Acid-Base Equilibrium and pH

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Questions and Answers

What is the pH of a solution with a hydrogen ion concentration of $1 \times 10^{-5}$ M?

  • 5 (correct)
  • -9
  • 9
  • -5

Which of the following is a characteristic of a strong acid in an aqueous solution?

  • It completely dissociates into ions. (correct)
  • It has a pH greater than 7.
  • It forms a buffer solution.
  • It partially dissociates into ions.

What is the primary function of a buffer solution?

  • To increase the concentration of H+ ions
  • To maintain a stable pH (correct)
  • To cause rapid changes in pH
  • To neutralize all acids in a solution

What is the equivalence point in an acid-base titration?

<p>The point at which the acid and base have completely neutralized each other. (B)</p> Signup and view all the answers

According to Le Chatelier's Principle, what happens to a system at equilibrium when the concentration of a reactant is increased?

<p>The equilibrium shifts to favor the forward reaction. (C)</p> Signup and view all the answers

Which of the following defines an Arrhenius acid?

<p>A substance that produces H+ ions in water. (A)</p> Signup and view all the answers

In a conjugate acid-base pair, what is the relationship between the acid and the base?

<p>They differ by the presence or absence of a proton. (A)</p> Signup and view all the answers

What does a low value of Ka indicate about the strength of an acid?

<p>It is a weak acid. (C)</p> Signup and view all the answers

Which of the following describes a polyprotic acid?

<p>An acid that can donate more than one proton per molecule. (C)</p> Signup and view all the answers

Given the equilibrium reaction: $HA \rightleftharpoons H^+ + A^-$, if the pH of the solution is equal to the pKa of the acid, what is the ratio of $[A^-]$ to $[HA]$?

<p>1 (D)</p> Signup and view all the answers

Which of the following statements is true regarding the pH of a strong acid solution compared to a weak acid solution of the same concentration?

<p>The strong acid solution will have a lower pH. (B)</p> Signup and view all the answers

What components are typically present in a buffer solution?

<p>A weak acid and its conjugate base (C)</p> Signup and view all the answers

What is the purpose of an indicator in an acid-base titration?

<p>To visually signal the endpoint of the titration (B)</p> Signup and view all the answers

How does increasing the temperature affect the equilibrium of an endothermic acid-base reaction?

<p>It shifts the equilibrium to favor the products. (D)</p> Signup and view all the answers

Which of the following is a Bronsted base?

<p>A substance that accepts protons. (B)</p> Signup and view all the answers

In the following reaction, $NH_3 + H_2O \rightleftharpoons NH_4^+ + OH^-$, identify the conjugate acid of $NH_3$.

<p>$NH_4^+$ (B)</p> Signup and view all the answers

If the pH of a weak acid solution is 4.0 and its concentration is 0.1 M, what additional information is needed to calculate the Ka of the acid?

<p>No additional information is needed. (A)</p> Signup and view all the answers

Which of the following is an example of a binary acid?

<p>$HCl$ (A)</p> Signup and view all the answers

A solution of a weak acid, HA, has a pH of 3.5. If the initial concentration of HA is 0.20 M, what is the approximate value of the acid dissociation constant, Ka?

<p>$1.6 \times 10^{-7}$ (B)</p> Signup and view all the answers

Which buffer system would be most appropriate for maintaining a pH of 9.0?

<p>Ammonium / Ammonia (pKa = 9.25) (A)</p> Signup and view all the answers

During the titration of a weak base with a strong acid, at what point is the pH equal to the pKa of the conjugate acid?

<p>At the half-equivalence point (A)</p> Signup and view all the answers

Consider the equilibrium: $2H_2O(l) \rightleftharpoons H_3O^+(aq) + OH^-(aq)$. Given that the forward reaction is endothermic, what effect will increasing the temperature have on the pH of pure water?

<p>The pH will decrease. (B)</p> Signup and view all the answers

Which of the following is an example of an oxyacid?

<p>HClOâ‚„ (C)</p> Signup and view all the answers

Consider a buffer solution made of benzoic acid ($C_6H_5COOH$, Ka = $6.3 \times 10^{-5}$) and its conjugate base, benzoate ($C_6H_5COO^−$). If the concentration of benzoic acid is 0.20 M and the concentration of benzoate is 0.25 M, what is the pH of the buffer solution?

<p>4.20 (C)</p> Signup and view all the answers

Calculate the pH of a 0.020 M solution of hydrofluoric acid (HF), given that its Ka is $6.8 \times 10^{-4}$.

<p>2.07 (C)</p> Signup and view all the answers

What is the main reason that strong acids have lower pH's than weak acids, assuming equal molar concentrations?

<p>Strong acids completely dissociate while weak acids only partially dissociate. (A)</p> Signup and view all the answers

How many endpoints will be observed in the titration of a solution of carbonic acid ($H_2CO_3$) with a solution of sodium hydroxide ($NaOH$)?

<p>Two (B)</p> Signup and view all the answers

Which of the following is true about Kw, the ion product of water?

<p>$K_w$ changes with temperature. (A)</p> Signup and view all the answers

A researcher adds a small amount of hydrochloric acid (HCl) to a buffer solution containing acetic acid ($CH_3COOH$) and sodium acetate ($CH_3COONa$). How does the buffer system respond to maintain a stable pH?

<p>The acetate ions accept protons from the added acid. (C)</p> Signup and view all the answers

Consider the titration of a weak monoprotic acid with a strong base. Which of the following statements accurately describes the pH at the equivalence point?

