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Questions and Answers

Which of the following is the substance formed as a direct result of a chemical reaction?

  • Resistance
  • Substrate
  • Product (correct)
  • Reactant

A company wants to determine the amount of paint needed to coat a spherical tank. Which measurement is most relevant?

  • Volume
  • Surface Area (correct)
  • Surface
  • Concentration

If salt is dissolved in water, what is the salt referred to as?

  • Solute (correct)
  • Solvent
  • Substance
  • Solid

In a solution of sugar and water, where water is in greater quantity, what is the water called?

<p>Solvent (B)</p> Signup and view all the answers

Which term describes a form of matter with a defined composition and unique properties?

<p>Substance (C)</p> Signup and view all the answers

When assessing reaction kinetics, how does the frequency of molecular collisions influence the overall reaction rate?

<p>TRUE (B)</p> Signup and view all the answers

For a chemical reaction to successfully yield products, which conditions must be simultaneously satisfied?

<p>Both collision with proper orientation and sufficient activation energy (C)</p> Signup and view all the answers

A collision between reactant molecules fails to produce any product. How is this type of collision generally characterized?

<p>Ineffective (B)</p> Signup and view all the answers

Why are a greater number of reactant molecules described as being 'more effective' at higher temperatures?

<p>Increased molecular collisions provide more opportunities for effective collisions. (B)</p> Signup and view all the answers

What is the term that describes the process of accelerating a chemical reaction through the addition of a catalyst?

<p>Catalysis (B)</p> Signup and view all the answers

Identify the type of catalysis that occurs when the catalyst and reactants are present in the same phase.

<p>Homogeneous catalysis (C)</p> Signup and view all the answers

Which of the following terms refers to the catalysts found in living systems?

<p>Enzymes (C)</p> Signup and view all the answers

Which of the following statements accurately describes the Second Law of Thermodynamics?

<p>For any spontaneous process, the entropy of the universe increases. (D)</p> Signup and view all the answers

Which thermodynamic property quantifies the degree of disorder or randomness in a system?

<p>Entropy (A)</p> Signup and view all the answers

Under which conditions will entropy decrease?

<p>A liquid changes to solid. (D)</p> Signup and view all the answers

What happens to the temperature and entropy when heat is added to a pure liquid?

<p>Increases and the entropy increases. (B)</p> Signup and view all the answers

Which of the following changes would NOT typically increase the rate of a chemical reaction?

<p>Increasing the volume of the reaction vessel without adding more reactants. (C)</p> Signup and view all the answers

Consider the reaction between zinc (Zn) and hydrochloric acid (HCl). Which factor, under typical lab conditions, would LEAST affect the rate of this reaction, assuming excess acid is already present?

<p>Total amount of hydrochloric acid used. (B)</p> Signup and view all the answers

Activation energy is best described as the minimum amount of energy required to:

<p>Break the bonds between the reacting molecules. (D)</p> Signup and view all the answers

A candle burns more rapidly inside an open jar compared to open air primarily due to:

<p>A higher concentration of oxygen available inside the jar. (B)</p> Signup and view all the answers

According to collision theory, what is the expected effect on the frequency of collisions when the concentration of reactants is doubled?

<p>The collision frequency increases. (D)</p> Signup and view all the answers

Which of the following best describes the outcome when molecules collide with both sufficient energy and proper orientation?

<p>Effective collision. (D)</p> Signup and view all the answers

How does a higher concentration of reactants generally affect the frequency of collisions between reactant molecules?

<p>More frequent collisions. (D)</p> Signup and view all the answers

Which statement best describes the fundamental idea behind collision theory?

<p>For a chemical reaction to occur, reacting particles must collide with one another. (C)</p> Signup and view all the answers

Under standard conditions, will water at room temperature spontaneously decompose into hydrogen and oxygen gas?

<p>Spontaneous in the reverse direction (B)</p> Signup and view all the answers

Calculate the entropy change when 60.0g of Hg(l) freezes at its normal freezing point of –38.9 °C, given that the molar enthalpy of fusion is 2.29 kJ/mol and the molar mass of Hg is 200.59 g/mol.

<p>– 2.64 J/K (D)</p> Signup and view all the answers

What is the entropy change when 60.0g of Al(s) freezes at its normal freezing point of 660.3°C, given that the molar enthalpy of fusion is 8.66 kJ/mol and the molar mass of Al is 26.98 g/mol?

