Hydrocarbon Formula List Solutions PDF

. The Science Privates Hub TSPH NAME: CHEMISTRY CLASSROOM TEST TOPIC: ALKYNE WORKSHEET Q-D Write the molecular formula: a) Alkanes - CnH2n+2 b) Alkenes - CnH2n c) Alkynes - CnH2n-2 Q-2] Hydrocarbons containing one triple bond between two carbon atoms are called Alkynes. Q-3] The first stable membe...

. The Science Privates Hub TSPH NAME: CHEMISTRY CLASSROOM TEST TOPIC: ALKYNE WORKSHEET Q-D Write the molecular formula: a) Alkanes - CnH2n+2 b) Alkenes - CnH2n c) Alkynes - CnH2n-2 Q-2] Hydrocarbons containing one triple bond between two carbon atoms are called Alkynes. Q-3] The first stable member of Alkyne is Acetylene/Ethyne Q-4] Write the number of σ and π bond in Ethyne (Acetylene). H-C≡C-H 9-5] The alkynes in which both the sides of triple bond are same are called as Symmetrical Alkynes. Q-6] Hybridisation of Alkynes → SP Q-7] Bond Angle of Alkynes → 180° Q-8] Geometry of Alkynes→ Linear Q-9] Write the Uses of Alkynes: ① Ethyne is used in preparation of Ethanal., acetone, acetic acid. ② manufacture of polymers, Synthetic rubber, Synthetic fibre, plastic etc. ③ For artificial ripening of fruits. ④ In Oxy-acetylene flame for welding and cutting of metals. Q-10] Complete the following table. | Structure | Common Name | IUPAC | |--------------|-------------------|--------------| | CH≡CH | Acetylene | Ethyne | | CH3-C≡CH | Methyl acetylene | Propyne | | CH3-CH2-C≡CH | Ethylacetylene | But-1-yne | | HC≡C-CH3 | Dimethylacetylere. | But-2-yne | | CH≡C-CH2-C≡CH | - | Penta-1,4-diyne | | CH≡C-CH2-C≡CH | - | Pent-1-en-4-yne | | CH3-C≡C-CH2-CH3 | - | Pent-3-en-1-yne | | CH3-C≡C-CH2-C≡CH | - | Hexa-1,4-diyne | | CH≡C-C≡C-C≡CH | - | Hexa-1,3,5-triyne | | CH2=CH-C≡C-CH3 | - | Penta-1,3-diyne | Q-11] Complete the following reactions and name them. a) 6CH₄ + 2O₂ → 2CO₂ + 10H₂O + heat b) CaC₂ + H₂O → Ca(OH)₂ + HC≡CH c) BeC₂ + H₂O → CH₄ + Be(OH)₂ d) Mg₂C₃ + H₂O → 2Mg(OH)₂ + CH₃-C≡CH e) HC≡CH + HBr → HC=CH f) CH₃-C≡CH + HCl → g) CH₃-CH₂-C≡CH + HBr → h) CH₃-CH₂-CH₂-Cl + KOH → i) CH₃-CH₂-COONa → j) COOH → k) CH₃-C≡C-CH₂-CH₃ → l) CH₃-C≡CH + 2Br₂ → m) CH₃-CH₂-C≡CH + 2HBr → n) CH3-C≡C-CH3 → CH₃-CH₃ + H₂C=CH3 o) CH3-C≡C-CH3 → p) CH3-C≡C-CH3 → q) CH3-C≡C-CH3 → r) CH3-C≡C-CH3 → s) CH3-C≡C-CH3 → t) CH3-C≡C-CH3 + HOH → u) CH3-C≡C-CH3 + HOH → v) H₂C = CH₂ → w) F₂C=CF₂ → x) HC≡CH → Q-12) Compare the Acidic character. a) HC≡CH, CH₂=CH₂, CH₃-CH₃ b) CHECH, CH₃-C≡CH, CH₃-CH₂=CH. . The Science Privates Hub TSPH NAME: CHEMISTRY CLASSROOM WORKSHEET (Formula List) TOPIC: REACTIONS AND MOP OF ALKANES. • Complete the following reactions and name them. 1) CH₃-CH=CH₂ + H₂ → CH₃-CH₂-CH₃ 2) CH₃-C≡C-H + 2H₂ → CH₃-CH₂-CH₃ 3) CH₃-CH₂-Cl + [H] → CH₃-CH₃ + HCl 4) CH₃-CH₂-CH₂-Cl+ [H] → CH₃-CH₂-CH₃ + HCl 5) CH₃-CH₂-Br + 2Na + Br-CH₂-CH₃ → CH₃-CH₂-CH₂-CH₃ + 2NaBr 6) CH₃-CH₂-CH₂-COÒNG + NaOH → CH₃-CH₂-CH₃ + Na₂CO₃ 7) 2CH₃COONa + H₂O → CH₃-CH₃ + 2CO₂+H₂ 8) CH₃-CH₂-COÒNa → CH₃-CH₃ 9) CH₃-CH₂-Cl → CH₃-CH₃ . Complete the following reactions and name them. REACTIONS OF ALKENES CH₄ + O₂ → CO₂ + 2H₂O CH₄ + O₂ → CCS) + 2H₂O(l) CH₄ → 2CH₃OH CH₄ → HCHO +H₂O CH₄ → CO + 3H₂ CH₃-CH₂-CH₂-CH₂-CH₃ → CH₃-CH-CH₂-CH₂-CH₃ CH₃ CH₃-CH₂-CH₂-CH₂-CH₃ → CH₃-CH₂-CH-CH₂-CH₃ CH₃ n-Heptane → Benzene C₁₂H₂₆ → C₇H₁₆ + C₅H₁₀ + Other Dodecane The Science Privates Hub TSPH NAME: CLASSROOM WORKSHEET (Formula list) TOPIC: Reactions of Alkene. Complete the following reactions and name the product. (AODITION REACTIONS) CH3 CH3-C=CH2 Isobutylene H₂/R. Ni Hydrogenation Br2/cclu Halogenation •i] Cold.conc HOH Hydration HBr, H2O2 H2504 Anti - Markovnikov's Rule HBr Markovnikov's Rule. (OXIDATION) Hot kmnoul OR K2Cr2O7, Acidic medium CH3 CH3-CFCH₂ (Baeyer's Reagent) Cold.kmnoy Alkaline medium 03 H20/Zn Dust CH3 CH3-CH-CH 3 2-methyl propane CH3 CH3-C-CH2 1 Br ( Βγ 2 methyl 1,2-dibromo propare CH3 CH3-C-CH3 + - Butyl alcohol 1 OH CH3-CH-CH2 Br. CH3 1 CH3 1-Bromo-3-methyl propane CH3-C-CH3 ३४ 2-13rom-2-methyl propare My - ¿- CH3 + CM 23 CH3-C-CH3 Acetone 애애 + CH2} CO2+H2O formaldehyde. CH3-C-CH2 2-methyl propylene 0 CH3 유 glycol or 2- nethyl propan 1,2diol. CH3-C-CH3 + CH₂ +2no Acetone formaldehyde. • Write the general and IUPAC name of the following Compounds. Formula Common Name JUPAC Name. CH₂C12 :methylene Chloride 2-Ен-сиз 2] C-CH-CH₃ Isopropyl Chloride 2 3)₃--CH₂-Br Isobutyl Bromide Y Dichloromethane Chloro propane 1-Bromo-2-methyl Propane 1-chloro-2,2-di- methyl propane. CH3 4 CH3-C-Br. Tert-Butyl bromide 1 CH3 CHO 5] CH3 CH3-CH2-C1 Heo-pentyl chloride. 1-chloro 2-2 di methyl CH 3 6] CH2=CH-C} Vinyl chloride Propane 1-chloroethere 7] CH2=CH-CH2- Br Allyl Bromide. 3-Bromo-propene. Chloro ethyne. CH≡C-CI Chloro-Acetylene CHI 0 Benzyl Iodide. Iodophenyl methane. 问 I P-Iodo toluene. H.C CI 1-Iodo-4-methyl Benzene or 4-Iodo toluene. Chloro-Benzene or chloro benzene Benzene chloride The Science Privates Hub TSPH CLASSROOM WORKSHEET (Formula List). CHEMISTRY 4 TOPIC: Reactions in Alkenes NAME: • Complete the following reactions and name the product. (ADDITION REACTIONS) CH₃ 1 H₂/RoNi, Hydrogenation Br2/cclu Halogenation. i) cold. Conc. H2SO4ⅱ) HH Hydration HBr, H2O2 4 Anti-markonikov's Rule CH3 methyl cyclohexane CH3 Br BY CH3 애 CH3 BY HBr Markonikov's Rule. (OXIDATION) Hot KMnOy OR ✓ CH₃ K2Cr2O7, & acidic medium C-OH g CF (Baeyer's reagent) CH3 