

<p>The atomic number is equal to the number of protons in an atom.</p> Signup and view all the answers

How is mass number calculated?

<p>Mass number = number of protons + number of neutrons</p> Signup and view all the answers

How to calculate the number of neutrons?

<p>Number of neutrons = mass number - atomic number</p> Signup and view all the answers

Define the term, isotope.

<p>Atoms of the same element with different numbers of neutrons and therefore different mass numbers.</p> Signup and view all the answers

Why do different isotopes of the same element react in the same way? (2)

<p>Neutrons have no impact on the chemical reactivity. Reactions involve electrons, isotopes have the same number of electrons in the same arrangement.</p> Signup and view all the answers

Define relative atomic mass.

<p>The weighted mean mass of an atom of an element compared with one twelfth of the mass of an atom of carbon-12.</p> Signup and view all the answers

The relative isotopic mass is the same as which number?

<p>Mass number</p> Signup and view all the answers

What two assumptions are made when calculating mass number?

<p>Contribution of the electron is neglected. Mass of both proton and neutron is taken as 1.0 u.</p> Signup and view all the answers

How to calculate the relative molecular mass and relative formula mass?

<p>Both can be calculated by adding the relative atomic masses of each of the atoms making up the molecule or the formula.</p> Signup and view all the answers

What are the uses of mass spectrometry? (3)

<p>Identify unknown compounds. Find relative abundance of each isotope of an element. Determine structural information.</p> Signup and view all the answers

What is the m/z value of the M+ ion?

<p>The m/z value of the M+ ion is the value of the last peak - 72</p> Signup and view all the answers

The mass spectrum of a sample of tellurium is shown in ______ 1.

<p>Figure</p> Signup and view all the answers

Use Figure 1 to calculate the relative atomic mass of this sample of tellurium. Give your answer to one decimal place.

<p>(124 x 2) + (126 x 4) + (128 x 7) + (130 x 6) or 2428/19 or 127.8 or (124 x 10.5) + (126 x 21.1) + (128 x 36.8) + (130 x 31.6) or 2428/19 or 127.8</p> Signup and view all the answers

What does the principal quantum number indicate?

<p>The shell occupied by the electrons.</p> Signup and view all the answers

What is a shell?

<p>A group of orbitals with the same principal quantum number.</p> Signup and view all the answers

How many electrons can the 1st shell hold?

<p>2</p> Signup and view all the answers

What is an orbital?

<p>A region around the nucleus that can hold up to two electrons with opposite spins</p> Signup and view all the answers

How many electrons can an orbital hold?

<p>2</p> Signup and view all the answers

What are the 4 types of orbitals?

<p>s orbital, p orbital, d orbital, f orbital</p> Signup and view all the answers

What is the shape of a s-orbital?

<p>Spherical</p> Signup and view all the answers

How many orbitals are found in a S subshell?

<p>1</p> Signup and view all the answers

How many electrons can be held in a S subshell?

<p>2</p> Signup and view all the answers

How many orbitals does P subshell have?

<p>3</p> Signup and view all the answers

How many orbitals are present in a D subshell?

<p>5</p> Signup and view all the answers

How many electrons can fill F subshell?

<p>14</p> Signup and view all the answers

When using ‘electrons in box’ representation, what shape is used to represent the electrons?

<p>Arrows</p> Signup and view all the answers

What letter used to represent shell number?

<p>n</p> Signup and view all the answers

From which shell onwards is S orbital present?

<p>n = 1</p> Signup and view all the answers

What are the rules by which electrons are arranged in the shell? (5)

<p>Electrons are added one at a time. Lowest available energy level is filled first. Each energy level must be filled before the next one can fill. Each orbital is filled singly before pairing. 4s is filled before 3d.</p> Signup and view all the answers

Why does 4s orbital fill before 3d orbital?

<p>The 4s orbital has a lower energy than the 3d orbital before it is filled.</p> Signup and view all the answers

What is the electron configuration of krypton?

<p>1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6</p> Signup and view all the answers

How can the electron configuration be written in short?

