Wave-Particle Duality and de Broglie Hypothesis
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Questions and Answers

Which phenomenon provides evidence that the true nature of light requires considering both wave and particle properties?

  • Interference
  • Refraction
  • Diffraction
  • Photoelectric effect (correct)

According to de Broglie's hypothesis, the wavelength associated with a particle is directly proportional to its momentum.

False (B)

What experimental evidence led to the acceptance of de Broglie's hypothesis, confirming the wave properties of particles?

Davisson and Germer experiment

According to Bragg's diffraction law, the condition for constructive interference is given by $d sin θ = nλ$, where d is the inter-atomic spacing, θ is the angle of incidence, n is an integer, and λ is the ________.

<p>wavelength</p> Signup and view all the answers

Match each term with its corresponding description:

<p>de Broglie wavelength = The wavelength associated with a moving particle. Photoelectric effect = The emission of electrons when light shines on a material. Bragg's diffraction = The diffraction of X-rays by crystal lattices. Momentum = Product of mass and velocity.</p> Signup and view all the answers

In the Davisson-Germer experiment, what was the primary purpose of using a nickel crystal?

<p>To scatter electrons (D)</p> Signup and view all the answers

According to de Broglie, if the kinetic energy of particle increases, its wavelength will also increase.

<p>False (B)</p> Signup and view all the answers

What is the relationship between the frequency of a matter wave and the total relativistic energy of the particle it is associated with?

<p>$f = E/h$</p> Signup and view all the answers

What is the significance of the agreement between the calculated wavelength and that derived from Bragg's diffraction law in the context of the de Broglie hypothesis?

<p>It provides evidence supporting the wave nature of electrons, consistent with the de Broglie hypothesis. (A)</p> Signup and view all the answers

A wave packet representing a quantum particle is formed solely through destructive interference of numerous waves in a localized region of space.

<p>False (B)</p> Signup and view all the answers

Explain how the superposition of numerous waves leads to the formation of a wave packet representing a quantum particle. Hint: Consider the roles of constructive and destructive interference.

<p>When numerous waves superpose, they create a region of constructive interference where the amplitudes add up, forming a localized wave packet. Outside this region, destructive interference cancels out the waves, confining the wave packet to a small area, thus representing a quantum particle.</p> Signup and view all the answers

According to classical predictions, what is the effect of oscillating electromagnetic waves on electrons?

<p>Electrons experience oscillations and re-radiate in all directions, and radiation pressure causes acceleration in the direction of wave propagation. Different electrons move at different speeds after the interaction. (C)</p> Signup and view all the answers

In the mathematical representation of two waves, $y_1 = A \cos(k_1x - \omega_1t)$ and $y_2 = A \cos(k_2x - \omega_2t)$, the term $\Delta k$ represents the difference in ______ , while $\Delta \omega$ represents the difference in ______.

<p>wave numbers, angular frequencies</p> Signup and view all the answers

In Compton scattering, the incident photon's energy ($E_o$) is equal to the scattered photon's energy ($E'$) plus the kinetic energy (K) of the electron, represented as $E_o = E' + K$. This equation reflects the principle of energy creation during the collision.

<p>False (B)</p> Signup and view all the answers

Match the mathematical terms with their descriptions in the context of wave packet analysis.

<p>$\Delta k$ = Difference in wave numbers $\Delta \omega$ = Difference in angular frequencies $\frac{\Delta k}{2}x - \frac{\Delta \omega}{2}t$ = Modulation term influencing the envelope of the wave packet $\frac{k_1 + k_2}{2}x - \frac{\omega_1 + \omega_2}{2}t$ = Carrier wave representing the average wave properties within the wave packet</p> Signup and view all the answers

In the context of Compton scattering, what physical quantities are conserved during the interaction between a photon and an electron?

<p>total energy and total linear momentum</p> Signup and view all the answers

The Compton shift equation, which describes the change in wavelength of a photon after scattering from an electron, is given by $λ' - λ_o = \frac{h}{mc}(1 - cos θ)$. In this equation, $θ$ represents the ______ angle of the scattered photon.

<p>scattering</p> Signup and view all the answers

Which of the following equations correctly represents the relativistic relationship between the total energy (E), momentum (p), and rest mass (m) of an electron?

<p>$E = \sqrt{p^2c^2 + m^2c^4}$ (B)</p> Signup and view all the answers

Match the variable with the correct expression in the context of Compton scattering and relativistic equations:

<p>$λ_o$ = Wavelength of the incident photon $p_o$ = Momentum of the incident photon $E'$ = Energy of the scattered photon $γ$ = Relativistic factor $1/\sqrt{1 - v^2/c^2}$</p> Signup and view all the answers

Given that $γ = \frac{1}{\sqrt{1 - \frac{v^2}{c^2}}}$, how does the kinetic energy (K) of an electron relate to its total relativistic energy (E) and rest energy ($mc^2$) in Compton scattering?

