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Questions and Answers
Which of the following is the substance formed as a direct result of a chemical reaction?
Which of the following is the substance formed as a direct result of a chemical reaction?
- Resistance
- Substrate
- Product (correct)
- Reactant
A company wants to determine the amount of paint needed to coat a spherical tank. Which measurement is most relevant?
A company wants to determine the amount of paint needed to coat a spherical tank. Which measurement is most relevant?
- Volume
- Surface Area (correct)
- Surface
- Concentration
If salt is dissolved in water, what is the salt referred to as?
If salt is dissolved in water, what is the salt referred to as?
- Solute (correct)
- Solvent
- Substance
- Solid
In a solution of sugar and water, where water is in greater quantity, what is the water called?
In a solution of sugar and water, where water is in greater quantity, what is the water called?
Which term describes a form of matter with a defined composition and unique properties?
Which term describes a form of matter with a defined composition and unique properties?
When assessing reaction kinetics, how does the frequency of molecular collisions influence the overall reaction rate?
When assessing reaction kinetics, how does the frequency of molecular collisions influence the overall reaction rate?
For a chemical reaction to successfully yield products, which conditions must be simultaneously satisfied?
For a chemical reaction to successfully yield products, which conditions must be simultaneously satisfied?
A collision between reactant molecules fails to produce any product. How is this type of collision generally characterized?
A collision between reactant molecules fails to produce any product. How is this type of collision generally characterized?
Why are a greater number of reactant molecules described as being 'more effective' at higher temperatures?
Why are a greater number of reactant molecules described as being 'more effective' at higher temperatures?
What is the term that describes the process of accelerating a chemical reaction through the addition of a catalyst?
What is the term that describes the process of accelerating a chemical reaction through the addition of a catalyst?
Identify the type of catalysis that occurs when the catalyst and reactants are present in the same phase.
Identify the type of catalysis that occurs when the catalyst and reactants are present in the same phase.
Which of the following terms refers to the catalysts found in living systems?
Which of the following terms refers to the catalysts found in living systems?
Which of the following statements accurately describes the Second Law of Thermodynamics?
Which of the following statements accurately describes the Second Law of Thermodynamics?
Which thermodynamic property quantifies the degree of disorder or randomness in a system?
Which thermodynamic property quantifies the degree of disorder or randomness in a system?
Under which conditions will entropy decrease?
Under which conditions will entropy decrease?
What happens to the temperature and entropy when heat is added to a pure liquid?
What happens to the temperature and entropy when heat is added to a pure liquid?
Which of the following changes would NOT typically increase the rate of a chemical reaction?
Which of the following changes would NOT typically increase the rate of a chemical reaction?
Consider the reaction between zinc (Zn) and hydrochloric acid (HCl). Which factor, under typical lab conditions, would LEAST affect the rate of this reaction, assuming excess acid is already present?
Consider the reaction between zinc (Zn) and hydrochloric acid (HCl). Which factor, under typical lab conditions, would LEAST affect the rate of this reaction, assuming excess acid is already present?
Activation energy is best described as the minimum amount of energy required to:
Activation energy is best described as the minimum amount of energy required to:
A candle burns more rapidly inside an open jar compared to open air primarily due to:
A candle burns more rapidly inside an open jar compared to open air primarily due to:
According to collision theory, what is the expected effect on the frequency of collisions when the concentration of reactants is doubled?
According to collision theory, what is the expected effect on the frequency of collisions when the concentration of reactants is doubled?
Which of the following best describes the outcome when molecules collide with both sufficient energy and proper orientation?
Which of the following best describes the outcome when molecules collide with both sufficient energy and proper orientation?
How does a higher concentration of reactants generally affect the frequency of collisions between reactant molecules?
How does a higher concentration of reactants generally affect the frequency of collisions between reactant molecules?
Which statement best describes the fundamental idea behind collision theory?
Which statement best describes the fundamental idea behind collision theory?
Under standard conditions, will water at room temperature spontaneously decompose into hydrogen and oxygen gas?
Under standard conditions, will water at room temperature spontaneously decompose into hydrogen and oxygen gas?
Calculate the entropy change when 60.0g of Hg(l) freezes at its normal freezing point of –38.9 °C, given that the molar enthalpy of fusion is 2.29 kJ/mol and the molar mass of Hg is 200.59 g/mol.