<p>The noble gas before the element is used to abbreviate. E.g Li → 1s22s1 ; Li → [He] 2s1</p> Signup and view all the answers

How are the elements arranged in a periodic table?

<p>They are arranged in the order of increasing atomic numbers.</p> Signup and view all the answers

How is the group number related to the number of electrons?

<p>The group number is equal to the number of electrons in the outer shell.</p> Signup and view all the answers

What is a period on a periodic table?

<p>The horizontal rows.</p> Signup and view all the answers

Does the group number indicate horizontal or vertical columns in the periodic table?

<p>True (A)</p> Signup and view all the answers

What is meant by periodicity?

<p>The repeating trends in chemical and physical properties.</p> Signup and view all the answers

What change happens across each period?

<p>Elements change from metals to non-metals.</p> Signup and view all the answers

Define first ionisation energy.

<p>The energy required to remove a mole of electrons from a mole of gaseous atoms to form one mole of gaseous 1+ ions under standard conditions.</p> Signup and view all the answers

Write an equation for the first ionisation energy of magnesium.

<p>Mg(g) → Mg+(g) + e-</p> Signup and view all the answers

What are the factors that affect ionisation energy?

<p>Atomic radius, Nuclear charge, Electron shielding or screening</p> Signup and view all the answers

Explain the trend on this graph.

<p>First Ionisation energy increases across a period because of: Increased nuclear charge. Decreased atomic radius. Same electron shielding. This means more energy is needed to remove the first electron. Dips at Al because: outer electron is in a 3p orbital, higher energy than 3s orbital → less energy needed to remove electron. Dips at S because one 3p orbital contains two electrons → repulsion between paired electrons → less energy needed to remove one.</p> Signup and view all the answers

Why does first ionisation energy decrease between group 2 to 3?

<p>Decreases between 2 to 3 because in group 3 the outermost electrons are in p orbitals. Whereas in group 2 they are in s orbital, so the electrons are easier to be removed.</p> Signup and view all the answers

Does first ionisation increase or decrease between the end of one period and the start of next? Why?

<p>Decrease. There is an increase in atomic radius. Increase in electron shielding.</p> Signup and view all the answers

Does first ionisation increase or decrease down a group? Why?

<p>Decrease. Shielding increases → weaker attraction. Atomic radius increases → distance between the outer electrons and nucleus increases → weaker attraction. Increase in number of protons is outweighed by increase in distance and shielding.</p> Signup and view all the answers

Describe the structure, forces and bonding in every element across period 2.

<p>Li &amp; Be → giant metallic ; strong attraction between positive ions and delocalised electrons ; metallic bonding. B &amp; C → giant covalent ; strong forces between atoms ; covalent. N2, O2, F2, Ne → simple molecular ; weak intermolecular forces between molecules ; covalent bonding within molecules and intermolecular forces between molecules.</p> Signup and view all the answers

Flashcards

Dalton's Atomic Theory

Atoms are tiny particles, indivisible, and identical within elements.

Thompson's Electron Discovery

Electrons have a negative charge, can be deflected, and are very light.

Current Atomic Model

Nucleus contains protons and neutrons; electrons orbit in shells.

Charge of Proton and Electron

Proton = +1 charge; Electron = -1 charge.

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Mass Comparison

Neutrons and protons have roughly the same mass.

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Atom's Mass Composition

Most mass comes from protons and neutrons.

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Atomic Number

Determines the number of protons in an atom.

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Mass Number Calculation

Mass number = number of protons + neutrons.

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Neutron Count

Calculate neutrons: Neutrons = mass number - atomic number.

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Isotope Definition

Atoms of the same element with differing neutron numbers.

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Reactivity of Isotopes

Different isotopes react similarly due to same electron arrangement.

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Relative Atomic Mass

Weighted average mass of an element’s atoms compared to carbon-12.

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Relative Isotopic Mass

Mass of a specific isotope relative to carbon-12.

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Mass Number vs Isotopic Mass

Relative isotopic mass equals the mass number of an isotope.

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Calculating Mass Number Assumptions

Neglect electron mass; consider protons and neutrons as 1.0 u each.