<p>K = E - mc^2 (C)</p> Signup and view all the answers

Light exclusively exhibits diffraction and interference phenomena, which can be entirely explained by its particle nature.

<p>False (B)</p> Signup and view all the answers

Which of the following best describes the significance of Planck's constant ($h$) derived from fitting Planck's law to experimental blackbody radiation data?

<p>It represents the smallest unit of energy that can be emitted or absorbed as electromagnetic radiation, demonstrating energy quantization. (A)</p> Signup and view all the answers

According to the Rayleigh-Jeans law, the intensity of radiation emitted by a blackbody decreases as the wavelength approaches zero, preventing the ultraviolet catastrophe.

<p>False (B)</p> Signup and view all the answers

Explain how Planck's hypothesis of quantized energy levels for oscillators in the cavity walls of a blackbody resolves the ultraviolet catastrophe predicted by classical physics.

<p>Planck's hypothesis posits that energy is emitted or absorbed in discrete packets (quanta), limiting the number of high-frequency (short-wavelength) modes that can be excited, thereby preventing the intensity from diverging to infinity as predicted by the Rayleigh-Jeans Law.</p> Signup and view all the answers

According to Stefan's Law, the power radiated by a blackbody is directly proportional to the fourth power of its absolute ______.

<p>temperature</p> Signup and view all the answers

Match the concepts with their descriptions:

<p>Stefan's Law = The total energy radiated per unit surface area of a black body across all wavelengths per unit time is directly proportional to the fourth power of the black body's thermodynamic temperature. Wien's Displacement Law = The black body radiation curve for different temperatures peaks at a wavelength inversely proportional to the temperature. Rayleigh-Jeans Law = An early attempt to describe the spectral radiance of electromagnetic radiation emitted by a black body; fails at short wavelengths. Planck's Law = Describes the spectral density of electromagnetic radiation emitted by a black body in thermal equilibrium at a given temperature; accurately predicts the black body spectrum.</p> Signup and view all the answers

Which of the following statements accurately describes the relationship between the wavelength at which maximum blackbody radiation intensity occurs ($\lambda_m$) and the temperature ($T$) of the blackbody, according to Wien's Displacement Law?

<p>$\lambda_m$ is inversely proportional to $T$. (B)</p> Signup and view all the answers

How does Planck's Law modify the classical understanding of energy emission and absorption in blackbody radiation?

<p>It proposes that energy is emitted or absorbed in discrete packets (quanta) proportional to the frequency of the radiation. (A)</p> Signup and view all the answers

Consider a blackbody at temperature $T_1$ emitting radiation with peak wavelength $\lambda_1$. If the temperature is doubled to $2T_1$, what happens to the new peak wavelength $\lambda_2$?

<p>$\lambda_2 = \lambda_1 / 2$ (it halves) (B)</p> Signup and view all the answers

What is the relationship between group velocity ($v_g$) and phase velocity ($v_p$) described?

<p>$v_g = v_p - \lambda \frac{dv_p}{d\lambda}$ (B)</p> Signup and view all the answers

What is the formula for phase velocity ($v_p$) in terms of angular frequency ($\omega$) and wave number ($k$)?

<p>$v_p = \frac{\omega}{k}$ (B)</p> Signup and view all the answers

The group speed ($v_g$) of a wave packet is always greater than the phase speed ($v_p$) of the individual waves within the packet.

<p>False (B)</p> Signup and view all the answers

In the double-slit experiment, what does the variable 'd' represent in the equation $d \sin \theta = m \lambda$?

<p>slit separation</p> Signup and view all the answers

The relationship between group speed ($v_g$) and particle speed ($u$) indicates that $v_g$ is equal to ____.

<p>u</p> Signup and view all the answers

Match the following terms with their corresponding descriptions:

<p>Phase Speed ($v_p$) = Speed at which the crest of an individual wave moves. Group Speed ($v_g$) = Speed of the wave packet. $\omega$ = Angular frequency. $k$ = Wave number.</p> Signup and view all the answers

Given $\omega = 2 \pi f$ and $k = \frac{2 \pi}{\lambda}$, and knowing $v_p = \frac{\omega}{k}$, which of the following is an alternative expression for $v_p$?

<p>$v_p = f \lambda$ (B)</p> Signup and view all the answers

In the context of the relationship between group speed ($v_g$) and particle speed ($u$), which equation correctly represents the group speed in terms of the derivative of energy ($E$) with respect to momentum ($p$)?

