Addition or Molecular Compounds

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20 Questions

Which ligand classification is based on the number of donor atoms present?

Monodentate, bidentate, and tridentate

Which of the following is an example of a bidentate ligand?

CO₂

Why do metal carbonyls effectively obey the EAN rule?

Because they exist in a zero oxidation state

What is the effective atomic number (EAN) of Co in the compound Co(CO)₄?

72

What are addition or molecular compounds?

Compounds formed by mixing simple salts in molecular proportions resulting in new crystalline compounds

What is the effective atomic number (EAN) of V in the compound V(CO)₆?

35

What is the main difference between double salts and complex salts?

Double salts break down into their constituents when dissolved in water, while complex salts retain their identity even in solution

What is the role of ligands in coordination compounds?

Ligands form coordinate bonds with the central metal atom or ion

Which type of compound retains its identity even in solution and has properties different from those of its constituents?

Complex salts

In modern usage, how is the complex ion shown which behaves as a single unit?

Enclosed in square brackets, e.g. [Fe(CN)]

What prefixes are used for indicating multiple ligands in names like ethylenediamine and dipyridyl?

di, tri, tetra

What prefixes are used for complicated ligands like ethylenediamine and dipyridyl, which already have the prefixes di, tri in their names?

bis, tris, tetrakis

Which type of valency is equal to the coordination number of the metal in coordination compounds?

Secondary valency

Which theory postulates that metals in coordination compounds possess two types of valency: primary and secondary valency?

Werner's theory

What type of species satisfies the primary valency in a coordination compound according to Werner's theory?

Anions

How are simple salts named?

Cation followed by anion

What is the naming order for complex ions?

Ligands, central metal ion

How are negative ligands named?

Ends in -O

What is the naming convention for neutral ligands?

Use of special names like aqua, ammine, carbonyl

How are simple ligands like chloride (Cl⁻) and cyanide (CN⁻) named?

Named as the molecules

Explore the concept of addition or molecular compounds and their types, such as double or lattice compounds. Learn about their properties and behavior when dissolved in water.

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