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Relative Molecular Mass Calculation

Sum of relative atomic masses of all atoms in the molecule.

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Uses of Mass Spectrometry

Identify compounds, measure isotope abundance, and understand structures.

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Principal Quantum Number

Indicates the electron shell occupied by electrons.

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Shells in Atoms

Groups of orbitals with the same principal quantum number.

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First Shell Electron Capacity

The first shell can hold 2 electrons.

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Second Shell Electron Capacity

The second shell can hold 8 electrons.

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Third Shell Electron Capacity

The third shell can hold 18 electrons.

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Orbital Definition

Region where up to two electrons with opposite spins can exist.

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Types of Orbitals

s, p, d, and f orbitals, each with distinct shapes.

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Electron Configuration Abbreviation

Using the last noble gas to simplify electron configuration.

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Periodic Table Arrangement

Elements arranged by increasing atomic number and grouped by properties.

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Group Number Significance

Group number indicates the number of outer shell electrons.

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Study Notes

Dalton's Atomic Theory

  • Atoms are tiny particles made of elements
  • Atoms cannot be divided
  • All atoms in an element are the same
  • Atoms of one element are different to those of other elements

Thomson's Discoveries about Electrons

  • Electrons have a negative charge
  • Electrons can be deflected by electromagnetic fields
  • Electrons have very small mass

Current Atomic Model

  • Protons and neutrons are found in the nucleus
  • Electrons orbit the nucleus in shells
  • The nucleus is tiny compared to the total volume of the atom
  • Most of an atom's mass is in the nucleus
  • Most of the atom is empty space between the nucleus and the electrons

Charge of Proton and Electron

  • Proton = +1
  • Electron = -1

Particle with Same Mass as Proton

  • Neutron

Particles Making up Most of an Atom's Mass

  • Protons and neutrons

Atomic Number

  • Atomic number = number of protons in an atom

Mass Number Calculation

  • Mass number = number of protons + number of neutrons

Calculating Number of Neutrons

  • Number of neutrons = mass number - atomic number

Isotope Definition

  • Atoms of the same element with different numbers of neutrons and therefore different mass numbers

Isotope Reactivity

  • Neutrons have no impact on chemical reactivity
  • Reactions involve electrons; isotopes have the same number of electrons in the same arrangement

Relative Atomic Mass Definition

  • The weighted mean mass of an atom of an element compared with one twelfth of the mass of an atom of carbon-12

Relative Isotopic Mass Definition

  • The mass of an atom of an isotope compared with one twelfth of the mass of an atom of carbon-12

Relative Isotopic Mass and Mass Number

  • Relative isotopic mass is the same as the mass number

Assumptions in Mass Number Calculation

  • Contribution of the electron is neglected
  • Mass of both proton and neutron is taken as 1.0 u

Relative Molecular/Formula Mass Calculation

  • Both are calculated by adding the relative atomic masses of each atom making up the molecule or the formula

Mass Spectrometry Uses

  • Identify unknown compounds
  • Find relative abundance of each isotope of an element
  • Determine structural information

M+ Ion m/z Value

  • The m/z value of the M+ ion is the value of the last peak - 72

Calculation of Relative Atomic Mass from a Mass Spectrum

  • Example calculation provided using data from a given mass spectrum

Principal Quantum Number

  • The principal quantum number indicates the shell occupied by the electrons

Shell Definition

  • A group of orbitals with the same principal quantum number

Number of Electrons in 1st Shell

  • 2

Number of Electrons in 2nd Shell

  • 8

Number of Electrons in 3rd Shell

  • 18

Number of Electrons in 4th Shell

  • 32

Orbital Definition

  • A region around the nucleus that can hold up to two electrons with opposite spins

