Summary

This document contains a series of practice questions covering various aspects of acids, including carboxylic acids and their reactions. It tests understanding of concepts such as solubility, reactions with different reagents, and the products formed in these reactions. The questions also focus on the general formulas and functional groups of different compounds.

Full Transcript

1. What is the general formula for a carboxylic acid? * A) RCHO * B) RCOR * C) RCOOH * D) RCOOR 2. Which of the following describes the solubility of short-chain carboxylic acids in water? * A) Insoluble * B) Soluble * C) They react violently with water * D) They decompose in water 3. Why are carb...

1. What is the general formula for a carboxylic acid? * A) RCHO * B) RCOR * C) RCOOH * D) RCOOR 2. Which of the following describes the solubility of short-chain carboxylic acids in water? * A) Insoluble * B) Soluble * C) They react violently with water * D) They decompose in water 3. Why are carboxylic acids soluble in water? * A) They are non-polar molecules * B) They form hydrogen bonds with water molecules. * C) They are ionic compounds. * D) They have a low boiling point. 4. Which of the following is the strongest acid? * A) Ethanol * B) Water * C) Phenol * D) Ethanoic acid 5. What is formed when a carboxylic acid reacts with sodium hydroxide? * A) An ester and water * B) A salt and water * C) An alkane and water * D) An alcohol and water 6. What is the product of the reduction of a carboxylic acid using LiAlH4? * A) An aldehyde * B) A primary alcohol * C) A ketone * D) An alkane 7. What are the reagents needed for the esteri cation of a carboxylic acid? fi * A) An alcohol and an acid catalyst * B) An alcohol and a base catalyst * C) An acyl chloride and an alcohol * D) An aldehyde and an alcohol 8. What is the name given to the following compound, CH3COOCH2CH3? * A) Methyl Ethanoate * B) Ethyl Methanoate * C) Ethyl Propanoate * D) Ethyl Ethanoate 9. What are the products of the acid hydrolysis of an ester? * A) A carboxylic acid and an alcohol * B) A salt of a carboxylic acid and an alcohol * C) An acyl chloride and water * D) An amide and water 10. What are the products of the alkaline hydrolysis of an ester? * A) A carboxylic acid and an alcohol * B) A salt of a carboxylic acid and an alcohol * C) An acyl chloride and water * D) An amide and water 11. Which of the following is a use of esters? * A) As a fuel * B) As a plasticiser * C) As a strong acid * D) As an oxidising agent 12. What is the formula of an acyl chloride? * A) RCOCl * B) RCOOH * C) RCl * D) RCOOR 13. What is produced when an acyl chloride reacts with water? * A) A carboxylic acid and hydrogen chloride gas * B) An ester and water * C) An alcohol and hydrogen chloride gas * D) An amide and water 14. What observation is made when an acyl chloride reacts with water? * A) No visible change * B) A silver mirror forms * C) Steamy fumes are produced * D) A yellow precipitate is formed 15. What reagent is used to convert a carboxylic acid to an acyl chloride? * A) Concentrated HCl * B) PCl5 * C) SOCl2 * D) Cl2 16. What type of compound is produced by the reaction between a carboxylic acid and ammonia? * A) An ester * B) A primary amide * C) A secondary amide * D) A nitrile 17. What is the general formula of a primary amide? * A) RCONH2 * B) RCONHR * C) RCONR2 * D) RCN 18. What reagent can be used to convert a primary amide to a nitrile? * A) LiAlH4 * B) P4O10 * C) NaBH4 * D) KCN 19. What is produced from the hydrolysis of a nitrile under acidic conditions? * A) An amide * B) A carboxylic acid * C) An amine * D) An alcohol 20. What is the functional group in a nitrile? * A) -CN * B) -CONH2 * C) -COCl * D) -COOR 21. What are the products when propanamide, CH3CH2CONH2 undergoes acid hydrolysis? * A) Propanoic acid and ammonia * B) Propanoic acid and ammonium chloride * C) Sodium Propanoate and ammonia * D) Propanenitrile and water 22. What is the product when a haloalkane reacts with KCN? * A) An alcohol * B) A nitrile * C) An amine * D) A carboxylic acid 23. What reagent can reduce a nitrile to a primary amine? * A) KCN * B) P4O10 * C) LiAlH4 * D) H2O/H+ 24. Which of the following equations correctly represents the decarboxylation of sodium ethanoate with soda lime? * A) CH3COONa + NaOH → CH4 + Na2CO3 * B) CH3COOH + NaOH → CH4 + Na2CO3 * C) CH3CH2COONa + NaOH → CH3CH3 + Na2CO3 * D) CH3COONa + 2NaOH → CH4 + Na2CO3 + H2O 25. How can benzoic acid be produced from methylbenzene? * A) Re ux with alkaline potassium manganate(VII), followed by acidi cation with HCl. fi fl * B) React directly with concentrated H2SO4 and HNO3 * C) React with chlorine in the presence of UV light * D) React with PCl5 Answers and Explanations: 1. C - RCOOH 2. B - Short-chain carboxylic acids are soluble due to hydrogen bonding. 3. B 4. D - Carboxylic acids are stronger acids than phenols, water, or alcohols. 5. B - Neutralisation reaction. 6. B - LiAlH4 is a strong reducing agent. 7. A - Alcohol + Carboxylic Acid --(Acid Catalyst)--> Ester + Water 8. D 9. A 10. B 11. B 12. A 13. A - Acyl chlorides react violently with water. 14. C The HCl gas produced creates steamy fumes. 15. B - PCl5 (phosphorus pentachloride) in dry ether. 16. B 17. A 18. B 19. B 20. A 21. B Because the hydrolysis is carried out in acidic conditions, the ammonia produced reacts to form the ammonium ion. 22. B 23. C 24. A - Decarboxylation *removes* CO2 from the original molecule. 25. A - Oxidation of the methyl side chain. The acidi cation is crucial to convert the salt to the acid. fi

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