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Questions and Answers
What is the pH of a solution with a hydrogen ion concentration of $1 \times 10^{-5}$ M?
What is the pH of a solution with a hydrogen ion concentration of $1 \times 10^{-5}$ M?
- 5 (correct)
- -9
- 9
- -5
Which of the following is a characteristic of a strong acid in an aqueous solution?
Which of the following is a characteristic of a strong acid in an aqueous solution?
- It completely dissociates into ions. (correct)
- It has a pH greater than 7.
- It forms a buffer solution.
- It partially dissociates into ions.
What is the primary function of a buffer solution?
What is the primary function of a buffer solution?
- To increase the concentration of H+ ions
- To maintain a stable pH (correct)
- To cause rapid changes in pH
- To neutralize all acids in a solution
What is the equivalence point in an acid-base titration?
What is the equivalence point in an acid-base titration?
According to Le Chatelier's Principle, what happens to a system at equilibrium when the concentration of a reactant is increased?
According to Le Chatelier's Principle, what happens to a system at equilibrium when the concentration of a reactant is increased?
Which of the following defines an Arrhenius acid?
Which of the following defines an Arrhenius acid?
In a conjugate acid-base pair, what is the relationship between the acid and the base?
In a conjugate acid-base pair, what is the relationship between the acid and the base?
What does a low value of Ka indicate about the strength of an acid?
What does a low value of Ka indicate about the strength of an acid?
Which of the following describes a polyprotic acid?
Which of the following describes a polyprotic acid?
Given the equilibrium reaction: $HA \rightleftharpoons H^+ + A^-$, if the pH of the solution is equal to the pKa of the acid, what is the ratio of $[A^-]$ to $[HA]$?
Given the equilibrium reaction: $HA \rightleftharpoons H^+ + A^-$, if the pH of the solution is equal to the pKa of the acid, what is the ratio of $[A^-]$ to $[HA]$?
Which of the following statements is true regarding the pH of a strong acid solution compared to a weak acid solution of the same concentration?
Which of the following statements is true regarding the pH of a strong acid solution compared to a weak acid solution of the same concentration?
What components are typically present in a buffer solution?
What components are typically present in a buffer solution?
What is the purpose of an indicator in an acid-base titration?
What is the purpose of an indicator in an acid-base titration?
How does increasing the temperature affect the equilibrium of an endothermic acid-base reaction?
How does increasing the temperature affect the equilibrium of an endothermic acid-base reaction?
Which of the following is a Bronsted base?
Which of the following is a Bronsted base?
In the following reaction, $NH_3 + H_2O \rightleftharpoons NH_4^+ + OH^-$, identify the conjugate acid of $NH_3$.
In the following reaction, $NH_3 + H_2O \rightleftharpoons NH_4^+ + OH^-$, identify the conjugate acid of $NH_3$.
If the pH of a weak acid solution is 4.0 and its concentration is 0.1 M, what additional information is needed to calculate the Ka of the acid?
If the pH of a weak acid solution is 4.0 and its concentration is 0.1 M, what additional information is needed to calculate the Ka of the acid?
Which of the following is an example of a binary acid?
Which of the following is an example of a binary acid?
A solution of a weak acid, HA, has a pH of 3.5. If the initial concentration of HA is 0.20 M, what is the approximate value of the acid dissociation constant, Ka?
A solution of a weak acid, HA, has a pH of 3.5. If the initial concentration of HA is 0.20 M, what is the approximate value of the acid dissociation constant, Ka?
Which buffer system would be most appropriate for maintaining a pH of 9.0?
Which buffer system would be most appropriate for maintaining a pH of 9.0?
During the titration of a weak base with a strong acid, at what point is the pH equal to the pKa of the conjugate acid?
During the titration of a weak base with a strong acid, at what point is the pH equal to the pKa of the conjugate acid?
Consider the equilibrium: $2H_2O(l) \rightleftharpoons H_3O^+(aq) + OH^-(aq)$. Given that the forward reaction is endothermic, what effect will increasing the temperature have on the pH of pure water?
Consider the equilibrium: $2H_2O(l) \rightleftharpoons H_3O^+(aq) + OH^-(aq)$. Given that the forward reaction is endothermic, what effect will increasing the temperature have on the pH of pure water?