<p>$v_g = \frac{dE}{dp}$ (C)</p> Signup and view all the answers

In the double-slit experiment, increasing the wavelength ($\lambda$) of the electrons used will decrease the separation between the interference fringes observed.

<p>False (B)</p> Signup and view all the answers

According to the material, what variables determine group speed?

<p>$\Delta\omega$ and $\Delta k$</p> Signup and view all the answers

What is the fundamental implication of the Heisenberg uncertainty principle regarding simultaneous measurements of a subatomic particle's position and momentum?

<p>The act of measuring a particle's position inevitably disturbs its momentum, and vice versa, leading to inherent uncertainties. (D)</p> Signup and view all the answers

According to Wien's displacement law, as the temperature of a black body increases, the wavelength at which its emission spectrum peaks shifts towards longer wavelengths.

<p>False (B)</p> Signup and view all the answers

A blackbody emits radiation. If the temperature of the blackbody doubles, by what factor does the total power radiated by the blackbody increase, according to the Stefan-Boltzmann law? Give your answer as a number.

<p>16</p> Signup and view all the answers

In the context of the photoelectric effect, the minimum energy required to remove an electron from a metal surface is known as the ______.

<p>work function</p> Signup and view all the answers

What is the effect on a photon's wavelength when it undergoes Compton scattering and transfers some of its energy to an electron?

<p>The wavelength increases because the photon loses energy. (B)</p> Signup and view all the answers

Which of the following scenarios best illustrates wave-particle duality?

<p>Electrons behaving as particles when detected at a specific location but exhibiting interference patterns that are characteristic of waves. (B)</p> Signup and view all the answers

Match the scientist with their contribution to quantum physics:

<p>Heisenberg = Uncertainty Principle Wien = Displacement Law Stefan = Stefan Constant</p> Signup and view all the answers

What is the relationship between the lifetime of an excited atomic state and the line width ($\Delta f$) of the emitted radiation, as described by the uncertainty principle?

<p>The line width is inversely proportional to the lifetime of the excited state; shorter lifetimes result in broader line widths. (C)</p> Signup and view all the answers

Flashcards

Black-body Radiation

Electromagnetic radiation emitted by a black body.

Stefan's Law

Hotter objects emit more energy per unit area than colder objects.

Wien's Displacement Law

The peak wavelength shifts shorter as temperature increases.

Rayleigh-Jeans Law

Intensity per unit wavelength interval from a blackbody (accurate for long wavelengths).

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Ultraviolet Catastrophe

Prediction of infinite energy output as wavelengths approach zero.

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Planck's Law

Intensity or power per unit area emitted from a blackbody.

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Energy Quantization

Energy of an oscillator is quantized.

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Energy Emission/Absorption

Emission/absorption occurs in multiples of hf.

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Electron Response to EM Waves (Classical)

Electrons oscillate and re-radiate in all directions when electromagnetic waves interact with them.

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Radiation Pressure Effect on Electrons

Electrons accelerate in the direction of wave propagation due to radiation pressure.

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Doppler Shift in Scattered Waves

The scattered wave frequency exhibits a range of Doppler-shifted values.

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Photon Definition (Compton)

A particle with energy E = hfo = hc/λo and zero rest energy.

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Energy and Momentum Conservation (Compton)

Total energy and total linear momentum are conserved during the scattering process.

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Compton Shift Equation

λ' − λo = (h/mc)(1 − cos θ)

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Light Diffraction

Light bends around obstacles/slits.

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Light Interference

Light waves combine constructively or destructively.

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Electron Momentum

The momentum of an electron is the product of its mass and velocity.

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De Broglie Wavelength

The de Broglie wavelength relates a particle's momentum to its wavelength, suggesting wave-particle duality.

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Wave Packet

A wave packet is formed by the superposition of numerous waves, resulting in constructive interference in a small, localized region of space.

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Quantum Particle

Wave packets represent quantum particles by combining multiple waves.

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Wave Packet Equation

Mathematical representation of combining two waves with slightly different wave numbers and frequencies to create a wave packet. Key parameters: k = 2π/λ (wave number), ω = 2πf (angular frequency).

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Wave-particle duality

Light behaves as both a wave and a particle; it is a complementary relationship.

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Matter wave frequency

f = E/h, where E is the total relativistic energy of the particle and h is Planck's constant.

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Davisson-Germer experiment

Experiment that verified de Broglie's hypothesis by demonstrating the wave nature of electrons.

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Verifying de Broglie

Using Bragg's diffraction to find electron wavelength, comparing with de Broglie's prediction.

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Wave diffraction

When a wave encounters an obstacle/opening, bending around corners.

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Bragg's Law

d sin(θ) = nλ. Where d: interatomic spacing, θ: angle of incidence, n: order of diffraction, λ: wavelength.

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Phase Speed (vp)

The speed at which a wave crest of an individual wave moves.

