Atomic Structure & Theories

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Questions and Answers

Which statement accurately describes alpha rays?

  • They consist of positively charged protons and neutrons. (correct)
  • They are unaffected by external electric fields.
  • They consist of high energy rays similar to X rays.
  • They consist of negatively charged particles called electrons.

What does the atomic number of an element represent?

  • The sum of neutrons and protons in the atom.
  • The total number of protons present in the atom. (correct)
  • The total number of neutrons in the nucleus.
  • The charge of the atom overall.

How is the mass number defined?

  • It is the sum of the protons and electrons in the atom.
  • It is the number of electrons present in the atom.
  • It is the total number of protons and neutrons in the nucleus. (correct)
  • It is equal to the atomic number minus the number of neutrons.

Which of the following statements about beta rays is true?

<p>Beta rays consist of negatively charged particles. (A)</p> Signup and view all the answers

In atomic notation, what do the superscript and subscript denote?

<p>Superscript denotes mass number and subscript denotes atomic number. (B)</p> Signup and view all the answers

What happens when there is no subscript shown next to an element's symbol?

<p>The atomic number can be deduced from the element's symbol or name. (D)</p> Signup and view all the answers

Which of the following describes gamma rays?

<p>Gamma rays are a type of high energy electromagnetic radiation. (D)</p> Signup and view all the answers

Which characteristic is true about the electrons in an atom?

<p>Electrons carry a negative charge and their mass is negligible. (C)</p> Signup and view all the answers

What significant concept did Democritus introduce regarding matter?

<p>Matter consists of indivisible particles called atoms. (D)</p> Signup and view all the answers

What was a key limitation of John Dalton's atomic theory?

<p>He considered atoms to be indivisible. (A)</p> Signup and view all the answers

Which statement correctly describes Rutherford's atomic model?

<p>Positive charge is concentrated in a nucleus. (B)</p> Signup and view all the answers

What major advancement did Niels Bohr's model introduce?

<p>Electrons have fixed orbits with defined energies. (D)</p> Signup and view all the answers

What was a significant flaw identified in J.J. Thomson's atomic model?

<p>Moving electrons could not maintain stable orbits. (B)</p> Signup and view all the answers

Which of the following is true about atomic elements according to these theories?

<p>Atoms of a particular element differ from those of other elements. (B)</p> Signup and view all the answers

What important concept was missing from Dalton's understanding of atoms?

<p>Atoms consist of subatomic particles. (A)</p> Signup and view all the answers

What assumption did Bohr's model correct about electron behavior?

<p>Electrons do not emit energy when in stable orbits. (C)</p> Signup and view all the answers

What distinguishes a cation from an anion?

<p>Cations have a net positive charge, whereas anions have a net negative charge. (D)</p> Signup and view all the answers

Which of the following best defines a diatomic molecule?

<p>A molecule that contains two atoms of the same element. (D)</p> Signup and view all the answers

Which of the following statements about polyatomic ions is correct?

<p>Polyatomic ions can consist of multiple atoms bonded together with an overall positive or negative charge. (B)</p> Signup and view all the answers

What characterizes molecules in terms of their atomic composition?

<p>Molecules are aggregates of at least two atoms held together by chemical bonds. (C)</p> Signup and view all the answers

In terms of electron transfer, which statement about ionic bonding is true?

<p>Ionic bonding results from the attraction between cations and anions formed by the transfer of electrons. (A)</p> Signup and view all the answers

Which of the following is an example of a polyatomic molecule?

<p>H2O (A)</p> Signup and view all the answers

What is the main factor that defines an ionic compound?

<p>Ionic compounds are formed from cations and anions through electron transfer. (A)</p> Signup and view all the answers

Which of the following ions represents a cation?

<p>Na+ (A)</p> Signup and view all the answers

What is the relationship between moles and the number of atoms in a substance?

<p>1 mole contains 6.022 x 10^23 atoms. (D)</p> Signup and view all the answers

Which of the following statements about hydrates is incorrect?