Cold kmnoy Alkaline medium 03 ii) H20/zn dust 0 C-H 15 CH3 BY -on 04. • write the general & IUPAC name of the following Compounds. HO-CH2-CH2-CH3 2CH3-CH-CH3 L OH Propan-1-of Or n-propyl Alcohol. Propan-2-01 OR Isopropyl Alcohol 3 CH3-CH2-CH2-CH2-OH Butan-1-01 OR n-Butanol 4) CH3-CH2-CH-CH3 Butan-2-01 OR Sec-Butyl alcohol OH CH 43 5CH3-C-CH3 OH 6] CH3-CH-CH2-OH - CH CH3 CH3-CH2-C- C-CH2-CH3 OH CH3 2-methyl propan-2-01 OR tert-Butyl alcohol 2-methyl propan-1-01 •Pentan-3-01 OR 3-pentano이. 8 CH3-C-CH2-CH3 -CH2-CH₃ OH 4 • 2-methyl butan-2-01 9] CH3-CH2-CH2-CH2-CH2-애→ Hexan-1-01 10] CH3-CH2-CH-CH2-OH→2-methyl Butanol CH3-CH₂CH₂O애 3,3-dimethyl Butanol CH3 CH3 1 сн₃ 애 ] 0 phenol COOM 13. 0 Benzoic acid Topic: Nomenclature of Benzene Derivative • Write IUPAC / General name of the following Compounds. CI NO2 2] CH3 Chlorobenzene OR Phenyl chloride -Nitrobenzene 3-CH 8 १) H-R Cl. O-chloro benzaldehyde OR NH2-chloro benzaldehyde Benzamide 3- Tert-Butyl benzene 1a] on • Write IUPAC / General name of the following Compounds. CI 1.2-Dichlorobenzene OR O-Dichlorobenzene m-Dinitrobenzene 27년 123 - Dinitrobenzene NO2 NO2 H -P-Bromoiodobenzene 3] 1-Brama-4-iodobenzene Br OR Gr CI Br 1,2,4-Tribromo- benzene Br NO2 1-chloro-2,4- -No₂ dinitrbenzene -CH34-Bromo-1,2 -CH₃ dimethybenzene 1-chloro-phenol Crenomal Name 勾 CH3 Toluene NH2 OH m-chloronitro- ១ -No21-Chloro-3- benzene NH2 5] - Aniline * Benzoic acid 5 CI nitrobenzene O-chloro aniline CH3 CH3 CH3 2-chloroaniline OH 11-CH3 6] Phenol No2 om-nitrotoluene O-xylene 23-Nitrotoluene 애 он O-CH3 7] Acetophenone T 7] 1 0= -P-Bromophenol O-Toluic acid CHO 11 4-Bromophenol o-Cresol Salicylic acid 애 Anisole 127 Br Salicylad OR Benzoylchloride methoxy benzene CH3 P-Xylene 1,4-Dimethyl benzene Pthalic acid TSPH IEE-NEET MHT- Benzophenone Topic: MOP and Reactions of benzene •Complete the following reactions and name the Product. 3CH=CH Red hot irontube Acetylene 873k Benzene Polymerisation 3 CH3-C=CH Propyne -ala 2] CaO + Naон OH 0/+Na2CO3 Decarboxylation CH3 + NaOH Cao A Benzene •Complete the following reactions and name the product.2.мано Red hot iron tube 873K CH3 H₃C 0 2 CH₃ mesitylene CH3 + Na2CO3 Toluene CH3 3+Zn O Benzene Reduction a SH₃ + Zn +Zno Go/VzDs 1 4] 773k 10-20atm O Benzene Aromatisatio CH3 +3C12 CI CI 5+3Cl2 CH3 CI CI Ni 473k +3H2 458k to H2O Ci Benzero hexa- Chloride Gammaxare (BHC) +303 H-몬몬-ㅐ Ozonolysis. Addition Ni +3H2 Cyclohexane Addition 6] glyoxal to * CH + 3H2 458 k to CH +03 473 k C203 Or V205 773k 4 10-20 atm CH3 ZnH2O CH3-18-8-H + TSPH 요요 H-C-C-H LEENEET MNT CEY "H-2-2-4 glyoxanal. + Zno Toluene FC13 + 3HCI Trichloro methyl benzene methyl cychohexane ESR of Benzene Write the major product of the following reactiond and name them. 