Summary

This document is a set of notes on reaction mechanisms in organic chemistry.

Full Transcript

# Reaction At Benzym ## Reaction At Benzym - **Br** - **NH2/NH3** How many types of produced form?? - Ratio of form product Intermediate - * - * - NH2 - ③ NH₂ NH₂ - * - * -2 - + ## Will form away from Group ### CHOYE - **-dive** LEDG ### LIVE - **-Live** EWS - Chaye - Form - Nearto...

# Reaction At Benzym ## Reaction At Benzym - **Br** - **NH2/NH3** How many types of produced form?? - Ratio of form product Intermediate - * - * - NH2 - ③ NH₂ NH₂ - * - * -2 - + ## Will form away from Group ### CHOYE - **-dive** LEDG ### LIVE - **-Live** EWS - Chaye - Form - Nearto - E.W.G. - **Br** - **NH2** - **H** - Intermediate - **GF.D.G** - **e**. - **NH2** - **G=F.W.G.** - **NH2** # For the Determination of E.D.G4F.W.G. We mainly focus on Inductive effect only. (Note:- do not consider Resonance as on effect) - **Feim** - **Ome** - **OM GE.W.G.** - **Br** - **WH/NH3**, 77 - **But in combenzy we we treet i tas** - **ew.G. as it show-I effect** - **Va Meta** - **(6) Para** - **(c) ortho** - **(वा पता नहरी।** - **Me** - **NH** - **OMP** # In case of Benzyne - **Step1 - form of benzyne Wing Acidic Hydrogen** - **Step2 - Breaking of Benzym in Such a way that Carbonanion is stable** - **Step3 - Carbonanion React with [E+) & if Et is not given it will abstract tit** # - **FIT** - **Mon Acidic** - **O Me** - **O Me** - **NH2** - **Led Meta** - **(6) Para** - **(c) ortho** - **(d) पता नही** - **Br** - **Ht** - **OM** - **NH2** # - * O - **O Me** - **Br** - **NH2/NH3** - **OMe+F.W.G.** - **NH2** - **OMe** - **NH2** - **Para** - **Me** - **O Me** - **Br** - **O2H+** - **NH2/NH3** - **[I+]** - **NH2** - **O** - **NH2** # JAM 2018 - **n** - **H** - **H** - **NH2/ NH₂** - **(c)** - **(a)** - **(b) NH₂** - **(d)** # - **0** - **CN** - **CN** - **O** # - **NGP** - **Benzym PPF** - **7-8 photos** - **Cs & Clayden** - **with Solution** - **JAM/NIG** - **NIG** - **form ofbenzyn** - **PDF Pgno lo Generation** # - **for Nt Gate only** - **Pleas Jam wale Ise Na dekh** - **Pgno. 17, 18, 21** - **122,26, 30** - **31-35** - **39, 38, 37, 36** - **NETGATE** - **even net** - **4 Gate** - **Just Go through** - **वाले भीtry** - **ना करे।** # - **(a)** - **2** - **NH** - **NH** - **e** - **RH₂/NH3** - **(d)** - **H** - **(c)** - **NH₂** - **NH** - **2** - **O** - **H** # - **dyes** - **CN** - **σ** - **0-5℃** - **slightly** - **Banc** - **slightly** - **Acidic** - **NH2** - **N=N** - **N=N** - **୦** - **୦** - **OH** - **Color ??** - **Color??** # - **HOMEWORK** - **B-Napthol** - **O** - **O** - **OH** - **F+** - **O** - **O** - **OH** - **α-Napthol** - **O** - **OH** - **O** - **F+** - **O** - **O** - **OH** # - **SN²+** - **SN² + Carbocation नही बनेगा** - **(Prime Conjugat Addition** - **Br** - **Good for SM²** - **NaI IDMSO** - **Cond=SN²** - **Nu** # - **Br** - **M** - **Br** - **S** # Then all add depends - **SN¹** - **Allylic Requirement** - **alkem** - **Nucleophil** - **Stability of product** - **Stability of alkene** - **lowerigy, H₂O/ROM** - **Mox hinderealsice preffer** - **Hish emyy** - **OR, IT, OH, Br, CN** - **less hindered side React** # - **2** - **NaIlOMSO** - **I** - **Path 1** - **Path 2** - **Mat/DMSO** - **I** # Organo Copper - **Gillman Reyent Ro Culi** - **fet e Rich Pon** - **RCU** - **always choon Sp2 Path Remember** - **Major** - **Cu** # - **The End** - **Smiles** - **PS** - **🙂🙂🙂🙂🙂🙂🙂🙂🙂🙂** - **❤️❤️❤️** - **🚩🚩🚩**

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