Organic Chemistry Notes PDF

# Subject: Halogenation of Alkane Date: 11 ## Initiation - Free radical propagation ## # Stability of Free radical - 3°>2°>1° ## Date: 11 ## Subject: - if no hv, no reaction - $CH_3CH_2CH_3 + Cl_2$ → $CH_3CH_2CH_2 + CH_3CHCH_3$ - 1-chloropropene 2-chloropropane - $Cl_2$ → $2Cl$ - $CH_3CH_2CH_2 +...

# Subject: Halogenation of Alkane Date: 11 ## Initiation - Free radical propagation ## # Stability of Free radical - 3°>2°>1° ## Date: 11 ## Subject: - if no hv, no reaction - $CH_3CH_2CH_3 + Cl_2$ → $CH_3CH_2CH_2 + CH_3CHCH_3$ - 1-chloropropene 2-chloropropane - $Cl_2$ → $2Cl$ - $CH_3CH_2CH_2 + [Cl]$ → $CH_3CH_2CH_2Cl + HCl$ - $αH= 2$ - $CH_3-CH-CH_2$ - $CH_3-CH_2-CH_2$ - %60 - %40 ## Date: 1/1 ## Assignment - Neopentane - 30 pentane - $CH_3$ - $CH_3-C-CH_2-Cl$ - $CH_3$ - 1-chloro- 2,2 dimethyl Propane - $CH_3$ - $CH_3-C-CH_2 -CH_3$ - 2-chloro-2 kmethyle butan - mech? - more studity? - why? ## Date: 11 ## Subject: Cyclopropane - $C_3H_6 + Cl_2$ - $Cl_2$ - *(z)/(cis)* - *(E)/(trans)* - *Geminal* - *vecinal* ## Date: 11 ## Subject: Alkeenes - = bond - unsaturated - $sp^2$ - at least 2C - $C_nH_{2n}$ - addition reaction - $CH_2 = CH_2$ ethylene - $CH_3CH = CH_2$ Propylene - $CH_3 - C = CH_2$ Isobutylene - $CH_3$ ## Date: 11 ## Subject: - primary / normal - Iso/ secndry - neo/ ter - parent name - suffix → - prefix→ - exo- - 5,2-dimethyle-2-heptene - 4-chloro-1-pentene ## Date: 11 ## Subject: - $C=C$ - Vinyle - $CH_3-C=C$ - Allyl