Number of Electrons per Orbital

  • 2

Types of Orbitals

  • s orbital
  • p orbital
  • d orbital
  • f orbital

Shape of s Orbital

  • Spherical

Shape of p Orbital

  • Dumb-bell shape

Number of Orbitals in an s Subshell

  • 1

Number of Electrons in an s Subshell

  • 2

Number of Orbitals in a p Subshell

  • 3

Number of Electrons in a p Subshell

  • 6

Number of Orbitals in a d Subshell

  • 5

Number of Electrons in a d Subshell

  • 10

Number of Orbitals in an f Subshell

  • 7

Number of Electrons that can Fill an f Subshell

  • 14

Electron Representation in Box Diagrams

  • Arrows are used to represent electrons

Letter Representing Shell Number

  • n

Shell Where s Orbital is Present

  • n=1

Shell Where p Orbital is Present

  • n=2

Shell Where d Orbital is Present

  • n=3

Shell Where f Orbital is Present

  • n=4

Electron Arrangement Rules

  • Electrons are added one at a time
  • Lowest available energy level is filled first
  • Each energy level must be filled before the next one can be filled
  • Each orbital is filled singly before pairing
  • 4s is filled before 3d

Why 4s Orbital Fills Before 3d Orbital

  • 4s orbital has a lower energy than 3d orbital before it is filled

Electron Configuration of Krypton

  • 1s22s22p63s23p64s23d104p6

Shortening Electron Configuration

  • The noble gas before the element is used to abbreviate

Periodic Table Arrangement of Elements

  • Elements are arranged in the increasing order of atomic numbers

Group Number Relationship to Outer Shell Electrons

  • Group number = number of electrons in the outer shell

Period Definition

  • The horizontal rows

Group Definition

  • The vertical columns

Periodicity Definition

  • Repeating trends in chemical and physical properties

Change Across Each Period

  • Elements change from metals to non-metals

First Ionisation Energy Definition

  • The energy required to remove a mole of electrons from a mole of gaseous atoms to form one mole of gaseous 1+ ions under standard conditions

First Ionisation Energy Equation for Magnesium

  • Mg(g) → Mg+(g) + e-

Factors Affecting Ionisation Energy

  • Atomic radius
  • Nuclear charge
  • Electron shielding/screening

Trend in Ionisation Energy Across Period 3

  • First ionisation energy increases across period 3 because of increased nuclear charge and decreased atomic radius
  • Same electron shielding is needed to remove the first electron
  • Dips at Al because the outer electron is in a 3p orbital, higher energy than 3s orbital
  • Dips at S because one 3p orbital contains two electrons causing repulsion between paired electrons, requiring less energy to remove one

Ionisation Energy Decrease Between Group 2 and 3

  • Decreases between 2 and 3 because in group 3 the outermost electrons are in p orbitals; whereas in group 2 they are in s orbitals, so the electrons are easier to be removed

Ionisation Energy Decrease Between Group 5 and 6

  • Decrease between 5 and 6 because group 5 electrons in p orbitals are single electrons
  • In group 6, outermost electrons are spin paired, exhibiting some repulsion
  • Therefore electrons are slightly easier to remove

Ionisation Energy Between Periods

  • Decreases between the end of one period and the start of the next; due to:
  • Increase in atomic radius
  • Increase in electron shielding

Ionisation Energy Down a Group

  • Decreases down a group; due to:
  • Shielding increases, resulting in weaker attraction
  • Atomic radius increases, increasing distance between outer electrons and nucleus, which gives weaker attraction
  • Increase the number of protons is outweighed by increased distance and shielding

Structure, Forces, and Bonding Across Period 2

  • Li and Be are giant metallic with strong attraction between positive ions and delocalized electrons (metallic bonding).
  • B and C are giant covalent with strong forces between atoms (covalent).
  • N2, O2, F2, and Ne are simple molecular with weak intermolecular forces between molecules and covalent bonding within the molecules.

Structure, Forces, and Bonding Across Period 3

  • Na, Mg, and Al are giant metallic with strong attraction between positive ions and delocalized electrons (metallic bonding).
  • Si is giant covalent with strong forces between atoms (covalent).
  • P4, S8, Cl2, and Ar are simple molecular with weak intermolecular forces and covalent bonding within the molecules.

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Test your knowledge on Dalton's Atomic Theory, Thomson's discoveries, and the current atomic model. Explore fundamental concepts such as atomic number, mass number, and particle charges. Perfect for students studying chemistry and physics.

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