<p>Hydrates are only ionic compounds. (B)</p> Signup and view all the answers

Which category best describes a metalloid?

<p>Intermediate properties between metals and nonmetals. (A)</p> Signup and view all the answers

How is the molar mass of a substance defined?

<p>Mass in grams of one mole of a substance. (B)</p> Signup and view all the answers

Which property is NOT characteristic of alkali metals?

<p>High melting and boiling points. (A)</p> Signup and view all the answers

What is the significance of the number 6.022 x 10^23 in chemistry?

<p>It indicates the number of entities in one mole of a substance. (C)</p> Signup and view all the answers

Which formula correctly represents the conversion between moles and the number of molecules?

<p>Number of molecules = 6.022 x moles. (C)</p> Signup and view all the answers

Which of the following compounds is classified as a hydrate?

<p>Hydrated Copper Sulfate (CuSO4·5H2O) (A)</p> Signup and view all the answers

What is ionization energy primarily dependent on?

<p>The outermost electron's distance from the nucleus (D)</p> Signup and view all the answers

How does ionization energy trend across a period from left to right?

<p>It increases (A)</p> Signup and view all the answers

Which of the following statements about electron affinity is correct?

<p>It decreases as you move down a group (C)</p> Signup and view all the answers

What is the effect of increasing nuclear charge on ionization energy?

<p>It increases the energy required to remove an electron (B)</p> Signup and view all the answers

What concept does electron configuration help with regarding elements?

<p>Predicting the properties of a group of elements (C)</p> Signup and view all the answers

During successive ionization of an element, what trend is observed?

<p>Each ionization requires more energy than the last (C)</p> Signup and view all the answers

Which characteristic of the elements is associated with low boiling points and low melting points?

<p>Being colorless and odorless (C)</p> Signup and view all the answers

How is energy change expressed when an atom gains an electron?

<p>As a negative number (D)</p> Signup and view all the answers

Which characteristic is NOT typical of alkaline earth metals?

<p>High melting points (B)</p> Signup and view all the answers

What defines lanthanides in terms of their valence electrons?

<p>Contain one valence electron in the 5d shell (C)</p> Signup and view all the answers

Which statement about actinides is correct?

<p>They exhibit high electropositivity. (D)</p> Signup and view all the answers

How are metalloids characterized in terms of conductivity?

<p>Semiconductors at high temperatures (C)</p> Signup and view all the answers

What is a common feature of transition metals?

<p>Typically have low ionization energies (C)</p> Signup and view all the answers

What property is associated with nonmetals?

<p>High ionization energies (C)</p> Signup and view all the answers

What aspect of atomic radius is correctly defined?

<p>Distance between nuclei of two identical atoms bonded together (C)</p> Signup and view all the answers

Which of the following describes post-transition metals?

<p>Solid at standard temperature and high density (A)</p> Signup and view all the answers

Which characteristic differentiates metals from metalloids?

<p>Metals are good conductors (D)</p> Signup and view all the answers

Which of the following statements does NOT apply to alkali metals?

<p>They contain multiple valence electrons. (D)</p> Signup and view all the answers

Flashcards

Democritus' atom concept

Ancient Greek philosopher who first proposed that matter was composed of indivisible particles called 'atomos'.

Dalton's Atomic Theory

Elements are made of atoms, atoms of an element are identical, atoms of different elements combine to form compounds, and chemical reactions rearrange atoms.

Plum Pudding Model

J.J. Thomson's model of the atom, picturing a sphere of positive charge with negatively charged electrons embedded.

Rutherford's Nuclear Model

Rutherford discovered that the atom's positive charge and most of its mass are concentrated in a tiny, dense nucleus.

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Bohr Model

Niels Bohr proposed that electrons orbit the nucleus in fixed energy levels.

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Atomic Nucleus

The central, dense part of an atom, containing protons and neutrons.

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Subatomic Particles

Particles smaller than an atom, such as protons, neutrons, and electrons that make up an atom.

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Atomic Mass Unit

A very small unit of mass used to describe the mass of atoms and subatomic particles (e.g., protons, neutrons).

