Chemistry Chapter: Acid-Base Equilibria

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Questions and Answers

What is the equilibrium constant expression for the autoionization of water?

  • $K_w = [H_3O+][OH^-]$ (correct)
  • $K_w = [H_2O]/[H_3O+][OH^-]$
  • $K_w = [H_2O]^2/[H_3O+][OH^-]$
  • $K_w = [H_3O+][OH^-]/[H_2O]^2$

If the concentration of hydroxide ions ([OH-]) in a solution is 1.0 x 10^-10 M, what is the concentration of hydronium ions ([H3O+]) at 25°C?

  • 1.0 x 10^-10 M
  • 1.0 x 10^-14 M
  • 1.0 x 10^-7 M
  • 1.0 x 10^-4 M (correct)

A solution with a pH of 11 would best be described as what?

  • Strongly acidic
  • Strongly basic (correct)
  • Neutral
  • Slightly acidic

Which of the following statements accurately describes the autoionization of water?

<p>Water molecules are amphoteric, meaning they can act as both an acid and a base, and they ionize to a very small extent. (A)</p> Signup and view all the answers

What is the pOH of a solution with a hydronium ion concentration of 1.0 x 10^-3 M at 25°C?

<p>11 (D)</p> Signup and view all the answers

In the Henderson-Hasselbalch equation, what does the term 'pKa' represent?

<p>The negative logarithm of the acid dissociation constant (Ka) (B)</p> Signup and view all the answers

A buffer solution is prepared by mixing 0.10 M CH3COOH and 0.10 M CH3COONa. What is the pH of this buffer if the Ka for CH3COOH is 1.8 x 10^-5?

<p>4.74 (C)</p> Signup and view all the answers

Which of the following statements is TRUE about a buffer solution?

<p>A buffer solution resists changes in pH when small amounts of strong acid or base are added. (D)</p> Signup and view all the answers

What is the pH of a solution containing 0.10 M HCOOH and 0.10 M HCOO- if the pKa of HCOOH is 3.75?

<p>3.75 (A)</p> Signup and view all the answers

A buffer solution is prepared by mixing 0.20 M NH3 and 0.10 M NH4Cl. If the Kb for NH3 is 1.8 x 10-5, what is the pH of this buffer solution?

<p>9.25 (C)</p> Signup and view all the answers

What is the pH of a buffer solution consisting of 0.10 M H2CO3 and 0.10 M HCO3- if the Ka for H2CO3 is 4.3 x 10^-7?

<p>6.37 (A)</p> Signup and view all the answers

A buffer solution is prepared by mixing 0.25 M HF and 0.50 M NaF. What is the pH of this buffer if the Ka for HF is 7.2 x 10^-4?

<p>3.14 (A)</p> Signup and view all the answers

A solution containing 0.50 M CH3COOH and 0.50 M CH3COONa has a pH of 4.74 (pKa for CH3COOH is 4.74). If 0.01 mol of NaOH is added to 1 L of this buffer solution, what is the new pH of the solution?

<p>4.77 (B)</p> Signup and view all the answers

A student is performing an acid-base titration using a burette filled with a standardized sodium hydroxide solution. During the titration, they observe that the solution in the burette has air bubbles. Why is this a problem?

<p>Air bubbles will cause an inaccurate measurement of the volume of sodium hydroxide solution used. (B)</p> Signup and view all the answers

In a titration, a drop of phenolphthalein indicator is added to the analyte solution. What color change would the student expect to observe as the titration progresses?

<p>The solution will change from colorless to pink. (D)</p> Signup and view all the answers

A student carefully added 10.0 mL of hydrochloric acid to a clean Erlenmeyer flask. After the titrant was added, the student observed that the solution in the flask was still acidic. What should the student do next?

<p>Continue adding sodium hydroxide solution until the pink color persists. (C)</p> Signup and view all the answers

Why is it important to record the initial and final burette readings to the nearest 0.1mL during a titration?

<p>To ensure that the volume of titrant used is accurately determined. (D)</p> Signup and view all the answers

In the titration, a student records the initial burette reading as 10.0 mL and the final reading as 25.5 mL. What is the total volume of sodium hydroxide solution used in the titration?

<p>15.5 mL (A)</p> Signup and view all the answers

The normality of a solution is defined as the number of equivalents of solute per liter of solution. What is the normality of a 0.1 M solution of sodium hydroxide (NaOH)?

<p>0.1 N (C)</p> Signup and view all the answers

What is the primary purpose of using indicators like phenolphthalein in a titration?