可 C12 anhy. Alcl Chlorobenzene CH₃ Cl2 anhy-Alci CONH +HCI Halogenation 2] Conc HNO NO2 Nitration CH3 conc H₂SO₄ 0+ H2O Nitrobenzene H2504 3] Conc. Hasou SO3H. Benzenech Sulphurill cox Oleum +H2039 4] CH3-C) CH3 anhy. Alci F.C. 0 5] 0 Sulphonation - Toluene. CH3-C-CI anhy. Alci alkylation L-CH35] CH oleum anhy. CH3 0 + HCI • Write the major product of the the following following P-chlorotoluene 2] CH3 N02 P-Nitrotoluene +H2O. reactions and name them. OCH3 c12 AlCl 3 anhy. Conc. HNO H2504 OCH3 NO2 P-chloro Anisole CI OCH3 P-Nitro anisole OCH 3] CH3-CI OCH [P-methyl Anhy. AlCl3 Anisole OCH3 CH3 OCH3 Anhy. Alcla 1P-methoxy Lacetopbedone С-н Сопандоз Conc. H2SO4 C-CH3 CHO Δ NO2 SO3H P-Toluene Sulphuric 4] CH3 acid. Aich (0) P-xylene CHIC-CI CH₃ anhy. F. C. Acylation Acetophenone Alclz Nitrating Conc CH3 0 mixture Conc. HNO3 + Conc•H₂sayf 2 Electophiles in Chlorination CH FON Nitration Sulphonation So 503 4-methyl +HCl. Propion phenol CH3 5] 6] C-H -- Benzaldehyde 요 -H Brz anhy-AlBrz Benzaldehyde 4 C-H 0 Br m-Nitrobenzaldagle. m-Bromobepzaldehyde TSPH JEK NEET WHTCAT • Convert and Name the product. Benzene to chlorobenzene Anly Alci +C12 4 Benzene ② Benzene to Nitrobenzene + CONC. HONO₂ 0 Chlorobenzeno conc-Hasoy ③Benzene to Benzenesulphonic acid + H₂Soy or Oleum D NO2 Nitrobenzere • Write the major product and name it. OCH3 대국이 C1 CHAnhy Alcl OCH3 CHC-CY- CH₃ Anhy. Alci OCH3 QCH3 C12 Alcls anby. CI OCH3 -CH3 anhy Alcla Anisole CONC HNO3 H2504 HO₂ FH3 CH CH3 CH3 C12 CHICI Alc anhy Benzene CH3 Conc-HNO3 H2804 543 Sulphonic CHC-CI Anhy AlCl3 Toluene CH 요 503H -H -on C-H G-CH Br2 0 0 Br BY AIBT3 AlBY 1 CONG HNO3 H2SO4 -애 Conx HNg H2504 Benzoic 0 0 No acid No 2 ④ Benzene to Ethyl benzene acid 回 C2HS-CI Anhy AlCl3 C2H5 0 ⑤ Benzene to Acetophenone [0] 0 대₃--1 Anhy Alc Ethyl benzene -CH3 Acetophenone ال Benzaldehyde Conc-H₂Soy oleum TSP JEE-NESTM •Complete the missing Links of the reactions and Name the reactions. J 2] 3 160 3대대 Acetylene -ONA Red hot ixon tube 873 k < + NaOH Polymerisation Cao + Cr203/V205 773k 10-20-atm Reaction) Decarboxylation Nasco 3 Aromatisation 0 ] Δ +200 0 +Zn Reduction •Complete the missing links. and name the reactions. 