<p>– 17.2 J/K (C)</p> Signup and view all the answers

Determine the entropy change of the system when 60.0g of Au(s) freezes at its normal freezing point of 1063°C, given the molar enthalpy of fusion is 13.2 kJ/mol and the molar mass of Gold is 197 g/mol.

<p>– 4.31 J/K (D)</p> Signup and view all the answers

Which type of molecular motion involves the movement of the entire molecule from one location to another?

<p>Translational (A)</p> Signup and view all the answers

What term describes the periodic motion of atoms within a molecule?

<p>Vibrational (C)</p> Signup and view all the answers

How does the amount of heat added to a system relate to the system's capacity?

<p>Can increase the system's internal energy. (A)</p> Signup and view all the answers

In a closed system, which scenario would result in an increase in entropy?

<p>A spontaneous chemical reaction producing gaseous products from solid reactants (B)</p> Signup and view all the answers

In a closed thermodynamic system, what combination of changes is impossible according to the second law of thermodynamics?

<p>Increase the temperature, decrease internal energy, and do external work. (B)</p> Signup and view all the answers

Which of the following statements accurately reflects the implications of the second law of thermodynamics regarding heat flow?

<p>Heat cannot flow from cold to hot without external energy. (B)</p> Signup and view all the answers

Why are heat engines, such as jet engines, more efficient when operated at higher temperatures?

<p>High temperatures allow for greater expansion of gases, extracting more work. (C)</p> Signup and view all the answers

According to thermodynamics, what is the natural tendency of processes in isolated systems?

<p>From higher order to lower order. (B)</p> Signup and view all the answers

How does an increase in entropy within a system typically affect the energy distribution and order within that system?

<p>Becomes less ordered. (D)</p> Signup and view all the answers

Calculate the entropy change when 103 g of mercury (Hg) freezes at its normal freezing point of -38.9 C, given that the molar enthalpy of fusion (Hfusion) is 2.29 kJ/mol and the molar mass of Hg is 200.59 g/mol.

<p>-5.97 J/K (D)</p> Signup and view all the answers

Determine the entropy change of the system when 155 g of gold (Au) solidifies at its normal freezing point of 1063C. The molar enthalpy of fusion (Hfusion) for gold is 13.2 kJ/mol, and its molar mass is 197 g/mol.

<p>-7.77 J/K (C)</p> Signup and view all the answers

When 85.0g of solid aluminum freezes at its normal freezing point, what is the change in entropy of the system? Molar mass of Al = 26.98 g/mol, $ΔH_{fusion}$ = 8.66 kJ/mol.

<p>– 32.7 J/K (C)</p> Signup and view all the answers

Given that copper has a normal freezing point of 1085°C and a molar enthalpy of fusion of 13.2 kJ/mol, what is the entropy change of the system when 65.0g of solid copper freezes? Molar mass of Cu = 63.55 g/mol.

<p>– 7.88 J/K (D)</p> Signup and view all the answers

Aluminum has a molar enthalpy of fusion ($ΔH_{fusion}$) of 8.66 kJ/mol and a normal freezing point of 660.3°C. Calculate the entropy change when 135 g of solid aluminum freezes. Molar mass of Al = 26.98 g/mol.

<p>– 46.4 J/K (D)</p> Signup and view all the answers

What is the entropy change when 70.0g of solid copper freezes at its normal freezing point of 1085°C, given that the molar enthalpy of fusion ($ΔH_{fusion}$) is 13.2 kJ/mol? Molar mass of Cu = 63.55 g/mol.

<p>– 10.2 J/K (C)</p> Signup and view all the answers

Mercury has a normal freezing point of –38.9 °C and a molar enthalpy of fusion ($ΔH_{fusion}$) of 2.29 kJ/mol. What is the entropy change of the system when 59.0g of liquid mercury freezes? Molar Mass of Hg = 200.59 g/mol.

<p>– 2.87 J/K (A)</p> Signup and view all the answers

Which of the following properties of copper is most responsible for its application in electrical wiring?

<p>Its high electrical conductivity (A)</p> Signup and view all the answers

How does the face-centered cubic crystalline structure of copper contribute to its physical properties?