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Alpha Rays (α particles)

Positively charged particles consisting of protons.

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Beta Rays (β particles)

Negatively charged particles consisting of electrons.

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Gamma Rays (γ particles)

High-energy rays with no charge.

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Atomic Number (Z)

The number of protons in an atom's nucleus.

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Mass Number (A)

The total number of protons and neutrons in an atom's nucleus.

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Electron Charge

A negative charge, approximately -1.602 x 10^-19 Coulombs.

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Electron Mass

Negligibly small compared to proton and neutron masses

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Proton Charge

A positive charge, approximately +1.602 x 10^-19 Coulombs.

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Law of Definite Proportions

A chemical compound always contains the same elements in the same proportions by mass, regardless of its source or method of preparation.

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What is a molecule?

A group of two or more atoms held together by chemical bonds. These atoms can be of the same element or different elements.

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Diatomic Molecule

A molecule composed of only two atoms. These atoms can be the same element or different elements.

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Polyatomic Molecule

A molecule composed of more than two atoms, which can be combinations of two or more different elements.

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Cation

An ion with a positive charge, formed when a neutral atom loses one or more electrons.

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Anion

An ion with a negative charge, formed when a neutral atom gains one or more electrons.

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Monoatomic Ion

An ion containing only one atom, formed by the loss or gain of electrons from a neutral atom.

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Polyatomic Ion

An ion composed of two or more atoms, where these atoms combine to form a unit with a net positive or negative charge.

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Hydrate

A compound that has a specific number of water molecules attached to it.

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Naming Hydrates

Follow the general rules of chemical compound naming, and use prefixes for the number of water molecules.

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Mole Concept

A unit used for extremely large numbers of particles, like atoms or molecules.

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Avogadro's Number

The number of particles in one mole, approximately 6.022 × 10^23.

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Molar Mass

The mass in grams of one mole of a substance.

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Periodic Table

A chart organizing elements by their properties and atomic number.

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Metals

Elements that are good conductors of heat and electricity.

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Non-metals

Elements that are poor conductors of heat and electricity.

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Periods

Horizontal rows on the periodic table organized by increasing atomic number, representing the number of electron orbitals.

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Groups/Families

Vertical columns on the periodic table organized by similar chemical properties, indicating the same number of valence electrons.

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Alkaline Earth Metals

Group 2 elements, known for being reactive, good conductors, having a low density, and readily losing two electrons in reactions.

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Transition Metals

Groups 3-11 elements, characterized by multiple oxidation states, high conductivity, metallic properties, and often form colorful compounds.

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Lanthanides

Rare earth metals with one valence electron in the 5d shell, known for their high reactivity and silvery appearance.

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Actinides

Rare earth metals, highly reactive, radioactive, and exhibit paramagnetic, pyromorphic, and allotropic properties.

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Metalloids

Elements with properties of both metals and nonmetals, like semiconductors and brittle.

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Atomic Radius

The distance between the nuclei of two bonded identical atoms, representing the size of an atom.

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What is the relationship between periods and electron orbitals?

Elements within the same period share the same number of electron orbitals, increasing as you move down the periodic table.

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Ionization Energy

The minimum amount of energy required to remove the outermost electron from a neutral, gaseous atom in its ground state.

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Electron Affinity

The energy change that occurs when a neutral atom in the gaseous state gains an electron.

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Periodic Trend: Ionization Energy

Ionization energy generally increases across a period and decreases down a group on the periodic table.

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Periodic Trend: Electron Affinity

Electron affinity generally increases across a period and decreases down a group on the periodic table.

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Electron Configuration

Describes the arrangement of electrons in the energy levels and orbitals of an atom.

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Uses of Electron Configuration

Electron configuration is used to determine valency, predict properties of elements, and interpret atomic spectra.

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1st Ionization Energy

The energy required to remove the first electron from a neutral atom.

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Successive Ionization Energies

The energy required to remove subsequent electrons from an ion.