Calculate the entropy change when 60.0g of Hg(l) freezes at its normal freezing point of –38.9 °C, given that the molar enthalpy of fusion is 2.29 kJ/mol and the molar mass of Hg is 200.59 g/mol.
What is the entropy change when 60.0g of Al(s) freezes at its normal freezing point of 660.3°C, given that the molar enthalpy of fusion is 8.66 kJ/mol and the molar mass of Al is 26.98 g/mol?
What is the entropy change when 60.0g of Al(s) freezes at its normal freezing point of 660.3°C, given that the molar enthalpy of fusion is 8.66 kJ/mol and the molar mass of Al is 26.98 g/mol?
Determine the entropy change of the system when 60.0g of Au(s) freezes at its normal freezing point of 1063°C, given the molar enthalpy of fusion is 13.2 kJ/mol and the molar mass of Gold is 197 g/mol.
Determine the entropy change of the system when 60.0g of Au(s) freezes at its normal freezing point of 1063°C, given the molar enthalpy of fusion is 13.2 kJ/mol and the molar mass of Gold is 197 g/mol.
Which type of molecular motion involves the movement of the entire molecule from one location to another?
Which type of molecular motion involves the movement of the entire molecule from one location to another?
What term describes the periodic motion of atoms within a molecule?
What term describes the periodic motion of atoms within a molecule?
How does the amount of heat added to a system relate to the system's capacity?
How does the amount of heat added to a system relate to the system's capacity?
In a closed system, which scenario would result in an increase in entropy?
In a closed system, which scenario would result in an increase in entropy?
In a closed thermodynamic system, what combination of changes is impossible according to the second law of thermodynamics?
In a closed thermodynamic system, what combination of changes is impossible according to the second law of thermodynamics?
Which of the following statements accurately reflects the implications of the second law of thermodynamics regarding heat flow?
Which of the following statements accurately reflects the implications of the second law of thermodynamics regarding heat flow?
Why are heat engines, such as jet engines, more efficient when operated at higher temperatures?
Why are heat engines, such as jet engines, more efficient when operated at higher temperatures?
According to thermodynamics, what is the natural tendency of processes in isolated systems?
According to thermodynamics, what is the natural tendency of processes in isolated systems?
How does an increase in entropy within a system typically affect the energy distribution and order within that system?
How does an increase in entropy within a system typically affect the energy distribution and order within that system?
Calculate the entropy change when 103 g of mercury (Hg) freezes at its normal freezing point of -38.9 C, given that the molar enthalpy of fusion (Hfusion) is 2.29 kJ/mol and the molar mass of Hg is 200.59 g/mol.
Calculate the entropy change when 103 g of mercury (Hg) freezes at its normal freezing point of -38.9 C, given that the molar enthalpy of fusion (Hfusion) is 2.29 kJ/mol and the molar mass of Hg is 200.59 g/mol.
Determine the entropy change of the system when 155 g of gold (Au) solidifies at its normal freezing point of 1063C. The molar enthalpy of fusion (Hfusion) for gold is 13.2 kJ/mol, and its molar mass is 197 g/mol.
Determine the entropy change of the system when 155 g of gold (Au) solidifies at its normal freezing point of 1063C. The molar enthalpy of fusion (Hfusion) for gold is 13.2 kJ/mol, and its molar mass is 197 g/mol.
When 85.0g of solid aluminum freezes at its normal freezing point, what is the change in entropy of the system? Molar mass of Al = 26.98 g/mol, $ΔH_{fusion}$ = 8.66 kJ/mol.
When 85.0g of solid aluminum freezes at its normal freezing point, what is the change in entropy of the system? Molar mass of Al = 26.98 g/mol, $ΔH_{fusion}$ = 8.66 kJ/mol.
Given that copper has a normal freezing point of 1085°C and a molar enthalpy of fusion of 13.2 kJ/mol, what is the entropy change of the system when 65.0g of solid copper freezes? Molar mass of Cu = 63.55 g/mol.
Given that copper has a normal freezing point of 1085°C and a molar enthalpy of fusion of 13.2 kJ/mol, what is the entropy change of the system when 65.0g of solid copper freezes? Molar mass of Cu = 63.55 g/mol.
