Alkenes: Definition, Formula, and Properties
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Questions and Answers

Match the functional groups with their respective types of hydrocarbons:

Carbon-carbon double bonds = Alkenes Carbon-carbon triple bonds = Alkynes Carbon-carbon single bonds = Alkanes

Match the general formulas with their respective types of hydrocarbons:

CnH2n = Alkenes CnH2n-2 = Alkynes CnH2n+2 = Alkanes

Match the chemical properties with their respective types of hydrocarbons:

Electrophilic addition reactions = Alkenes Acid-base reactions = Alkynes Substitution reactions = Alkanes

Match the reaction types with their respective products:

<p>Dehydrohalogenation = Alkenes Dehydration = Alkenes Dehalogenation = Alkynes</p> Signup and view all the answers

Match the nomenclature rules with their respective types of hydrocarbons:

<p>Suffix: -ene = Alkenes Suffix: -yne = Alkynes Prefix: cyclo- = Cycloalkanes</p> Signup and view all the answers

Match the physical properties with their respective types of hydrocarbons:

<p>Lower boiling points and densities than alkanes = Alkenes Higher boiling points and densities than alkenes = Alkynes Higher boiling points and densities than alkanes = Alcohols</p> Signup and view all the answers

Match the isomerism types with their respective types of hydrocarbons:

<p>Cis-trans isomerism = Alkenes Structural isomerism = Alkanes Optical isomerism = Chiral molecules</p> Signup and view all the answers

Match the reaction types with their respective reactants:

<p>Alkylation = Alkynes Dehydrohalogenation = Alkyl halides Dehydration = Alcohols</p> Signup and view all the answers

Study Notes

Alkenes

  • Definition: Alkenes are unsaturated hydrocarbons containing one or more carbon-carbon double bonds.
  • General Formula: CnH2n
  • Nomenclature:
    • Prefix: alk- (e.g., eth-, prop-, but-)
    • Suffix: -ene (e.g., -ene, -diene, -triene)
    • Numbering starts from the end closest to the double bond
  • Physical Properties:
    • Lower boiling points and densities than alkanes
    • Insoluble in water, soluble in organic solvents
  • Chemical Properties:
    • Electrophilic Addition Reactions: react with electrophiles to form carbocations
    • Markovnikov's Rule: in asymmetric alkenes, the electrophile adds to the more substituted carbon
    • Stereochemistry: alkenes exhibit cis-trans isomerism due to restricted rotation around the double bond
  • Synthesis:
    • Dehydrohalogenation: elimination reaction of alkyl halides
    • Dehydration: elimination reaction of alcohols

Alkynes

  • Definition: Alkynes are unsaturated hydrocarbons containing one or more carbon-carbon triple bonds.
  • General Formula: CnH2n-2
  • Nomenclature:
    • Prefix: alk- (e.g., eth-, prop-, but-)
    • Suffix: -yne (e.g., -yne, -diyne, -triyne)
    • Numbering starts from the end closest to the triple bond
  • Physical Properties:
    • Higher boiling points and densities than alkenes
    • Insoluble in water, soluble in organic solvents
  • Chemical Properties:
    • Acid-Base Reactions: alkynes are acidic due to the high electronegativity of the triple bond
    • Reduction Reactions: alkynes can be reduced to alkenes or alkanes using hydrogen and catalysts
    • Cycloaddition Reactions: alkynes participate in Diels-Alder reactions with dienes
  • Synthesis:
    • Dehalogenation: reaction of alkyl dihalides with strong bases
    • Alkylation: reaction of alkynes with alkyl halides and strong bases

Alkenes

  • Unsaturated hydrocarbons with one or more carbon-carbon double bonds
  • General formula: CnH2n
  • Nomenclature rules:
    • Use alk- prefix (e.g., eth-, prop-, but-)
    • Use -ene suffix (e.g., -ene, -diene, -triene)
    • Numbering starts from the end closest to the double bond
  • Physical properties:
    • Lower boiling points and densities compared to alkanes
    • Insoluble in water, but soluble in organic solvents
  • Chemical properties:
    • Undergo electrophilic addition reactions to form carbocations
    • Follow Markovnikov's Rule in asymmetric alkenes
    • Exhibit cis-trans isomerism due to restricted rotation around the double bond
  • Synthesis methods:
    • Dehydrohalogenation: elimination reaction of alkyl halides
    • Dehydration: elimination reaction of alcohols

Alkynes

  • Unsaturated hydrocarbons with one or more carbon-carbon triple bonds
  • General formula: CnH2n-2
  • Nomenclature rules:
    • Use alk- prefix (e.g., eth-, prop-, but-)
    • Use -yne suffix (e.g., -yne, -diyne, -triyne)
    • Numbering starts from the end closest to the triple bond
  • Physical properties:
    • Higher boiling points and densities compared to alkenes
    • Insoluble in water, but soluble in organic solvents
  • Chemical properties:
    • Acidic due to the high electronegativity of the triple bond
    • Undergo reduction reactions to form alkenes or alkanes using hydrogen and catalysts
    • Participate in Diels-Alder reactions with dienes
  • Synthesis methods:
    • Dehalogenation: reaction of alkyl dihalides with strong bases
    • Alkylation: reaction of alkynes with alkyl halides and strong bases

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Learn about alkenes, a type of unsaturated hydrocarbon, including their general formula, nomenclature, physical properties, and chemical properties.

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