Which of the following is an example of an oxyacid?
Which of the following is an example of an oxyacid?
Consider a buffer solution made of benzoic acid ($C_6H_5COOH$, Ka = $6.3 \times 10^{-5}$) and its conjugate base, benzoate ($C_6H_5COO^−$). If the concentration of benzoic acid is 0.20 M and the concentration of benzoate is 0.25 M, what is the pH of the buffer solution?
Consider a buffer solution made of benzoic acid ($C_6H_5COOH$, Ka = $6.3 \times 10^{-5}$) and its conjugate base, benzoate ($C_6H_5COO^−$). If the concentration of benzoic acid is 0.20 M and the concentration of benzoate is 0.25 M, what is the pH of the buffer solution?
Calculate the pH of a 0.020 M solution of hydrofluoric acid (HF), given that its Ka is $6.8 \times 10^{-4}$.
Calculate the pH of a 0.020 M solution of hydrofluoric acid (HF), given that its Ka is $6.8 \times 10^{-4}$.
What is the main reason that strong acids have lower pH's than weak acids, assuming equal molar concentrations?
What is the main reason that strong acids have lower pH's than weak acids, assuming equal molar concentrations?
How many endpoints will be observed in the titration of a solution of carbonic acid ($H_2CO_3$) with a solution of sodium hydroxide ($NaOH$)?
How many endpoints will be observed in the titration of a solution of carbonic acid ($H_2CO_3$) with a solution of sodium hydroxide ($NaOH$)?
Which of the following is true about Kw, the ion product of water?
Which of the following is true about Kw, the ion product of water?
A researcher adds a small amount of hydrochloric acid (HCl) to a buffer solution containing acetic acid ($CH_3COOH$) and sodium acetate ($CH_3COONa$). How does the buffer system respond to maintain a stable pH?
A researcher adds a small amount of hydrochloric acid (HCl) to a buffer solution containing acetic acid ($CH_3COOH$) and sodium acetate ($CH_3COONa$). How does the buffer system respond to maintain a stable pH?
Consider the titration of a weak monoprotic acid with a strong base. Which of the following statements accurately describes the pH at the equivalence point?
Consider the titration of a weak monoprotic acid with a strong base. Which of the following statements accurately describes the pH at the equivalence point?
Which of the following changes will shift the equilibrium of the reaction $N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)$ + heat to favor the formation of ammonia ($NH_3$)?
Which of the following changes will shift the equilibrium of the reaction $N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)$ + heat to favor the formation of ammonia ($NH_3$)?
Identify the conjugate base of sulfuric acid ($H_2SO_4$).
Identify the conjugate base of sulfuric acid ($H_2SO_4$).
If the pH of a solution of acetic acid ($CH_3COOH$) is 2.87, and the pKa of acetic acid is 4.76, what is the ratio of [acetate, $CH_3COO^−$] to [acetic acid, $CH_3COOH$]?
If the pH of a solution of acetic acid ($CH_3COOH$) is 2.87, and the pKa of acetic acid is 4.76, what is the ratio of [acetate, $CH_3COO^−$] to [acetic acid, $CH_3COOH$]?
Ascorbic acid ($H_2C_6H_6O_6$) is a diprotic acid with $K_{a1} = 7.9 \times 10^{-5}$ and $K_{a2} = 1.6 \times 10^{-12}$. What is the pH of a 0.10 M solution of ascorbic acid, considering only the first dissociation?
Ascorbic acid ($H_2C_6H_6O_6$) is a diprotic acid with $K_{a1} = 7.9 \times 10^{-5}$ and $K_{a2} = 1.6 \times 10^{-12}$. What is the pH of a 0.10 M solution of ascorbic acid, considering only the first dissociation?
You have a solution of 0.1 M acetic acid ($CH_3COOH$, $K_a = 1.8 \times 10^{-5}$). What concentration of sodium acetate ($CH_3COONa$) must be added to create a buffer with a pH of 5.0?
You have a solution of 0.1 M acetic acid ($CH_3COOH$, $K_a = 1.8 \times 10^{-5}$). What concentration of sodium acetate ($CH_3COONa$) must be added to create a buffer with a pH of 5.0?