2] 3CH3-C=CH Red hotiron tube ..Pro pyne of the reactions CH3 S KL Polymerisation. CH₃ mesitylene 873k -ONa CH3 NaOH Cao + Sodium Salt of Toluere 3] 2-methyl benzoic acid 回 애 + Zn Δ £43 + Na2CO3 Decorboxylation CH3 + zno Reduction m-Cresol CH 4 ৯ 13 + 3Ch Toluene 0 Chlorination (Addit 5 CH3 Ni CH3 +3H2 458xto ( 473k Hydrogenation methyl cyclohexane 5 CI + 3012 6 1+30 Zn CI Addition of Chlorine CI BHC. + 30.320 H-8-8-H Ozonolysis --troxal 6 Toluene Cr₂03 08 V205 C3 773 k --A--heptane 10-20 atm, heptane CH3 +03 20/20 Toluene CH3-C-CH + 2H-C-C-H Aromatis Sotion Ozonolysis TSP glyoxanal TEENEET MHT • Draw the structure of the following Compounds. chlorobenzene Cl 向 0 2) Nitrobenzene No2 0 3tert-Butyl benzene HC-CH3 F 112-chlorobenzoic acid. •Draw the structure of the following Compounds. 8 Mesitylene - Benzoic acid. -애 H3C CH3 P-xylene - CH3 0 0 C43 0 a] CH3 10] Acetophenone C-CH3 2] Cresol 04 CH3 3 P-toluic acid-COOH -04 CI Naphthalene - 00 10] Anthracene - ORK 11 Phenanthrene - 0 0 12] Benzoyl chloride CH3 4] Salicylic acid. C04 CH3 12) Pyridine C-CI 애 N Pthalic acid NH2 13] Benzamide (-NH2 coon 13] Pyrrole- COOH 0 Phenol 0 OCH3 7 Anisole. 8] Benzaldehyde 0 14] Benzyl chloride 15] Benzyl alcohol. CH2-09 可 同 Salicylatdehyde-8-1 14] Furan CH2-C1 애 15] Pyran #Benzophenone - 16] Thiophene - S • Identify the type of Substituents Ortho-para director activator (O-P-A) Ortho-para deactivator CO-P-D) →Meta-director deactivator (M-D-D) COOM Topic: Directive Influence 12 B A =0 TSPH O-P-A 83-D-D 其辉MKTGT Br NH2 13] M-D-D O-P-D =6 2D-P-A No2 14 8 M-D-D Al O-P-A O-C-CH3 and name the product. O-P-A Anhy. Alca +Cl2 8 O-P-A AO-P-A BM-D-D • Identify Plectrophiles in the following reactions CI M-D-D CIT Chlorobenzene NH-C-CH3 (2). 问 CONC. HONO Conc. Hasou 202 No2t O-P-A Nitrobenzene M-D-D 3] fuming Hasoy SO3H pleum S03 ت M-D-D -대표대로 M-D-D Benzene Sulphonice-acid R-CI R Alkyl Anhy-AlCl3 R--CI ANMAICI R-1 AlCl3 benzene R+ 'Acyl R-+ benzene • Complete the following reactions and name the product CH3 Topic: Reactions in Alkenes • Write the general& IUPAC name of the following Compounds Tho-CH2-CH2-CH3 methyl cyclohexane 2] HS-CH-CH₃ 애 3 HF-CH2-CH2-CH2-OH CH-CH3 애 CH3 (Addition Reactions) H2/R-NIA Hydrogenation Br2/Cc4 CH3 B CH3 Halogenation Br Cad H2Sou in HOH 4] CH3-CH2-CH CH3 hydration -07 1-methyl= Cyclohexenel HBr, H2O2 Anti Markovníkov's Rule CH3 मुट Her CH CH3 markavnikov's Rule CH3 Br --도대 OH (Oxidation) Hot kmnoul C113 OR K2C201. acidic medium 1 CH3 (Baeyer's reagent) cold kMnou Alkaline medium 0 coon CH3 -04 애 C-CH-CH-OH 8HC-C-CH2-CH3 • Propan-1-01 Ion-propyl alcohol • Propan-2-01 Isopropyl alkohol 9] CH3-CH2-CH2-CH2-CH2-OH- -но-зю-но-чо-но го -HO- CB-C 대₂CH₂-0 CH 11] C-C 103 CH3 ii) H20/Zn dust HO & COOH 13 → •Butan-1-01 n-Butanor • Butan-2-01 sec-butyl alcon ol • 2-methyl propan-2-01 itert-Butyl alcohol 2-methyl propan-1-01 Pentan-3-011 3-pentanol 2-methyl Butan-2-01 • Hexan-1-01 2-methyl Butanol 3,3-dimethyl Butan ol Phenol Benzoic acid TSPH JEE-MEET ΜΕΤΑΣΤ ==End of OCR for page 19==