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Study Notes

Atomic Structure & Theories

  • Democritus (15th Century BC): coined the term "atomos" meaning "uncuttable" or "indivisible". Believed all matter is composed of tiny indivisible particles.

  • John Dalton (1808): proposed that atoms are indivisible building blocks of matter; elements are composed of extremely small particles; all atoms of a given element are identical; atoms of one element differ from others; chemical reactions involve rearrangement of atoms.

  • J.J. Thomson (1898): proposed the plum pudding model, where positive charge is uniformly distributed within a sphere, with negatively charged particles (electrons) embedded inside.

  • Ernest Rutherford (1911): proposed the nuclear model, where most of the atom's mass and positive charge are concentrated in a small nucleus, and electrons orbit around it. Electrons should emit energy and collapse into the nucleus. Did not work well for heavier atoms.

  • Erwin Schrodinger (1926): proposed the quantum model, suggesting electrons do not move in fixed orbits but in clouds where their location is uncertain. This is widely accepted as the most accurate model.

Subatomic Particles

  • Electron: negatively charged particle with negligible mass. Charge: -1e
  • Proton: positively charged particle. Charge: +1e, Mass: 1.672 x 10-19
  • Neutron: electrically neutral particle; nearly equal in mass to a proton.

Atomic Structure

  • Atomic number (Z): number of protons in an atom.
  • Mass number (A): total number of protons and neutrons in an atom
  • Isotopes: atoms of the same element with different mass numbers (same number of protons but different number of neutrons).
  • Atomic mass unit (amu): 1/12 the mass of a carbon-12 atom.

Basic Laws of Matter

  • Law of Conservation of Mass: Mass cannot be created or destroyed in a chemical reaction.
  • Law of Definite Proportions: A given compound always contains the same elements in the same proportion by mass.
  • Law of Multiple Proportions: If two elements combine to form more than one compound, the masses of one element that combine with a fixed mass of the other element are in ratios of small whole numbers.

Molecules

  • Molecule: an aggregate of at least two atoms held together by chemical forces/bonds.
  • Diatomic molecule: a molecule containing only two atoms, which can be of the same or different elements. (e.g., H2, O2).
  • Polyatomic molecule: a molecule containing more than two atoms.

Ions

  • Ion: an atom or group of atoms with a net positive or negative charge (due to loss or gain of electrons).
  • Cation: a positive ion (loss of electrons).
  • Anion: a negative ion (gain of electrons).

Ionic Compounds and Molecular Compounds

  • Ionic compounds: compounds formed from the electrostatic attraction between cations and anions.
  • Molecular compounds: compounds formed by the sharing of electrons between atoms (covalent bonding).

Chemical Formulas

  • Chemical formula: used to express the composition of molecules and ionic compounds in terms of chemical symbols.
  • Molecular formula: represents the actual number of atoms of each element in a molecule.
  • Empirical formula: represents the simplest whole-number ratio of atoms of each element in a molecule.

Nomenclature

  • Nomenclature: a systematic naming system for chemical compounds. Different naming systems and rules exist, such as the stock system, for various compounds (e.g., ionic, molecular and acids).

Periodic Table

  • Periodic table: a tabular arrangement of all known elements, organized by atomic number, electronic configuration and recurring chemical properties.
  • Periods: horizontal rows in the periodic table, corresponding to the principal quantum number; number of valence electrons.
  • Groups/families: vertical columns in the periodic table, grouping elements with similar properties; valence electrons.
  • Metals, Nonmetals, Metalloids.
  • Atomic Radius: size of an atom, increases as you move down a group and decreases as you move across a period
  • Ionization energy: energy to remove an electron from an atom, increases as you move across a period.
  • Electron affinity: energy released when an atom gains an electron, increases as you move across a period to a certain point.

Mole Concept

  • Mole: the amount of a substance containing 6.022 x 1023 particles (atoms, molecules, ions).
  • Molar mass: the mass in grams of one mole of a substance; numerically equal to the atomic or formula mass in amu.

Electron Configuration

  • Electron configuration: describes the arrangement of electrons within an atom.

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