<p>It allows copper to be highly malleable and ductile. (B)</p> Signup and view all the answers

Why does copper appear reddish in color?

<p>It reflects red and orange light. (C)</p> Signup and view all the answers

Flashcards

Product (Chemistry)

The substance resulting from a chemical reaction.

Surface Area

The measure of the exposed area of a solid object, in square units.

Solute

The substance that gets dissolved in a solution.

Solvent

The component present in the greatest amount in a solution.

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Substance (Chemistry)

Matter with a definite composition and distinct characteristics.

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Reaction Requirements

Reactions need correct alignment and enough energy to happen.

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Ineffective Collision

A collision that fails to form a product.

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Concentrated

More molecules lead to a higher probability for collisions at higher temperatures.

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Activation Energy

Minimum energy for a chemical reaction to occur.

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Collision Theory

States reacting particles must collide to react.

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Concentration and Rate

Increasing concentrations generally increases reaction rate.

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High Concentration

More molecules in the same space; increasing collisions.

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Doubling Concentrations

More molecules increases the collision quantity.

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Catalyst

A substance that speeds up a reaction without being consumed.

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Effective Reactant Molecules

More reactant molecules lead to a greater chance of effective collisions at higher temperatures, increasing reaction rate.

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Homogeneous Catalysis

Catalysis where the catalyst and reactants exist in the same phase (e.g., both liquid or both gas).

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Enzymes

Biological catalysts, usually proteins, that speed up reactions in living systems.

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Second Law of Thermodynamics

In any spontaneous process, the entropy of the universe always increases.

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Entropy

A thermodynamic quantity representing the degree of disorder or randomness in a system.

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Entropy Decrease

Entropy decreases when a liquid changes to solid.

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Heating a Pure Liquid

Temperature increases and entropy increases. Heat adds energy and disorder.

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Spontaneous Decomposition of Water

Water at room temperature does not spontaneously decompose into hydrogen and oxygen gas.

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Entropy Change of Freezing Mercury

The change in entropy (ΔS) when 60.0g of Hg(l) freezes at its normal freezing point is –2.44 J/K. (ΔS = q_rev/T)

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Entropy Change of Freezing Aluminum

The change in entropy (ΔS) when 60.0g of Al(s) freezes at its normal freezing point is –19.2 J/K. (ΔS = q_rev/T)

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Entropy Change of Freezing Gold

The change in entropy (ΔS) when 60.0g of Au(s) freezes at its normal freezing point is –4.31 J/K. (ΔS = q_rev/T)

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Translational Motion

Movement of the entire molecule from one place to another.

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Vibrational Motion

Periodic motion of atoms within a molecule.

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Second Law of Thermodynamics (Heat Flow)

Heat never spontaneously flows from a colder to a hotter object; external energy is needed.

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Heat Engine Efficiency

Engines operating at higher temperatures yield greater efficiency.

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Direction of Natural Processes

Natural processes move from states of order to disorder.

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Entropy and Order

Entropy rises, order decreases.

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Entropy Change Formula

Entropy is calculated using ΔS = Q/T, where Q represents heat transfer and T stands for temperature in Kelvin.

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Entropy Change During Freezing

The entropy change when a substance freezes involves the molar enthalpy of fusion (ΔHfusion) and the freezing point (T).

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Celsius to Kelvin Conversion

Convert Celsius to Kelvin (K = °C + 273.15) to use in thermodynamic calculations.

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Entropy Change Sign (Freezing)

Entropy change when a substance freezes is negative.

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Entropy Change of Freezing

Entropy change during freezing, ΔS = - (n * ΔH_fusion) / T, where n is moles, ΔH_fusion is molar enthalpy of fusion, and T is freezing point in Kelvin.

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Aluminum Freezing Point in Kelvin

Aluminum's freezing point is 660.3°C. Convert to Kelvin.

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Copper Freezing Point in Kelvin

Copper's normal freezing point is 1085°C. Convert to Kelvin for entropy calculations.

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Calculating Moles

To calculate moles, use: moles (n) = mass (g) / molar mass (g/mol).

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Mercury Freezing Point in Kelvin

–38.9 °C. Convert to Kelvin to calculate entropy changes.

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Aluminum Properties

Aluminum has a density lower than those of other common metals, and its normal freezing point is 660.3°C.

