Week 1-2 Chemistry Review PDF
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This document covers the development of the atomic theory, including the ideas of important scientists like Democritus and John Dalton. It also discusses the formation of elements and the different types of bonding.
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Week 1 extreme energy and temperature. The Big Bang: The universe Elements formed: expanded from a hot, dense state. ○ Hydrogen (H)...
Week 1 extreme energy and temperature. The Big Bang: The universe Elements formed: expanded from a hot, dense state. ○ Hydrogen (H) ○ Helium (He) 1. Expansion and Cooling: As the ○ Small amounts of universe expanded, it cooled. Lithium (Li) and 2. Particle Energy: The higher the Beryllium (Be). temperature, the more energetic the particles. Isotopes: 3. Element Identity: An element’s identity is determined by the Atoms of the same element number of protons it has. with different atomic masses (same protons, different Formation of Light and Heavy neutrons). Elements Light Elements: Formed during the Big Bang or Primordial Heavier Elements Nucleosynthesis. Formed through Stellar Heavy Elements: Formed in Nucleosynthesis inside stars. Stellar Nucleosynthesis (in High density and temperature stars). in the star’s core enable fusion for creating heavy elements like Nucleosynthesis Silicon and Iron. Definition: The process that creates atomic nuclei from protons and neutrons. Fusion Pathways for Heavy Elements: Light Elements Formed in the early universe 1. Proton-Proton Fusion when protons and neutrons 2. Carbon-Nitrogen-Oxygen fused in a process called (CNO) Cycle nuclear fusion due to the 3. Triple Alpha Process: Fuses Helium nuclei into Week 2 heavier elements. Democritus Neutron Capture & Supernova Matter is made of indivisible particles called atoms. Neutron Capture: Forms Atomos = "uncuttable" or elements heavier than iron by "indivisible" in Greek. adding neutrons to existing Atoms are solid, indestructible, nuclei. and separated by empty space Supernova: A massive (void). explosion that creates heavy Speculation: elements like Gold and ○ Sweet substances have Uranium. These elements smooth atoms. cannot be formed by fusion in ○ Bitter substances have stars due to the immense energy sharp atoms. required. ○ Atoms in liquids are slippery (flow easily), while in solids, they stick Atomic Number & Element together. Synthesis Modern Connection: Atoms today are still the smallest unit Atomic Number determines an of matter, but we understand element’s identity. their structure with protons, Nuclear Transmutation: neutrons, and electrons. Changing one element into another by changing the Aristotle number of protons. Rejected Democritus' atomic theory. His theory of the four elements Technetium was the first (Fire, Air, Water, Earth) was artificial element. accepted for over 2000 years. Empedocles' Experiment Suggested that all matter is a C. Structure of the Atom mix of the four elements. Experiment: Atom: Smallest unit of matter. ○ Stick burns (contains Composed of protons, neutrons, Fire). and electrons. ○ Residue is left (Earth). Subatomic Particles: ○ Residue is damp (Water). ○ Smoke is produced (Air). 1. Proton: Positive charge, in nucleus, defines the element. 2. Neutron: No charge, same mass as protons, in nucleus. B. Development of the Atomic 3. Electron: Negative charge, Theory outside nucleus, moves in John Dalton (1800s) energy levels or orbitals. Revived atomic theory. Dalton's Atomic Theory: D. Atomic Numbers and Mass 1. Matter is made of indivisible atoms. Atomic Number = Number of 2. Atoms combine in fixed protons. ratios to form Atomic Mass = Protons + compounds. Neutrons. Neutron Calculation = Atomic Alchemical Elements Mass – Atomic Number. Alchemy: Early chemistry; Examples: alchemists tried to turn base metals into gold. Chlorine (Cl): Atomic number They discovered lab techniques 17, mass number 35. Neutrons like distillation, sublimation, = 35 – 17 = 18. crystallization, and filtration. Carbon (C): Atomic number 6, mass number 12. Neutrons = 12 – 6 = 6. E.Scientists and Their Discoveries numbers. Joseph John Thompson Week 3 Cathode Ray Experiment: Discovered electrons as A. Chemical Bonding negatively charged particles. Proposed the Plum Pudding 1. IONIC BOND Model: Atoms have a positive A strong attraction between “soup” with electrons scattered positive and negative ions. inside. Ionic Compound: Compounds Ernest Rutherford held together by ionic bonds, usually formed between metals Gold Foil Experiment: Showed (which lose electrons) and atoms are mostly empty space, nonmetals (which gain with a dense nucleus. electrons). Discovered the nucleus Cations: Atoms that lose contains positive charge electrons and become positively (protons). charged. Anions: Atoms that gain electrons and become Niels Bohr negatively charged. Proposed that electrons move in Example: NaCl (Sodium Chloride). orbits around the nucleus, similar to planets around the sun. 2. COVALENT BOND Henry Moseley A bond where two atoms