Shapes of Molecules Practice Questions PDF
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This document contains practice questions and answers about the shapes of molecules, covering concepts like bond angles, lone pairs and the central atom. It is designed to test the understanding of chemical bonding as it relates to molecular geometry, and it includes explanations to help solidify concepts.
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1. What determines the shape of a simple molecule? * (A) The number of atoms in the molecule * (B) The number of electron pairs around the central atom * (C) The electronegativity of the atoms * (D) The size of the atoms 2. What is meant by a "lone pair" of electrons? * (A) A pair of electrons shar...
1. What determines the shape of a simple molecule? * (A) The number of atoms in the molecule * (B) The number of electron pairs around the central atom * (C) The electronegativity of the atoms * (D) The size of the atoms 2. What is meant by a "lone pair" of electrons? * (A) A pair of electrons shared between two atoms * (B) A pair of electrons not involved in bonding, belonging to one atom * (C) A single electron involved in bonding * (D) A pair of electrons transferred from one atom to another 3. Do lone pairs or bonding pairs of electrons repel more? * (A) Bonding pairs * (B) Lone pairs * (C) They repel equally * (D) Neither repel 4. What is the shape of a molecule with 2 bonding pairs and 0 lone pairs around the central atom? * (A) Linear * (B) Trigonal planar * (C) Tetrahedral * (D) Bent 5. What is the shape of a molecule with 3 bonding pairs and 0 lone pairs around the central atom? * (A) Linear * (B) Trigonal planar * (C) Tetrahedral * (D) Trigonal pyramidal 6. What is the shape of a molecule with 4 bonding pairs and 0 lone pairs around the central atom? * (A) Linear * (B) Trigonal planar * (C) Tetrahedral * (D) Square planar 7. What is the shape of a molecule with 2 bonding pairs and 2 lone pairs around the central atom? * (A) Linear * (B) Bent * (C) Tetrahedral * (D) Trigonal planar 8. What is the shape of a molecule with 3 bonding pairs and 1 lone pair around the central atom? * (A) Tetrahedral * (B) Trigonal planar * (C) Trigonal pyramidal * (D) Bent 9. What is the approximate bond angle in a linear molecule? * (A) 90° * (B) 109.5° * (C) 120° * (D) 180° 10. What is the approximate bond angle in a trigonal planar molecule? * (A) 90° * (B) 109.5° * (C) 120° * (D) 180° 11. What is the approximate bond angle in a tetrahedral molecule? * (A) 90° * (B) 109.5° * (C) 120° * (D) 180° 12. What is the approximate H-O-H bond angle in a water molecule? * (A) 104.5° * (B) 107° * (C) 109.5° * (D) 180° 13. What is the approximate H-N-H bond angle in an ammonia molecule? * (A) 104.5° * (B) 107° * (C) 109.5° * (D) 120° 14. What is the shape of a CO₂ molecule? * (A) Linear *(B) Bent *(C) Tetrahedral *(D) Trigonal Pyramidal 15. What is the shape of a BF₃ molecule? * (A) Linear * (B) Trigonal planar * (C) Tetrahedral * (D) Trigonal pyramidal 16. What is the shape of a CH₄ molecule? * (A) Linear * (B) Trigonal planar * (C) Tetrahedral * (D) Trigonal pyramidal 17. What is the shape of a NH₃ molecule? * (A) Linear * (B) Trigonal planar * (C) Tetrahedral * (D) Trigonal pyramidal 18. What is the shape of a H₂O molecule? * (A) Linear * (B) Bent *(C) Tetrahedral *(D) Trigonal pyramidal 19. Lone pairs of electrons reduce the bond angle by approximately how many degrees *per lone pair*? * (A) 1° * (B) 2.5° * (C) 5° * (D) 10° 20. Which of the following best explains why lone pairs reduce bond angles? * (A) Lone pairs are smaller than bonding pairs. * (B) Lone pairs are closer to the nucleus and repel more strongly. * (C) Bonding pairs are closer to the nucleus and repel more strongly. * (D) Lone pairs are further from the nucleus. Answers and Explanations 1. Answer: (B) The number of electron pairs around the central atom Explanation: Electron pairs (both bonding and lone pairs) repel each other, determining the shape. 2. Answer: (B) A pair of electrons not involved in bonding, belonging to one atom Explanation: This is the de nition of a lone pair. 3. Answer: (B) Lone pairs Explanation: Lone pairs are held closer to the central atom's nucleus and exert a greater repulsive force. 4. Answer: (A) Linear Explanation: Two electron pairs arrange themselves as far apart as possible (180°). 5. Answer: (B) Trigonal planar Explanation: Three electron pairs arrange themselves 120° apart in a at triangle. 6. Answer: (C) Tetrahedral Explanation: Four electron pairs arrange themselves in a tetrahedron (109.5° angles). 7. Answer: (B) Bent Explanation: The two lone pairs repel the bonding pairs, reducing the bond angle from 109.5° to approximately 104.5°. 8. Answer: (C) Trigonal pyramidal Explanation: The lone pair repels the three bonding pairs, creating a fl fi pyramid shape with a bond angle of about 107°. 9. Answer: (D) 180° Explanation: This is the angle that maximizes the distance between two electron pairs. 10. Answer: (C) 120° Explanation: This is the angle that maximizes the distance between three electron pairs in a plane. 11. Answer: (B) 109.5° Explanation: This is the characteristic bond angle in a tetrahedral arrangement. 12. Answer: (A) 104.5° Explanation: The two lone pairs on the oxygen atom reduce the bond angle from the ideal tetrahedral angle. 13. Answer: (B) 107° Explanation: The one lone pair on the nitrogen atom reduces the bond angle from the ideal tetrahedral angle. 14. Answer (A) Linear Explanation: 2 double bonds, no lone pairs. 15. Answer: (B) Trigonal planar Explanation: Three bonding pairs, no lone pairs. 16. Answer (C) Tetrahedral Explanation: 4 bonding pairs, 0 lone pairs. 17. Answer (D) Trigonal pyramidal Explanation: 3 bonding pairs and 1 lone pair. 18. Answer (B) Bent Explanation: 2 bonding pairs and 2 lone pairs. 19. Answer: (B) 2.5° Explanation: This is the approximate reduction in bond angle per lone pair, according to the documents. 20. Answer: (B) Lone pairs are closer to the nucleus and repel more strongly. Explanation: This is the key reason why lone pairs have a greater repulsive effect than bonding pairs. Powered by pmfm.ai Request Support