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Properties of Copper

Copper is reddish, malleable, ductile, and a good conductor.

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Properties of Gold

Gold is an excellent conductor of heat and electricity and is a soft, yellow metal.

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Study Notes

Chemical Reactions

  • A chemical reaction occurs when two substances combine to form a new substance.
  • The measure of the change in concentration of reactants and products is the activation rate.
  • A reactant is a substance or particle that enters into and is altered during a chemical reaction.
  • Concentration refers to the number of particles in a given solution volume.
  • Reaction rate measures how fast or slow a reaction occurs.
  • For a chemical reaction, particles must collide with enough energy.
  • Humidity does not affect the rate of a chemical reaction, but concentration, particle size, and temperature do.
  • Placing products in iced water slows down a chemical reaction.
  • A change of size isn't evidence of a chemical reaction, the absorption or liberation of heat and a change of color are.
  • Temperature measures the hotness or coldness of a substance.
  • A product is the substance formed from a chemical reaction.
  • Surface area is how much exposed area a solid object has in square units.
  • A solute is the substance dissolved in a solution.
  • A solvent is the component present in the greatest amount in a solution.
  • A compound is a form of matter with definite composition and characteristics.
  • The rate at which particles collide impacts the overall reaction rate.
  • Proper collisions need proper orientation and sufficient energy.
  • A collision that doesn't result in product formation is an ineffective collision.
  • Greater numbers of reactant molecules at higher temperatures makes them more energetic.
  • A lesser number of reactant molecules means there is a lesser probability for collisions.

Conditions for Reactions

  • Both proper orientation and sufficient energy must be present.
  • Increasing volume does not increase reaction rate; increasing temperature, adding a catalyst, and increasing concentration does.

Factors Affecting Reactive Rate

  • When dissolving zinc (Zn) in hydrochloric acid (HCl) and adding pieces of zinc, the amount of hydrochloric acid does affect the process.

Activation Energy

  • Activation energy is required to form bonds between product molecules.

External Factors

  • When a candle burns faster in an open jar, it is due to the increased oxygen concentration.
  • Doubling concentrations increases collisions.

Collisions

  • Molecules collide with energy and proper orientation to form a proper collision.
  • With high concentration, there are more collisions.
  • Collision theory states that reacting particles must collide for a chemical reaction. A collision that does not result is an ineffective collision.
  • Increasing reactant molecules makes them more energetic at higher temperatures.
  • Catalysis speeds up a reaction by using a catalyst
  • Homogenous catalysis occurs when a catalyst and reactant are in the same physical state.
  • Enzymes are known as catalyst in all living systems.

Thermodynamics

  • The Second Law of Thermodynamics says energy cannot be created nor destroyed.
  • Enthalpy is the thermodynamic quantity that describes disorder in a system.
  • Entropy decreases when a liquid changes to solid.
  • When heat is added to a pure liquid, the temperature increases and the entropy decreases.
  • When a piece of metal at 150°C is put in water at 40°C the water getting hotter is spontaneous.
  • Water at room temperature decomposing into hydrogen and oxygen gas is not spontaneous.

Elemental Properties

  • Entropy change cannot be determined with the information given for the reaction.
  • Mercury, Hg, is a silvery liquid at room temperature with a normal freezing point of -38.9 °C. Its molar enthalpy of fusion is ΔH fusion = 2.29 kJ/mol
  • Aluminum has a density about one third that of steel, with a normal freezing point of 660.3°C. Its molar enthalpy of fusion is ΔH fusion = 8.66 kJ/mol.
  • Gold is an excellent conductor of heat and electricity and the most malleable and ductile element. A single gram of it can be flattened into a thin sheet of gold. The normal freezing point of gold is at 1063°C, with an enthalpy of fusion of is ∆H fusio=13.2 kJ/mol
  • The entropy change for a metal freezing at its normal freezing point cannot be determined.

Molecular Motion

  • Translational motion is the movement of the entire molecule.
  • Vibrational motion is periodic motion of atoms within a molecule.

Heat Exchange

  • When heat is added to a system, temperature, internal energy, and external work all increase.
  • Heat cannot flow from cold to hot without external energy.
  • Heat engines are more efficient at high temperatures.
  • Natural processes move from higher to lower order.
  • As entropy increases, energy becomes less ordered.

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