Aluminum has a molar enthalpy of fusion ($ΔH_{fusion}$) of 8.66 kJ/mol and a normal freezing point of 660.3°C. Calculate the entropy change when 135 g of solid aluminum freezes. Molar mass of Al = 26.98 g/mol.
Aluminum has a molar enthalpy of fusion ($ΔH_{fusion}$) of 8.66 kJ/mol and a normal freezing point of 660.3°C. Calculate the entropy change when 135 g of solid aluminum freezes. Molar mass of Al = 26.98 g/mol.
What is the entropy change when 70.0g of solid copper freezes at its normal freezing point of 1085°C, given that the molar enthalpy of fusion ($ΔH_{fusion}$) is 13.2 kJ/mol? Molar mass of Cu = 63.55 g/mol.
What is the entropy change when 70.0g of solid copper freezes at its normal freezing point of 1085°C, given that the molar enthalpy of fusion ($ΔH_{fusion}$) is 13.2 kJ/mol? Molar mass of Cu = 63.55 g/mol.
Mercury has a normal freezing point of –38.9 °C and a molar enthalpy of fusion ($ΔH_{fusion}$) of 2.29 kJ/mol. What is the entropy change of the system when 59.0g of liquid mercury freezes? Molar Mass of Hg = 200.59 g/mol.
Mercury has a normal freezing point of –38.9 °C and a molar enthalpy of fusion ($ΔH_{fusion}$) of 2.29 kJ/mol. What is the entropy change of the system when 59.0g of liquid mercury freezes? Molar Mass of Hg = 200.59 g/mol.
Which of the following properties of copper is most responsible for its application in electrical wiring?
Which of the following properties of copper is most responsible for its application in electrical wiring?
How does the face-centered cubic crystalline structure of copper contribute to its physical properties?
How does the face-centered cubic crystalline structure of copper contribute to its physical properties?
Why does copper appear reddish in color?
Why does copper appear reddish in color?
Flashcards
Product (Chemistry)
Product (Chemistry)
The substance resulting from a chemical reaction.
Surface Area
Surface Area
The measure of the exposed area of a solid object, in square units.
Solute
Solute
The substance that gets dissolved in a solution.
Solvent
Solvent
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Substance (Chemistry)
Substance (Chemistry)
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Reaction Requirements
Reaction Requirements
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Ineffective Collision
Ineffective Collision
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Concentrated
Concentrated
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Activation Energy
Activation Energy
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Collision Theory
Collision Theory
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Concentration and Rate
Concentration and Rate
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High Concentration
High Concentration
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Doubling Concentrations
Doubling Concentrations
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Catalyst
Catalyst
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Effective Reactant Molecules
Effective Reactant Molecules
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Homogeneous Catalysis
Homogeneous Catalysis
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Enzymes
Enzymes
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Second Law of Thermodynamics
Second Law of Thermodynamics
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Entropy
Entropy
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Entropy Decrease
Entropy Decrease
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Heating a Pure Liquid
Heating a Pure Liquid
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Spontaneous Decomposition of Water
Spontaneous Decomposition of Water
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Entropy Change of Freezing Mercury
Entropy Change of Freezing Mercury
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Entropy Change of Freezing Aluminum
Entropy Change of Freezing Aluminum
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Entropy Change of Freezing Gold
Entropy Change of Freezing Gold
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Translational Motion
Translational Motion
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Vibrational Motion
Vibrational Motion
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Second Law of Thermodynamics (Heat Flow)
Second Law of Thermodynamics (Heat Flow)
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Heat Engine Efficiency
Heat Engine Efficiency
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Direction of Natural Processes
Direction of Natural Processes
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Entropy and Order
Entropy and Order
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Entropy Change Formula
Entropy Change Formula
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Entropy Change During Freezing
Entropy Change During Freezing
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Celsius to Kelvin Conversion
Celsius to Kelvin Conversion
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Entropy Change Sign (Freezing)
Entropy Change Sign (Freezing)
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Entropy Change of Freezing
Entropy Change of Freezing
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Aluminum Freezing Point in Kelvin
Aluminum Freezing Point in Kelvin
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Copper Freezing Point in Kelvin
Copper Freezing Point in Kelvin
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Calculating Moles
Calculating Moles
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Mercury Freezing Point in Kelvin
Mercury Freezing Point in Kelvin
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Aluminum Properties
Aluminum Properties
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Properties of Copper
Properties of Copper
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Properties of Gold
Properties of Gold
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Study Notes
Chemical Reactions
- A chemical reaction occurs when two substances combine to form a new substance.
