DAT Organic Alkene Reactions PDF

DAT Organic Alkene Reactions Study online at https://quizlet.com/_dhfcwi 1. Hydrohalogena- the addition of HCl or HBr to form an alkyl halide, tion of Alkenes markovnikov addition 2. Halogenation Reagents: Br2, CCl4, anti addition of the halides to form...

DAT Organic Alkene Reactions Study online at https://quizlet.com/_dhfcwi 1. Hydrohalogena- the addition of HCl or HBr to form an alkyl halide, tion of Alkenes markovnikov addition 2. Halogenation Reagents: Br2, CCl4, anti addition of the halides to form two products 3. Hydrobromina- Reagents: HBr, ROOR tion with Anti-markovnikov addition, the halide goes on the least peroxide substituted carbon 4. Hydration Reagents: H3O+, added a Hydroxyl group to the most substituted carbon 5. Bromination in Reagents: Br2 and H2O, Alcohol goes on the more substi- H2O tuted carbon, bromine is on the least substituted carbon 6. Oxymercura- Reagents: 1. Hg(OAc)2, H2O, 2. NaBH4, no rearrange- tion-Demercura- ment tion 7. Hydroboration- Reagents: 1. BH3, THF, 2. H2O2, OH, H2O. Alcohol will Oxidation go on the least substituted carbon, will create anti stereo- chemistry 1/2  DAT Organic Alkene Reactions Study online at https://quizlet.com/_dhfcwi 8. Syn-Dihydroxyla- 1. Oso4 2. H2O2 or KMnO4 (cold), OH-, OH will be a syn tion meso compound 9. Anti-Dihydroxyla- RCO3H, H3O+, anti addition of alcohol tion 10. Addition of alco- CH3OH, H+ hol 11. Bromination in Br2 and CH3OH, anti-addition Alcohol 12. Alkoxymercura- 1. Hg(OAc)2/ROH tion-demurcura- 2. NaBH4 tion Markovnikov addition 13. Epoxidation mCPBA or RCO3H 14. Catalytic Hydro- H2, Pd/C genation 15. Ozonolysis (re- 1. O3 ducing condi- 2. (CH3)2S or Zn/H2O tions) 16. Ozonolysis (ox- 1. O3 2. H2O2 or 1. KMnO4/heat 2. H3O+ idative condi- tions) 2/2