Alkenes: Definition, Formula, and Properties
8 Questions
16 Views

Choose a study mode

Play Quiz
Study Flashcards
Spaced Repetition
Chat to lesson

Podcast

Play an AI-generated podcast conversation about this lesson

Questions and Answers

Match the functional groups with their respective types of hydrocarbons:

Carbon-carbon double bonds = Alkenes Carbon-carbon triple bonds = Alkynes Carbon-carbon single bonds = Alkanes

Match the general formulas with their respective types of hydrocarbons:

CnH2n = Alkenes CnH2n-2 = Alkynes CnH2n+2 = Alkanes

Match the chemical properties with their respective types of hydrocarbons:

Electrophilic addition reactions = Alkenes Acid-base reactions = Alkynes Substitution reactions = Alkanes

Match the reaction types with their respective products:

<p>Dehydrohalogenation = Alkenes Dehydration = Alkenes Dehalogenation = Alkynes</p> Signup and view all the answers

Match the nomenclature rules with their respective types of hydrocarbons:

<p>Suffix: -ene = Alkenes Suffix: -yne = Alkynes Prefix: cyclo- = Cycloalkanes</p> Signup and view all the answers

Match the physical properties with their respective types of hydrocarbons:

<p>Lower boiling points and densities than alkanes = Alkenes Higher boiling points and densities than alkenes = Alkynes Higher boiling points and densities than alkanes = Alcohols</p> Signup and view all the answers

Match the isomerism types with their respective types of hydrocarbons:

<p>Cis-trans isomerism = Alkenes Structural isomerism = Alkanes Optical isomerism = Chiral molecules</p> Signup and view all the answers

Match the reaction types with their respective reactants:

<p>Alkylation = Alkynes Dehydrohalogenation = Alkyl halides Dehydration = Alcohols</p> Signup and view all the answers

Study Notes

Alkenes

  • Definition: Alkenes are unsaturated hydrocarbons containing one or more carbon-carbon double bonds.
  • General Formula: CnH2n
  • Nomenclature:
    • Prefix: alk- (e.g., eth-, prop-, but-)
    • Suffix: -ene (e.g., -ene, -diene, -triene)
    • Numbering starts from the end closest to the double bond
  • Physical Properties:
    • Lower boiling points and densities than alkanes
    • Insoluble in water, soluble in organic solvents
  • Chemical Properties:
    • Electrophilic Addition Reactions: react with electrophiles to form carbocations
    • Markovnikov's Rule: in asymmetric alkenes, the electrophile adds to the more substituted carbon
    • Stereochemistry: alkenes exhibit cis-trans isomerism due to restricted rotation around the double bond
  • Synthesis:
    • Dehydrohalogenation: elimination reaction of alkyl halides
    • Dehydration: elimination reaction of alcohols

Alkynes

  • Definition: Alkynes are unsaturated hydrocarbons containing one or more carbon-carbon triple bonds.
  • General Formula: CnH2n-2
  • Nomenclature:
    • Prefix: alk- (e.g., eth-, prop-, but-)
    • Suffix: -yne (e.g., -yne, -diyne, -triyne)
    • Numbering starts from the end closest to the triple bond
  • Physical Properties:
    • Higher boiling points and densities than alkenes
    • Insoluble in water, soluble in organic solvents
  • Chemical Properties:
    • Acid-Base Reactions: alkynes are acidic due to the high electronegativity of the triple bond
    • Reduction Reactions: alkynes can be reduced to alkenes or alkanes using hydrogen and catalysts
    • Cycloaddition Reactions: alkynes participate in Diels-Alder reactions with dienes
  • Synthesis:
    • Dehalogenation: reaction of alkyl dihalides with strong bases
    • Alkylation: reaction of alkynes with alkyl halides and strong bases

Alkenes

  • Unsaturated hydrocarbons with one or more carbon-carbon double bonds
  • General formula: CnH2n
  • Nomenclature rules:
    • Use alk- prefix (e.g., eth-, prop-, but-)
    • Use -ene suffix (e.g., -ene, -diene, -triene)
    • Numbering starts from the end closest to the double bond
  • Physical properties:
    • Lower boiling points and densities compared to alkanes
    • Insoluble in water, but soluble in organic solvents
  • Chemical properties:
    • Undergo electrophilic addition reactions to form carbocations
    • Follow Markovnikov's Rule in asymmetric alkenes
    • Exhibit cis-trans isomerism due to restricted rotation around the double bond
  • Synthesis methods:
    • Dehydrohalogenation: elimination reaction of alkyl halides
    • Dehydration: elimination reaction of alcohols

Alkynes

  • Unsaturated hydrocarbons with one or more carbon-carbon triple bonds
  • General formula: CnH2n-2
  • Nomenclature rules:
    • Use alk- prefix (e.g., eth-, prop-, but-)
    • Use -yne suffix (e.g., -yne, -diyne, -triyne)
    • Numbering starts from the end closest to the triple bond
  • Physical properties:
    • Higher boiling points and densities compared to alkenes
    • Insoluble in water, but soluble in organic solvents
  • Chemical properties:
    • Acidic due to the high electronegativity of the triple bond
    • Undergo reduction reactions to form alkenes or alkanes using hydrogen and catalysts
    • Participate in Diels-Alder reactions with dienes
  • Synthesis methods:
    • Dehalogenation: reaction of alkyl dihalides with strong bases
    • Alkylation: reaction of alkynes with alkyl halides and strong bases

Studying That Suits You

Use AI to generate personalized quizzes and flashcards to suit your learning preferences.

Quiz Team

Description

Learn about alkenes, a type of unsaturated hydrocarbon, including their general formula, nomenclature, physical properties, and chemical properties.

More Like This

Organic Chemistry: Alkene and Alkyl Halide Preparation
22 questions
Organic Chemistry Test 3 Flashcards
30 questions
Organic Chemistry: Alkenes and Reactions
21 questions
Use Quizgecko on...
Browser
Browser