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Questions and Answers

In the reaction $Fe^{3+}(aq) + SO_2(g) \rightarrow Fe^{2+}(aq) + SO_4^{2-}(aq)$, which of the following correctly identifies the oxidation and reduction half-reactions?

  • Oxidation: $SO_2(g) + 2H_2O(l) \rightarrow SO_4^{2-}(aq) + 4H^+(aq) + 2e^-$, Reduction: $Fe^{3+}(aq) + e^- \rightarrow Fe^{2+}(aq)$ (correct)
  • Oxidation: $Fe^{2+}(aq) \rightarrow Fe^{3+}(aq) + e^-$, Reduction: $SO_4^{2-}(aq) + 4H^+(aq) + 2e^- \rightarrow SO_2(g) + 2H_2O(l)$
  • Oxidation: $SO_4^{2-}(aq) + 4H^+(aq) + 2e^- \rightarrow SO_2(g) + 2H_2O(l)$, Reduction: $Fe^{2+}(aq) \rightarrow Fe^{3+}(aq) + e^-$
  • Oxidation: $Fe^{3+}(aq) + e^- \rightarrow Fe^{2+}(aq)$, Reduction: $SO_2(g) + 2H_2O(l) \rightarrow SO_4^{2-}(aq) + 4H^+(aq) + 2e^-$

Consider the reaction: $H_2O_2(aq) + I^-(aq) \rightarrow H_2O(l) + I_2(s)$. Which statement accurately describes the role of each reactant?

  • $H_2O_2$ is the oxidizing agent, accepting electrons, and $I^-$ is the reducing agent, donating electrons. (correct)
  • $H_2O_2$ and $I^-$ are both reducing agents, donating electrons.
  • $H_2O_2$ is the reducing agent, donating electrons, and $I^-$ is the oxidizing agent, accepting electrons.
  • $H_2O_2$ and $I^-$ are both oxidizing agents, accepting electrons.

For the reaction: $MnO_4^-(aq) + Br^-(aq) \rightarrow Mn^{2+}(aq) + Br_2(aq)$, what is the coefficient of $Br^-(aq)$ when the equation is balanced using the smallest whole-number coefficients?

  • 5
  • 10 (correct)
  • 16
  • 2

In the reaction between dichromate ions and bisulfite ions: $Cr_2O_7^{2-}(aq) + HSO_3^-(aq) \rightarrow Cr^{3+}(aq) + SO_4^{2-}(aq)$, what color change would you expect to observe as the reaction proceeds?

<p>Orange to green. (B)</p> Signup and view all the answers

When chlorine gas is bubbled into a solution of potassium bromide, a color change is observed. What is the correct explanation for why this color change occurs?

<p>Chlorine gas oxidizes bromide ions to bromine, resulting in a brown-orange color. (C)</p> Signup and view all the answers

Which of the following correctly ranks the halogens chlorine ($Cl_2$), bromine ($Br_2$), and iodine ($I_2$) in order of decreasing oxidizing strength?

<p>$Cl_2 &gt; Br_2 &gt; I_2$ (C)</p> Signup and view all the answers

What are the products formed when chlorine gas reacts with water, and what is the common name for the resulting solution?

<p>$HCl$ and $HOCl$; Chlorinated water. (B)</p> Signup and view all the answers

When iron metal (steel wool) reacts with chlorine gas, what is the formula of the major iron-containing product formed?

<p>$FeCl_3$ (D)</p> Signup and view all the answers

Flashcards

What is oxidation?

Loss of electrons, increase in oxidation number.

What is reduction?

Gain of electrons, decrease in oxidation number.

What is a redox reaction?

A reaction involving both oxidation and reduction processes.

What is an oxidant (oxidizing agent)?

The reactant that causes oxidation in another substance; it accepts electrons.

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What is a reductant (reducing agent)?

The reactant that causes reduction in another substance; it donates electrons.

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What color change occurs when chlorine gas is bubbled into potassium bromide solution?

Br2 (brown/orange) is formed, displacing colorless bromide ions.

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Which halide is the strongest oxidant?

Chlorine (Cl2)

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What is the name of the ion OCl-?

Hypochlorite ion

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Study Notes

  • Redox reactions involve oxidation and reduction processes.
  • Ion-electron half equations are used to represent oxidation and reduction separately.
  • Balancing redox equations involves balancing both mass and charge.
  • Colour changes can indicate the progress of a redox reaction.

Balancing Redox Reaction (a)

  • Reactants: Fe3+(aq) and SO2(g).
  • Products: Fe2+(aq) and SO42-(aq).

Balancing Redox Reaction (b)

  • Reactants: Fe2+(aq) and Cl2(g).
  • Products: Fe3+(aq) and Cl-(aq).

Balancing Redox Reaction (c)

  • Reactants: H2O2(aq) and I-(aq).
  • Products: H2O(l) and I2(s).

Balancing Redox Reaction (d)

  • Reactants: MnO4-(aq) and Br-(aq).
  • Products: Mn2+(aq) and Br2(aq).

Balancing Redox Reaction (e)

  • Reactants: Cr2O72-(aq) and HSO3-(aq).
  • Products: Cr3+(aq) and SO42-(aq).

Chlorine Gas and Potassium Bromide

  • When chlorine gas is bubbled into potassium bromide solution, a colour change is observed.

  • The colour change in the solution needs to be described.

  • The oxidant and reductant in this reaction must be named.

  • For oxidation and reduction reactions, balanced half-equations need to be formulated.

  • The balanced equation for the oxidation-reduction reaction can be derived by combining the half-equations.

  • Observations can be explained by referring to species in the balanced equation.

  • The strongest oxidant among chlorine, bromine, and iodine needs to be identified.

Reactions Involving Halogens

  • Balanced equations are required for reactions involving halogens:
  • Magnesium metal and chlorine gas.
  • Hydrogen gas and chlorine gas.
  • Aluminium metal powder and iodine powder.
  • Iron metal (steel wool) and chlorine gas.
  • Chlorine gas and water, naming the two acids that are produced.

Hypochlorite Ion

  • The formula for the hypochlorite ion must be stated
  • The common name of a solution containing this ion must be noted.

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