Summary

This document explains the changes in states of matter, such as melting, boiling, and vaporization. It focuses on the concepts of kinetic energy, forces of attraction, and latent heat, using examples like ice melting and water boiling. It's ideal for a secondary school science class.

Full Transcript

Start heating the beaker on a low flame. Note the temperature when the ice starts melting. Note the temperature when all the ice has converted into water. Record your observations for this conversion of solid to liquid state. Now, put a glass rod in the beaker and heat while stirring till the water...

Start heating the beaker on a low flame. Note the temperature when the ice starts melting. Note the temperature when all the ice has converted into water. Record your observations for this conversion of solid to liquid state. Now, put a glass rod in the beaker and heat while stirring till the water starts boiling. Keep a careful eye on the thermometer reading till most of the water has vaporised. Record your observations for the conversion of water in the liquid state to the gaseous state. On increasing the temperature of solids, the kinetic energy of the particles increases. Due to the increase in kinetic energy, the particles start vibrating with greater speed. The energy supplied by heat overcomes the forces of attraction between the particles. The particles leave their fixed positions and start moving more freely. A stage is reached when the solid melts and is converted to a liquid. The minimum temperature at which a solid melts to become a liquid at the atmospheric pressure is called its melting point. The melting point of a solid is an indication of the strength of the force of attraction between its particles. The melting point of ice is 273.15 K*. The process of melting, that is, change of solid state into liquid state is also known as fusion. When a solid melts, its temperature remains the same, so where does the heat energy go? You must have observed, during the experiment of melting, that the temperature of the system does not change after the melting point is reached, till all the ice melts. This happens even though we continue to heat the beaker, that is, we continue to supply heat. This heat gets used up in changing the state by overcoming the forces of attraction between the particles. As this heat energy is absorbed by ice without showing any rise in temperature, it is considered that it gets hidden into the contents of the beaker and is known as the latent heat. The word latent means hidden. The amount of heat energy that is required to change 1 kg of a solid into liquid at atmospheric pressure at its melting point is known as the latent heat of fusion. So, particles in water at 0oC (273 K) have more energy as compared to particles in ice at the same temperature. When we supply heat energy to water, particles start moving even faster. At a certain temperature, a point is reached when the particles have enough energy to break free from the forces of attraction of each other. At this temperature the liquid starts changing into gas. The temperature at which a liquid starts boiling at the atmospheric pressure is known as its boiling point. Boiling is a bulk phenomenon. Particles from the bulk of the liquid gain enough energy to change into the vapour state. For water this temperature is 373 K (100oC = 273 + 100 = 373 K). Can you define the latent heat of vaporisation? Do it in the same way as we have defined the latent heat of fusion. Particles in steam, that is, water vapour at 373 K (1000 C) have more energy than water at the same temperature. This is because particles in steam have absorbed extra energy in the form of latent heat of vaporisation. So, we infer that the state of matter can be changed into another state by changing the temperature. We have learnt that substances around us change state from solid to liquid and from liquid to gas on application of heat. But there *Note: Kelvin is the SI unit of temperature, 0o C =273.15 K. For convenience, we take 0o C = 273 K after rounding off the decimal. To change a temperature on the Kelvin scale to the Celsius scale you have to subtract 273 from the given temperature, and to convert a temperature on the Celsius scale to the Kelvin scale you have to add 273 to the given temperature. M AT T E R IN 7 O U R S U R R O U N D I N GS Rationalised 2023-24

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