Y10 Chemistry Trilogy: Organic Chemistry & Equilibrium
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Questions and Answers

Which of the following statements best describes the formation of crude oil?

  • Crude oil is formed from the rapid decomposition of volcanic rock under high pressure.
  • Crude oil is the result of the slow decomposition of marine organisms under high pressure and temperature over millions of years. (correct)
  • Crude oil is created from the chemical weathering of sedimentary rocks.
  • Crude oil is synthesized from atmospheric gases through photochemical reactions.

A hydrocarbon is a compound consisting exclusively of carbon and hydrogen atoms.

True (A)

Provide the chemical formula for butane and draw its structural formula.

Chemical formula: $C_4H_{10}$. Structural formula: A four-carbon chain with each carbon atom bonded to enough hydrogen atoms to satisfy its tetravalency.

In fractional distillation, substances are separated based on their different ______ points.

<p>boiling</p> Signup and view all the answers

Match each hydrocarbon trend in crude oil with its correct description:

<p>Boiling Point = Increases with increasing molecular size due to stronger van der Waals forces. Viscosity = Increases with increasing molecular size due to greater intermolecular attractions. Flammability = Decreases with increasing molecular size due to higher energy needed for vaporization.</p> Signup and view all the answers

When a hydrocarbon undergoes complete combustion, what are the primary products formed?

<p>Carbon dioxide and water (C)</p> Signup and view all the answers

Cracking is a process that converts smaller hydrocarbons into larger, less useful molecules.

<p>False (B)</p> Signup and view all the answers

Briefly describe the key differences in the conditions used for steam cracking and catalytic cracking.

<p>Steam cracking uses high temperatures and steam, while catalytic cracking uses lower temperatures and catalysts.</p> Signup and view all the answers

To test for the presence of a double bond in an alkene, you would typically use ______ water, and a positive result is indicated by the ______ of the solution.

<p>bromine, discoloration</p> Signup and view all the answers

In a chemical reaction at equilibrium, what does it mean when the forward and reverse reaction rates are equal?

<p>The net change in concentrations of reactants and products is zero. (A)</p> Signup and view all the answers

Adding a catalyst shifts the equilibrium position to favor the products.

<p>False (B)</p> Signup and view all the answers

State Le Chatelier's principle in your own words.

<p>If a change of condition is applied to a system in equilibrium, the system will shift in a direction that relieves the stress.</p> Signup and view all the answers

According to Le Chatelier's principle, increasing the temperature in an exothermic reaction will shift the equilibrium towards the ______ side.

<p>reactant</p> Signup and view all the answers

Match the change in reaction condition with its effect on the equilibrium of a reversible reaction:

<p>Increase in Reactant Concentration = Shifts equilibrium towards products. Increase in Product Concentration = Shifts equilibrium towards reactants. Increase in Pressure (for gaseous reactions) = Shifts equilibrium towards the side with fewer moles of gas.</p> Signup and view all the answers

For a reaction at equilibrium that produces fewer moles of gas on the product side, how will an increase in pressure affect the equilibrium position?

<p>Shift towards the products (C)</p> Signup and view all the answers

The rate of a chemical reaction is constant and cannot be altered by external factors.

<p>False (B)</p> Signup and view all the answers

Explain how to calculate the rate of a reaction from data or the gradient of a graph.

<p>The rate of reaction can be calculated by determining the change in concentration of a reactant or product over time. This is often found by calculating the slope (gradient) of a concentration vs. time graph.</p> Signup and view all the answers

According to collision theory, for a reaction to occur, reactant particles must collide with sufficient ______ and proper ______.

<p>energy, orientation</p> Signup and view all the answers

Match each factor with its effect on the rate of reaction:

<p>Increased Concentration of Reactants = Increases the rate of reaction by increasing frequency of collisions. Increased Temperature = Increases the rate of reaction by increasing the kinetic energy of particles and collision frequency. Increased Surface Area of Solid Reactants = Increases the rate of reaction by providing more area for collisions. Presence of a Catalyst = Increases the rate of reaction by lowering the activation energy.</p> Signup and view all the answers

How does a catalyst increase the rate of a reaction?

<p>By providing an alternate reaction pathway with a lower activation energy (A)</p> Signup and view all the answers

The Earth's atmosphere has remained constant in composition throughout its entire history.

<p>False (B)</p> Signup and view all the answers

Briefly explain how the Earth's oceans were formed.

