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What are the primary components of wood extractives and their significance?
What are the primary components of wood extractives and their significance?
The primary components are terpenes, resins, fatty acids, and phenols, which play a role in the wood's chemical properties and durability.
How does cellulose differ from hemicellulose in terms of composition?
How does cellulose differ from hemicellulose in terms of composition?
Cellulose consists of repeating units of D-glucose linked by 1,4’-b-glycosidic linkages, while hemicellulose is made up of various sugars including glucose, mannose, and galactose.
What is the significance of the crystalline and amorphous regions in cellulose?
What is the significance of the crystalline and amorphous regions in cellulose?
The crystalline region is impenetrable by solvents, providing structural integrity, while the amorphous region allows easier penetration by solvents and reagents.
How does the percentage of carbohydrates differ between hardwoods and softwoods?
How does the percentage of carbohydrates differ between hardwoods and softwoods?
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Identify the role of lignin in wood structure.
Identify the role of lignin in wood structure.
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What is the principal source of fiber for pulp and paper production?
What is the principal source of fiber for pulp and paper production?
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How do softwoods and hardwoods differ in their compositions?
How do softwoods and hardwoods differ in their compositions?
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What are the primary components found in the cell wall of wood?
What are the primary components found in the cell wall of wood?
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Explain the significance of extractives in wood.
Explain the significance of extractives in wood.
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What characterizes the fiber length in hardwood compared to softwood?
What characterizes the fiber length in hardwood compared to softwood?
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What role does lignin play in the structure of wood?
What role does lignin play in the structure of wood?
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How does the age of a wood plant affect its chemical composition?
How does the age of a wood plant affect its chemical composition?
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What are the differences in the types of trees classified as softwoods and hardwoods?
What are the differences in the types of trees classified as softwoods and hardwoods?
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What are the distinguishing features of Fischer projections compared to Haworth projections?
What are the distinguishing features of Fischer projections compared to Haworth projections?
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What is the significance of the D-configuration in D-glyceraldehyde and D-glucose?
What is the significance of the D-configuration in D-glyceraldehyde and D-glucose?
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Describe the difference between alpha (α) and beta (β) anomers in D-glucose.
Describe the difference between alpha (α) and beta (β) anomers in D-glucose.
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What is the relationship between hemiacetals and acetals in carbohydrate chemistry?
What is the relationship between hemiacetals and acetals in carbohydrate chemistry?
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Explain the role of glycosidic bonds in the formation of starch and glycogen.
Explain the role of glycosidic bonds in the formation of starch and glycogen.
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What contributes to the rigidity of cellulose at a molecular level?
What contributes to the rigidity of cellulose at a molecular level?
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How does mutarotation affect the behavior of α-D-glucose and β-D-glucose in solution?
How does mutarotation affect the behavior of α-D-glucose and β-D-glucose in solution?
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What is the significance of carbon numbering in cyclic forms of monosaccharides?
What is the significance of carbon numbering in cyclic forms of monosaccharides?
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What structural characteristics allow starch and glycogen to be effective energy storage molecules?
What structural characteristics allow starch and glycogen to be effective energy storage molecules?
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Describe the importance of chirality in monosaccharide structures.
Describe the importance of chirality in monosaccharide structures.
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Study Notes
Wood Composition
- Wood = 93% of global virgin fiber supply, primarily for pulp and paper
- 7% of fiber sources are non-wood, including bamboo, bagasse, cereal straw, cotton, linen, jute, hemp, abaca, and sisal, plus synthetic fibers
- Cell walls consist of cellulose and other support polymers
- Polymer chemistry specializes the simple cell structure of xylem, phloem, collenchyma, sclerenchyma, and parenchyma, amongst others
Wood Types
- Softwoods = Conifers/Gymnosperms, needle-leafed
- Hardwoods = Deciduous or Evergreen Angiosperms, broad-leafed
Wood Structure
- Sapwood
- Heartwood
- Dead Bark
- Live Bark
- Cambium Layer
- Growth Rings
- The Pith
- Medullary Rays
Average Composition of Softwood and Hardwood
-
Hardwood:
- 42% Cellulose (long chain molecules, no branching, mainly skeletal polysaccharides)
- 27% Hemicellulose (branched short chain molecules, mainly matrix polysaccharides)
- 28% Lignin (three-dimensional phenolic polymer network)
- 3% Extractives (extraneous substances extractable by neutral organic solvents or steam)
-
Softwood:
- 45% Cellulose
- 30% Hemicellulose
- 20% Lignin
- 5% Extractives
Softwood vs Hardwood
- Average fiber length differs (softwood typically having a longer average fiber length)
- Chemical composition of wood (cellulose, hemicellulose, lignin, pectin, resins, waxes, fatty and fixed oils, cyclitols, tannins, mucilage, and alkaloids) skews toward cellulose, hemicellulose, and lignin in mature woody plants
- Components vary between different woody plants
Wood Composition Breakdown
- Cell wall substances: Insoluble in neutral organic solvents or non-volatile with steam
- Lignin: 21% in hardwoods, 25% in softwoods
- Carbohydrates: 35% hardwoods, 25% softwoods
- Cellulose: 45%, composed of glucose units
- Hemicellulose: Consisting of glucose, mannose, galactose, xylose, and arabinose
Cellulose
- Cellulose is (C₆H₁₀O₅)ₙ
- Polysaccharide of repeating D-glucose units joined by 1,4′-β-glycosidic linkages
- Chains are exclusively linear, encouraging many intra and intermolecular interactions to form a structural polysaccharide of plants
- Two regions exist within cellulose: crystalline (impenetrable by solvents) and amorphous (easily penetrated by solvents and reagents)
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Description
This quiz explores the composition, types, and structure of wood, highlighting the differences between hardwoods and softwoods. It covers the intricate details of wood fiber sources, cell wall composition, and various wood components. Test your knowledge on the essential aspects of wood in the context of pulp and paper production.