<p>To visually signal the endpoint of the titration. (A)</p> Signup and view all the answers

A student is titrating a solution of hydrochloric acid (HCl) with a standard sodium hydroxide solution (NaOH). What is the significance of the equivalence point in this titration?

<p>The equivalence point is the point at which the moles of HCl added are equal to the moles of NaOH added. (B)</p> Signup and view all the answers

In the equilibrium reaction given, what would happen if the initial concentration of CH3COOH is increased to 0.20M, while the initial concentration of H3O+ is kept constant at 0.10M?

<p>The equilibrium would shift to the right, favoring the formation of CH3COO- and H3O+. (B)</p> Signup and view all the answers

Why is the Cl− ion considered a spectator ion in the reaction shown?

<p>Because it does not participate in the proton transfer equilibrium of the reaction. (C)</p> Signup and view all the answers

What is the significance of the statement 'x is very small' in the calculation of Ka?

<p>It justifies ignoring the changes in concentration of CH3COOH and H3O+ at equilibrium, simplifying the calculation. (A)</p> Signup and view all the answers

In the calculation of Ka, why is (0.10 − x) approximated to 0.10?

<p>Because x is very small compared to 0.10, making the subtraction negligible. (B)</p> Signup and view all the answers

A solution containing 0.20 M CH3COOH and 0.30 M CH3COONa acts as a buffer. Which of the following statements accurately describes the role of CH3COONa in this buffer?

<p>CH3COONa provides the conjugate base component of the buffer. (C)</p> Signup and view all the answers

What is the pH of a buffer solution after the addition of a small amount of strong base, like NaOH?

<p>The pH will increase slightly, reflecting the reaction of the base with the weak acid in the buffer. (B)</p> Signup and view all the answers

A buffer is defined as a solution that resists changes in pH. Why does a buffer solution resist such changes?

<p>It contains a large concentration of a weak acid and its conjugate base, which can neutralize both added acids and bases. (C)</p> Signup and view all the answers

Why is the addition of a small amount of acid or base to a buffer solution less likely to cause a significant change in pH, whereas the same amount of acid or base added to an unbuffered solution would cause a larger pH change?

<p>The buffer solution contains a weak acid and its conjugate base, which can react with the added H+ or OH− ions, minimizing the changes in their concentrations. (D)</p> Signup and view all the answers

What is the approximate hydroxide ion concentration, [OH-], in a 0.040 M solution of ammonia (NH3)?

<p>3.6 x 10^-6 M (D)</p> Signup and view all the answers

What is the value of [NH3] at equilibrium in a 0.040 M ammonia solution, considering the approximation method used in the content?

<p>0.039 M (C)</p> Signup and view all the answers

If the approximation method used in the content is deemed invalid for a 0.040 M ammonia solution, how would you proceed to find the equilibrium concentration of ammonia?

<p>Use the quadratic formula to solve for x (A)</p> Signup and view all the answers

Which of the following is NOT a valid assumption for the use of the approximation method in calculating equilibrium concentrations of a weak base like ammonia?

<p>The equilibrium constant, Kb, is very small (D)</p> Signup and view all the answers

What is the value of the pOH of a 0.040 M ammonia solution, assuming the approximation method is valid?

<p>11.23 (A)</p> Signup and view all the answers

What is the pH of a 0.040 M ammonia solution, given that the pOH is 11.23?

<p>2.77 (B)</p> Signup and view all the answers

What is the effect on the equilibrium position of the ammonia ionization reaction in water when the common ion (e.g., ammonium ion) is added?

<p>The equilibrium will shift to the left, favoring the formation of ammonia (D)</p> Signup and view all the answers

Which of the following statements correctly describes the common ion effect?

<p>The common ion effect refers to the suppression of the ionization of a weak acid or base when a soluble salt containing the common ion is added to the solution (B)</p> Signup and view all the answers

Why is a weak acid-base conjugate pair necessary for effective buffer solutions?

<p>The presence of both acid and base components allows for the neutralization of both added H+ and OH- ions. (C)</p> Signup and view all the answers

Explain why the equilibrium concentrations of acetic acid (CH3COOH) and acetate ions (CH3COO-) in a buffer solution are assumed to be similar to their starting concentrations.

<p>The presence of both acetic acid and acetate ions inhibits the ionization of the weak acid and the hydrolysis of the acetate ion, preventing significant changes in their concentrations. (D)</p> Signup and view all the answers

How does a buffer solution containing acetic acid and sodium acetate neutralize the addition of a base (OH-)?