- The measure of the change in concentration of reactants and products is the activation rate.
- A reactant is a substance or particle that enters into and is altered during a chemical reaction.
- Concentration refers to the number of particles in a given solution volume.
- Reaction rate measures how fast or slow a reaction occurs.
- For a chemical reaction, particles must collide with enough energy.
- Humidity does not affect the rate of a chemical reaction, but concentration, particle size, and temperature do.
- Placing products in iced water slows down a chemical reaction.
- A change of size isn't evidence of a chemical reaction, the absorption or liberation of heat and a change of color are.
- Temperature measures the hotness or coldness of a substance.
- A product is the substance formed from a chemical reaction.
- Surface area is how much exposed area a solid object has in square units.
- A solute is the substance dissolved in a solution.
- A solvent is the component present in the greatest amount in a solution.
- A compound is a form of matter with definite composition and characteristics.
- The rate at which particles collide impacts the overall reaction rate.
- Proper collisions need proper orientation and sufficient energy.
- A collision that doesn't result in product formation is an ineffective collision.
- Greater numbers of reactant molecules at higher temperatures makes them more energetic.
- A lesser number of reactant molecules means there is a lesser probability for collisions.
Conditions for Reactions
- Both proper orientation and sufficient energy must be present.
- Increasing volume does not increase reaction rate; increasing temperature, adding a catalyst, and increasing concentration does.
Factors Affecting Reactive Rate
- When dissolving zinc (Zn) in hydrochloric acid (HCl) and adding pieces of zinc, the amount of hydrochloric acid does affect the process.
Activation Energy
- Activation energy is required to form bonds between product molecules.
External Factors
- When a candle burns faster in an open jar, it is due to the increased oxygen concentration.
- Doubling concentrations increases collisions.
Collisions
- Molecules collide with energy and proper orientation to form a proper collision.
- With high concentration, there are more collisions.
- Collision theory states that reacting particles must collide for a chemical reaction. A collision that does not result is an ineffective collision.
- Increasing reactant molecules makes them more energetic at higher temperatures.
- Catalysis speeds up a reaction by using a catalyst
- Homogenous catalysis occurs when a catalyst and reactant are in the same physical state.
- Enzymes are known as catalyst in all living systems.
Thermodynamics
- The Second Law of Thermodynamics says energy cannot be created nor destroyed.
- Enthalpy is the thermodynamic quantity that describes disorder in a system.
- Entropy decreases when a liquid changes to solid.
- When heat is added to a pure liquid, the temperature increases and the entropy decreases.
- When a piece of metal at 150°C is put in water at 40°C the water getting hotter is spontaneous.
- Water at room temperature decomposing into hydrogen and oxygen gas is not spontaneous.
Elemental Properties
- Entropy change cannot be determined with the information given for the reaction.
- Mercury, Hg, is a silvery liquid at room temperature with a normal freezing point of -38.9 °C. Its molar enthalpy of fusion is ΔH fusion = 2.29 kJ/mol
- Aluminum has a density about one third that of steel, with a normal freezing point of 660.3°C. Its molar enthalpy of fusion is ΔH fusion = 8.66 kJ/mol.
- Gold is an excellent conductor of heat and electricity and the most malleable and ductile element. A single gram of it can be flattened into a thin sheet of gold. The normal freezing point of gold is at 1063°C, with an enthalpy of fusion of is ∆H fusio=13.2 kJ/mol
- The entropy change for a metal freezing at its normal freezing point cannot be determined.
Molecular Motion
- Translational motion is the movement of the entire molecule.
- Vibrational motion is periodic motion of atoms within a molecule.
Heat Exchange
- When heat is added to a system, temperature, internal energy, and external work all increase.
- Heat cannot flow from cold to hot without external energy.
- Heat engines are more efficient at high temperatures.
- Natural processes move from higher to lower order.
- As entropy increases, energy becomes less ordered.
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