<p>pH &gt; 7 (A)</p> Signup and view all the answers

Which of the following changes will shift the equilibrium of the reaction $N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)$ + heat to favor the formation of ammonia ($NH_3$)?

<p>Removing ammonia as it forms (B)</p> Signup and view all the answers

Identify the conjugate base of sulfuric acid ($H_2SO_4$).

<p>$HSO_4^-$ (A)</p> Signup and view all the answers

If the pH of a solution of acetic acid ($CH_3COOH$) is 2.87, and the pKa of acetic acid is 4.76, what is the ratio of [acetate, $CH_3COO^−$] to [acetic acid, $CH_3COOH$]?

<p>0.0129 (C)</p> Signup and view all the answers

Ascorbic acid ($H_2C_6H_6O_6$) is a diprotic acid with $K_{a1} = 7.9 \times 10^{-5}$ and $K_{a2} = 1.6 \times 10^{-12}$. What is the pH of a 0.10 M solution of ascorbic acid, considering only the first dissociation?

<p>2.55 (A)</p> Signup and view all the answers

You have a solution of 0.1 M acetic acid ($CH_3COOH$, $K_a = 1.8 \times 10^{-5}$). What concentration of sodium acetate ($CH_3COONa$) must be added to create a buffer with a pH of 5.0?

<p>0.18 M (A)</p> Signup and view all the answers

A chemist prepares a buffer solution by mixing 25.0 mL of 0.200 M $NH_3$ with 25.0 mL of 0.250 M $NH_4Cl$. What is the pH of the resulting buffer? (The $pK_b$ of $NH_3$ is 4.75)

<p>9.15 (C)</p> Signup and view all the answers

What is the pH at which $Mg(OH)2$ precipitates from a solution with a $Mg^{2+}$ concentration of $1.0 \times 10^{-3}$ M? ($K{sp} = 5.6 \times 10^{-12}$)

<p>10.73 (A)</p> Signup and view all the answers

Flashcards

Acid-base equilibrium

Acids donate, bases accept protons (H+)

pH

Measure of acidity or basicity

pH Calculation Formula

pH = -log[H+], [H+] is hydrogen ion concentration

Strong acids

Dissociate completely into ions in water

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Buffer solutions

Resist pH change with small addition of acid or base

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Acid-base titrations

Neutralization with a known concentration solution

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Equivalence point

Point of complete acid/base neutralization

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Le Chatelier's Principle

Shifts to relieve stress

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Arrhenius acids

Produce H+ in water

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Bronsted acids

Proton Donors

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Conjugate acid-base pairs

Differ by presence/absence of a proton

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Ka

Acid dissociation constant

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Polyprotic acids

Donate more than one proton per molecule

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Binary acids

Hydrogen and one other element

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Oxyacids

Contain hydrogen, oxygen, and another element

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Carboxylic acids

Contain -COOH group; weak organic acids

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Weak acids

Only partially dissociate into ions in water

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Study Notes

  • Acid-base equilibrium involves the donation or acceptance of protons (H+ ions) in aqueous solutions.

pH Calculations

  • pH measures the acidity or basicity of a solution.
  • pH is calculated using the formula: pH = -log[H+], where [H+] is the concentration of hydrogen ions.
  • A pH less than 7 indicates an acidic solution, a pH of 7 is neutral, and a pH greater than 7 indicates a basic solution.

Strong vs. Weak Acids

  • Strong acids completely dissociate into ions in water, while weak acids only partially dissociate.
  • Strong acids have a very low pH
  • Weak acids have a higher pH than strong acids

Buffer Solutions

  • Buffer solutions resist changes in pH upon the addition of small amounts of acid or base.
  • Buffers are typically composed of a weak acid and its conjugate base or a weak base and its conjugate acid.
  • Important in maintaining stable pH levels in biological and chemical systems.

Acid-Base Titrations

  • Acid-base titrations are used to determine the concentration of an acid or base by neutralizing it with a solution of known concentration.
  • The equivalence point is reached when the acid and base have completely neutralized each other.
  • Indicators are used to visually signal the endpoint of the titration, which is close to the equivalence point.

Le Chatelier's Principle

  • Le Chatelier's Principle states that if a change of condition is applied to a system in equilibrium, the system will shift in a direction that relieves the stress.
  • Changes in concentration, temperature, or pressure can affect the equilibrium position of acid-base reactions.

Bronsted/Arrhenius Acids and Bases

  • Arrhenius acids produce H+ ions in water, while Arrhenius bases produce OH- ions in water.
  • Bronsted acids are proton donors, and Bronsted bases are proton acceptors.

Conjugate Acid-Base Pairs

  • Conjugate acid-base pairs consist of two species that differ by the presence or absence of a proton.
  • An acid donates a proton to form its conjugate base, and a base accepts a proton to form its conjugate acid.

Calculating Ka from pH and Vice Versa

  • Ka is the acid dissociation constant, which measures the strength of a weak acid.
  • Ka can be calculated from the pH of a solution of a weak acid using the equilibrium expression.
  • Conversely, the pH of a solution of a weak acid can be calculated from its Ka value.

Polyprotic/Binary/Oxyacids/Carboxylic Acids

  • Polyprotic acids can donate more than one proton per molecule.
  • Binary acids consist of hydrogen and one other element.
  • Oxyacids contain hydrogen, oxygen, and another element.
  • Carboxylic acids contain a carboxyl group (-COOH) and are weak organic acids.

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