<p>Oceans formed from water vapor released by volcanic activity, which condensed as the Earth cooled over millions of years.</p> Signup and view all the answers

The Great Oxidation Event led to a significant ______ in atmospheric carbon dioxide levels and an increase in atmospheric ______ levels.

<p>decrease, oxygen</p> Signup and view all the answers

Match each process with its effect on carbon dioxide levels in the early Earth's atmosphere:

<p>Photosynthesis = Decreased carbon dioxide levels by converting it into organic compounds and oxygen. Formation of Sedimentary Rocks = Decreased carbon dioxide levels through the long-term storage of carbon in minerals like limestone. Ocean Absorption = Decreased carbon dioxide levels by dissolving CO2 in seawater.</p> Signup and view all the answers

What was the primary mechanism for the increase in oxygen levels in the Earth's atmosphere?

<p>Photosynthesis by early cyanobacteria (B)</p> Signup and view all the answers

Nitrogen levels in the atmosphere have decreased significantly over geological time.

<p>False (B)</p> Signup and view all the answers

Explain how levels of nitrogen increased in the Earth's atmosphere over time.

<p>Nitrogen increased due to volcanic outgassing and biological processes such as denitrification. Its inert nature prevents it from being easily removed from the atmosphere.</p> Signup and view all the answers

Which of the following is NOT a direct factor affecting chemical equilibrium?

<p>Catalyst (A)</p> Signup and view all the answers

According to Le Chatelier's principle, adding an inert gas at constant volume will shift the equilibrium position.

<p>False (B)</p> Signup and view all the answers

The rate of reaction typically ______ with an increase in temperature because particles have more ______ energy, leading to more effective collisions.

<p>increases, kinetic</p> Signup and view all the answers

Match the following descriptions with the type of cracking they describe

<p>Steam cracking = Uses high temperatures and steam to break down hydrocarbons Catalytic cracking = Uses lower temperatures and a catalyst to break down hydrocarbons</p> Signup and view all the answers

What best describes chemical equilibrium?

<p>The state where the rates of the forward and reverse reactions are equal (C)</p> Signup and view all the answers

An increase in pressure always favors the side of the equilibrium with more gas molecules.

<p>False (B)</p> Signup and view all the answers

What is the effect of a decrease in temperature on an endothermic reaction at equilibrium?

<p>Decreasing the temperature will shift the equilibrium towards the reactants.</p> Signup and view all the answers

In the early Earth's atmosphere, high levels of volcanic activity contributed primarily to increased concentrations of water and ______.

<p>carbon dioxide</p> Signup and view all the answers

Match the term with its description:

<p>Cracking = A process to break big hydrocarbons into smaller ones Hydrocarbon = A compound consisting only of hydrogen and carbons Alkene = A hydrocarbon with double carbon-carbon bonds</p> Signup and view all the answers

Photosynthesis had what effect on the atmosphere

<p>Increased the proportion of oxygen over time (B)</p> Signup and view all the answers

A hydrocarbon is made of what two elements?

<p>Carbon, Hydrogen (C)</p> Signup and view all the answers

Why did the amount of Nitrogen increase in the atmosphere?

<p>Due to it's inertness, it built up over time (D)</p> Signup and view all the answers

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Flashcards

Formation of crude oil

Crude oil is formed from the remains of plants and animals, mainly plankton, that died millions of years ago and were buried under layers of sediment. Heat and pressure over millions of years transformed them into crude oil.

Hydrocarbon

A hydrocarbon is a compound made of hydrogen and carbon atoms only.

First four alkanes formulas

Methane (CH4), Ethane (C2H6), Propane (C3H8), Butane (C4H10).

Fractional distillation of crude oil

Fractional distillation separates crude oil into fractions based on boiling points. Products include: refinery gas, gasoline, kerosene, diesel, fuel oil, and bitumen.

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Trends in crude oil hydrocarbons

Boiling point and viscosity increase with increasing hydrocarbon chain length. Flammability decreases with increasing chain length.

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Combustion of hydrocarbons

Hydrocarbon + Oxygen -> Carbon Dioxide + Water.

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Cracking

Cracking breaks down large hydrocarbons into smaller, more useful molecules, including alkenes.

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Steam & Catalytic Cracking

Steam cracking uses high temperature and steam. Catalytic cracking uses a catalyst at a lower temperature.

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Test for alkene double bond

Add bromine water to the alkene. If the double bond is present, the bromine water will decolourise from orange to colourless.