<p>The acetic acid donates protons to the hydroxide ions, neutralizing the base and forming water. (C)</p> Signup and view all the answers

What is the main reason why the pH of blood is maintained at around 7.4?

<p>The presence of proteins and other macromolecules in blood serve as buffers to resist changes in pH. (A)</p> Signup and view all the answers

How does the Henderson-Hasselbalch equation relate to the pH of a buffer solution?

<p>The equation provides a mathematical approximation of the buffer's pH, dependent on the ratio of the acidic and basic components. (A)</p> Signup and view all the answers

Which of these statements accurately describes the principle underlying the functioning of a buffer solution?

<p>Buffer solutions maintain a stable pH by reacting with added acids or bases, minimizing the change in pH. (B)</p> Signup and view all the answers

Which of the following scenarios would NOT be a suitable application of a buffer solution?

<p>Neutralizing excess stomach acid. (B)</p> Signup and view all the answers

How does the concentration of the buffer components affect its buffering capacity?

<p>Higher concentrations of buffer components lead to an increased capacity to resist pH changes. (B)</p> Signup and view all the answers

Flashcards

Ionization of Water

The process where water molecules split into H3O+ and OH- ions.

Ion Product for Water (K_w)

The equilibrium constant for the ionization of water at 25°C, K_w = [H3O+][OH-].

Weak Electrolyte

A substance that partially ionizes in solution, such as water.

Percent Ionization

The fraction of a weak acid or base that ionizes, expressed as a percentage.

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Acid-Dissociation Constant (K_a)

A measure of the strength of an acid in solution, defined as K_a = [H+][A-]/[HA].

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Spectator Ion

An ion that does not affect the overall reaction or equilibrium concentration.

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Equilibrium Concentration

The concentrations of reactants and products in a system at equilibrium.

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Weak Acid

An acid that partially dissociates in solution, establishing an equilibrium.

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Conjugate Base

The species that remains after an acid donates a proton (H+).

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Buffer Solution

A solution that resists changes in pH upon the addition of acids or bases.

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Common Ion Effect

The reduction in the solubility of an ion when a common ion is added.

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Ka (Acid Dissociation Constant)

A measure of the strength of an acid in solution; quantifies dissociation.

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pH Calculation

Determining the acidity or basicity of a solution based on hydrogen ion concentration.

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Hydronium Ion Concentration

The amount of H3O+ ions in a solution, impacting pH.

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Kb (Base Ionization Constant)

A measure of a base's ability to dissociate and form OH- in solution.

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Conjugate Pair

A weak acid and its conjugate base or a weak base and its conjugate acid.

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Acetic Acid

A weak acid with the formula CH₃COOH used in buffer solutions.

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Sodium Acetate

A strong electrolyte that acts as the conjugate base in buffer solutions.

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Ionization of Ammonia

The reaction where ammonia (NH3) accepts protons to form ammonium ions (NH4+) and hydroxide ions (OH-).

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pH Resistance

The ability of a buffer to maintain pH despite additions of acid or base.

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Henderson-Hasselbalch Equation

An equation to estimate the pH of a buffer solution based on acid and conjugate base concentrations.

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Ionization Suppression

The process where the presence of one compound reduces the ionization of another in a buffer.

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pOH

A measure of hydroxide ion concentration, related to the acidity of a solution.

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pH of Blood

The normal pH value of blood is about 7.4, maintained by buffers.

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Haber Process

An industrial method for synthesizing ammonia from nitrogen and hydrogen.

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Titration

A technique to determine the concentration of an unknown solution using a known solution.

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Titrant

The solution of known concentration used in titration.

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Analyte

The substance being analyzed in a titration.

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Endpoint

The point in titration at which the reaction is complete, often indicated by a color change.

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Phenolphthalein

An acid-base indicator that changes from colorless to pink in a basic solution.

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Normality (N)

A measurement of concentration equivalent to the molarity of a solution multiplied by the number of equivalents of reactive species.

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Hydrochloric acid (HCl)

A strong acid commonly used in titrations, often tested against a base like sodium hydroxide.

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Burette

A graduated glass tube used to deliver a precise volume of titrant during titration.

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Dissociation Equation

The reaction showing an acid dissociating in water.

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Ka Expression

The equilibrium constant for acid dissociation.

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Equilibrium

A state where the concentrations of reactants and products remain constant.

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