share valence electrons, typically Proved that elements are between nonmetals. defined by atomic number, not Covalent Compound: A atomic weight. compound where atoms are Helped reorganize the Periodic held together by covalent Table based on atomic bonds. Types of Covalent Bonds: These forces affect the physical properties of molecular compounds. Polar Covalent Bond: Electrons are shared unequally, leading to 1. London Dispersion Forces: slight positive and negative Weak forces caused by charges. temporary electron distribution. ○ Why Oxygen attracts Example: CH4 (Methane). electrons more than 2. Dipole-Dipole Forces: Hydrogen: Oxygen’s Attraction between positive and nucleus has more negative ends of polar protons, attracting the molecules. Example: HCl. electrons more strongly. 3. Hydrogen Bonding: Special ○ Example: H2O (Water). dipole-dipole interaction Nonpolar Covalent Bond: involving H and electronegative Electrons are shared equally, atoms like N, O, or F. Stronger and the molecule remains than dipole-dipole. Example: neutral. H2O. ○ Example: O2 (Oxygen 4. Ion-Dipole Forces: Attraction molecule). between an ion and the partial charge of a polar molecule. Example: NaCl in water. 3. Molecular Polarity Polar Molecule: One end is C. Biological Molecules slightly positive, and the other end is slightly negative (due to 1. Carbohydrates: Organic unequal electron sharing). molecules that provide energy Dipole: A molecule with two (e.g., glucose). Two types: opposite electrical charges ○ Simple Sugars: Easily (positive and negative). processed, like monosaccharides and disaccharides. B. Intermolecular Forces ○ Complex Sugars: Polysaccharides made up of linked sugars, like starch (stored form of Collision Theory: Chemical reactions sugar in plants). occur when particles collide with 2. Lipids: Non-water soluble sufficient energy and in the correct molecules that play roles in orientation. energy storage, insulation, and forming cellular membranes. Factors for collision to lead to ○ Types: Fats, steroids, a reaction: waxes. 1. Collision: Particles must ○ Saturated vs. physically collide. Unsaturated: Saturated 2. Correct Orientation: fats are solid at room Particles must align in a temperature; unsaturated way that allows for the are liquid. breaking of bonds. 3. Proteins: Made from amino 3. Sufficient Energy: acids, essential for structure, Particles need enough transport, and movement. energy to break existing ○ Peptide Bond: Links bonds. amino acids in a chain. ○ Example Functions: Movement: Actin Chemical Reactions and myosin in muscles. A chemical reaction involves Transport: reactants (substances that start the Hemoglobin in red reaction) and products (new blood cells. substances formed). 4. Nucleic Acids: Made of nucleotides. DNA and RNA store genetic information. Catalysts: Week 4 - 5 Definition: Substances that speed up a chemical reaction Chemical Changes and Collision without being consumed. Theory Maxwell-Boltzmann Distribution: A graph showing the energy distribution of particles in a system. It shows Limiting Reactant: The how many particles have reactant that is completely used sufficient energy to overcome up first, determining the the activation energy needed amount of product formed. for a reaction. Excess Reagents: Reactants that are not fully used up by the end of the reaction. Factors Affecting the Rate of Stoichiometry: Chemical Reactions: Establishes mole and mass 1. Activation Energy: relationships between reactants ○ Minimum energy needed and products to determine the for a reaction to occur. quantity of products produced 2. Temperature: in a reaction. ○ Higher temperature increases particle movement, leading to more collisions and faster reactions. 3. Concentration: ○ More particles per Steps in Solving Stoichiometric volume leads to more Calculations: frequent collisions, speeding up the reaction. 4. Surface Area: ○ Greater surface area allows more particles to be exposed and react, speeding up the reaction. Limiting Reactants & Products Formation Energy Forms and Power Plants 2. Solar Power: Energy from sunlight. Energy: Example: The ability to do work and Calatagan Solar exists in different forms like Farm (Batangas) electrical and chemical energy. 3. Wind Power: Energy from wind. Example: Bangui Windmills (Ilocos Norte) Power Plants: 4. Geothermal: Energy from the Earth's heat. Facilities that generate Example: electricity by converting Malitbog primary energy into electrical Geothermal Power energy. Common sources Station (Leyte) include: 5. Biomass: Energy from ○ Coal, Natural Gas, organic materials like Renewable Resources plants and animals. Example: San Carlos Biopower Renewable vs. Non-Renewable (Negros Resources Occidental) Renewable Resources: Non-Renewable Resources: Sources that can be Resources that cannot be replenished naturally. replenished quickly Examples include: 1. Coal 1. Hydroelectric Power: 2. Oil Energy from flowing 3. Natural Gas water. These are primarily used for Example: Pulanai generating electricity. Hydropower Plant (Bukidnon) Goodluck!!