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Chemical equilibrium

A state where the rate of forward and reverse reactions are equal, and the concentrations of reactants and products remain constant.

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Factors affecting equilibrium

Temperature, pressure, and concentration affect chemical equilibrium.

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Le Chatelier's principle

If a change of condition is applied to a system in equilibrium, the system will shift in a direction that relieves the stress.

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Increase temperature at equilibrium

If the forward reaction is endothermic, an increase in temperature will shift the equilibrium towards the products. If exothermic, it will favor reactants.

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Decrease temperature at equilibrium

If the forward reaction is endothermic, a decrease in temperature will shift the equilibrium towards the reactants. If exothermic, it will favor products.

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Concentration and equilibrium

Increasing reactant concentration shifts equilibrium towards products; increasing product concentration shifts equilibrium towards reactants.

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Increase pressure

An increase in pressure favors the side with fewer moles of gas.

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Decrease Pressure

A decrease in pressure favors the side with more moles of gas.

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Reaction rate calculation

The rate of a reaction can be calculated from the change in concentration of reactants or products over time.

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Factors affecting rate

The rate of a reaction is affected by concentration, pressure (for gases), surface area, temperature, and catalysts.

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Collision theory

Collision theory states that reactions occur when particles collide with sufficient energy (activation energy) and proper orientation.

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Catalysts

Catalysts increase the rate of reaction by providing an alternative reaction pathway with a lower activation energy.

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Earth's atmosphere evolution.

Volcanic activity released gases, the early atmosphere was mainly carbon dioxide with little to no oxygen. Over time oxygen increased and carbon dioxide levels decreased.

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Ocean formation

Oceans formed as the Earth cooled, allowing water vapor in the atmosphere to condense into liquid water.

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Carbon dioxide decrease

Carbon dioxide levels decreased due to the formation of sedimentary rocks and the absorption by oceans and plants for photosynthesis.

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How oxygen increased

Oxygen levels increased due to photosynthesis by algae and plants.

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How nitrogen increased

Nitrogen levels increased due to the release of nitrogen from volcanic activity. Nitrogen is a very stable gas.

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Study Notes

  • Assessment series 2 for Y10 Chemistry Trilogy includes an online assessment.

C10 Organic Chemistry

  • Crude oil formation should be described.
  • A hydrocarbon should be defined.
  • Structures and chemical formulas for methane, ethane, propane, and butane can be drawn.
  • Fractional distillation and the uses of the produced products can be described.
  • Trends in boiling point, viscosity, and flammability of hydrocarbons in crude oil can be described.
  • Equations to show the combustion of hydrocarbons can be written.
  • Cracking breaks down large hydrocarbons into smaller, more useful molecules including alkenes.
  • Steam cracking and catalytic cracking can be described in terms of general conditions.
  • How to test for the double bond in an alkene can be explained.

Reversible Reactions and Equilibrium

  • Chemical equilibrium can be defined.
  • Factors that affect chemical equilibrium can be described.
  • Le Chatelier's principle can be defined.
  • The effect of an increase in temperature on a reaction at equilibrium can be explained.
  • The effect of a decrease in temperature on a reaction at equilibrium can be explained.
  • How changes in the concentration of reactants and products affect a reaction at equilibrium can be described.
  • The effect of an increase in pressure on a reaction at equilibrium can be explained.
  • The effect of a decrease in pressure on a reaction at equilibrium can be explained.

The Rate and Extent of Chemical Change

  • The rate of a reaction from data or from the gradient of a graph can be calculated.
  • How the rate of reaction is affected by the concentration of reactants in solution can be explained.
  • How the rate of reaction is affected by the pressure of reacting gases can be explained.
  • How the rate of reaction is affected by the surface area of solid reactants can be explained.
  • How the rate of reaction is affected by temperature can be explained.
  • How the rate of reaction is affected by catalysts can be explained.
  • Collision theory can be described.
  • How catalysts increase the rate of a reaction can be explained.

Chemistry of the Atmosphere

  • How the Earth's atmosphere has evolved over time can be described.
  • How the oceans formed can be explained.
  • How levels of carbon dioxide decreased can be explained.
  • How levels of oxygen increased can be explained.
  • How levels of nitrogen increased can be explained.

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Description

This assessment covers Year 10 Chemistry Trilogy, focusing on Organic Chemistry (crude oil, hydrocarbons, fractional distillation, cracking, alkenes) and Reversible Reactions/Equilibrium (factors affecting equilibrium and Le Chatelier's principle).

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