A chemist prepares a buffer solution by mixing 25.0 mL of 0.200 M $NH_3$ with 25.0 mL of 0.250 M $NH_4Cl$. What is the pH of the resulting buffer? (The $pK_b$ of $NH_3$ is 4.75)
A chemist prepares a buffer solution by mixing 25.0 mL of 0.200 M $NH_3$ with 25.0 mL of 0.250 M $NH_4Cl$. What is the pH of the resulting buffer? (The $pK_b$ of $NH_3$ is 4.75)
What is the pH at which $Mg(OH)2$ precipitates from a solution with a $Mg^{2+}$ concentration of $1.0 \times 10^{-3}$ M? ($K{sp} = 5.6 \times 10^{-12}$)
What is the pH at which $Mg(OH)2$ precipitates from a solution with a $Mg^{2+}$ concentration of $1.0 \times 10^{-3}$ M? ($K{sp} = 5.6 \times 10^{-12}$)
Flashcards
Acid-base equilibrium
Acid-base equilibrium
Acids donate, bases accept protons (H+)
pH
pH
Measure of acidity or basicity
pH Calculation Formula
pH Calculation Formula
pH = -log[H+], [H+] is hydrogen ion concentration
Strong acids
Strong acids
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Buffer solutions
Buffer solutions
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Acid-base titrations
Acid-base titrations
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Equivalence point
Equivalence point
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Le Chatelier's Principle
Le Chatelier's Principle
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Arrhenius acids
Arrhenius acids
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Bronsted acids
Bronsted acids
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Conjugate acid-base pairs
Conjugate acid-base pairs
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Ka
Ka
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Polyprotic acids
Polyprotic acids
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Binary acids
Binary acids
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Oxyacids
Oxyacids
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Carboxylic acids
Carboxylic acids
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Weak acids
Weak acids
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Study Notes
- Acid-base equilibrium involves the donation or acceptance of protons (H+ ions) in aqueous solutions.
pH Calculations
- pH measures the acidity or basicity of a solution.
- pH is calculated using the formula: pH = -log[H+], where [H+] is the concentration of hydrogen ions.
- A pH less than 7 indicates an acidic solution, a pH of 7 is neutral, and a pH greater than 7 indicates a basic solution.
Strong vs. Weak Acids
- Strong acids completely dissociate into ions in water, while weak acids only partially dissociate.
- Strong acids have a very low pH
- Weak acids have a higher pH than strong acids
Buffer Solutions
- Buffer solutions resist changes in pH upon the addition of small amounts of acid or base.
- Buffers are typically composed of a weak acid and its conjugate base or a weak base and its conjugate acid.
- Important in maintaining stable pH levels in biological and chemical systems.
Acid-Base Titrations
- Acid-base titrations are used to determine the concentration of an acid or base by neutralizing it with a solution of known concentration.
- The equivalence point is reached when the acid and base have completely neutralized each other.
- Indicators are used to visually signal the endpoint of the titration, which is close to the equivalence point.
Le Chatelier's Principle
- Le Chatelier's Principle states that if a change of condition is applied to a system in equilibrium, the system will shift in a direction that relieves the stress.
- Changes in concentration, temperature, or pressure can affect the equilibrium position of acid-base reactions.
Bronsted/Arrhenius Acids and Bases
- Arrhenius acids produce H+ ions in water, while Arrhenius bases produce OH- ions in water.
- Bronsted acids are proton donors, and Bronsted bases are proton acceptors.
Conjugate Acid-Base Pairs
- Conjugate acid-base pairs consist of two species that differ by the presence or absence of a proton.
- An acid donates a proton to form its conjugate base, and a base accepts a proton to form its conjugate acid.
Calculating Ka from pH and Vice Versa
- Ka is the acid dissociation constant, which measures the strength of a weak acid.
- Ka can be calculated from the pH of a solution of a weak acid using the equilibrium expression.
- Conversely, the pH of a solution of a weak acid can be calculated from its Ka value.
Polyprotic/Binary/Oxyacids/Carboxylic Acids
- Polyprotic acids can donate more than one proton per molecule.
- Binary acids consist of hydrogen and one other element.
- Oxyacids contain hydrogen, oxygen, and another element.
- Carboxylic acids contain a carboxyl group (-COOH) and are weak organic acids.
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