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Group Speed (vg)

The speed of the wave packet (group of waves).

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vg = Δω/Δk

vg is equal to the change in angular frequency (Δω) divided by the change in wave number (Δk).

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vp = ω/k or vp = fλ

Phase speed equals angular frequency divided by wave number OR frequency times wavelength.

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vg = vp - λ(dvp/dλ)

Group speed is equal to the phase speed minus wavelength times the derivative of phase speed with respect to wavelength.

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vg = u

Group speed is equal to the particle speed.

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ω = 2πE/h

Relates energy to frequency.

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k = 2πp/h

Relates wave number to momentum.

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E = p²/2m

The classical expression for kinetic energy.

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d sin θ = mλ

Defines the condition for constructive interference in a double-slit experiment.

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Uncertainty Principle

The principle stating it's impossible to know both position and momentum of a particle with perfect accuracy simultaneously.

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Position-Momentum Uncertainty

Relates the uncertainty in position (Δx) and momentum (Δpx): (Δx)(Δpx) ≥ h / 4π.

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Energy-Time Uncertainty

Relates the uncertainty in energy (ΔE) and time (Δt): (ΔE)(Δt) ≥ h / 4π.

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Stefan Constant

The constant (σ = 5.67 x 10-8 W/m²K⁴) used in Stefan-Boltzmann Law to relate black body temperature to energy emitted.

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Photoelectric Effect

The phenomenon where photons are emitted when light hits a material.

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Compton Scattering

The change in wavelength of a photon after it scatters off a free electron.

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Line Width

The inherent uncertainty in the frequency (or energy) of a spectral line due to the finite lifetime of the excited state.

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Study Notes

  • Quantum physics explains experimental results that can only be understood by the particle electromagnetic waves.
  • It also studies the particle properties of waves and the wave properties of particles and explains the uncertainty principle

Blackbody Radiation and Planck's Hypothesis

  • Electromagnetic radiation emitted by a black body is called black-body radiation

Basic laws of radiation

  • All objects emit radiant energy
  • Hotter objects emit more energy per unit area than colder objects, described by Stefan's Law: P = σAeT⁴
  • The peak of the wavelength distribution shifts to shorter wavelengths as the black body temperature increases, described by Wien's Displacement Law, λmT = constant

Rayleigh-Jeans Law

  • The intensity or power per unit area I(λ, T)dλ emitted in the wavelength interval λ to λ+dλ from a blackbody is given by I(λ, T) = (2πc kBT) / λ⁴
  • It agrees with experimental measurements only for long wavelengths
  • Predicts an energy output that diverges towards infinity as wavelengths become smaller, known as the ultraviolet catastrophe

Planck's Law

  • The intensity or power per unit area I(λ, T)dλ emitted in the wavelength interval λ to λ+dλ from a blackbody is given by I(λ, T) = (2πhc²) / λ⁵ * 1 / (e^(hc/λkT) - 1)

Planck's Law Assumptions

  • Energy of an oscillator in cavity walls is given by En = nhf
  • Amount of emission / absorption of energy will be integral multiples of hf

Results of Planck's Law

  • The denominator [exp(hc/λkT)] tends to infinity faster than the numerator (λ⁻⁵), resolving the ultraviolet catastrophe: I(λ, T) → 0 as λ → 0
  • For very large λ, I(λ, T) → 0 as λ → ∞; exp(hc/λkT) - 1 ≈ hc/λkT => I(λ, T) → 2πcλ⁻⁴kT
  • Planck's constant was derived from a fit between Planck's law and experimental data: h = 6.626 × 10⁻³⁴ J-s

Photoelectric Effect

  • Ejection of electrons occur from the surface of certain metals when it's irradiated by electromagnetic radiation of suitable frequency

Classical Predictions for Photoelectric Effect

  • Electron ejection should be frequency independent
  • KE of the electrons should increase with intensity of light
  • There should be a measurable time interval between the incidence of light and ejection of photoelectrons
  • KMAX should not depend upon the frequency of the incident light

Experimental Observations for Photoelectric Effect

  • No photoemission for frequency below threshold frequency
  • KMAX is independent of light intensity
  • It is an Instantaneous effect
  • KE of the most energetic photoelectrons is KMAX = eΔV & increases with increasing f

Einstein's Interpretation of Electromagnetic Radiation

  • Electromagnetic waves carry discrete energy packets (light quanta called photons now)
  • The energy E, per packet depends on frequency f: E = hf
  • More intense light corresponds to more photons, not higher energy photons
  • Each photon of energy E moves in vacuum at the speed of light: c = 3 x 10⁸ m/s, with momentum p = E/c
  • Einstein's photoelectric equation: Kmax = hf - φ

Compton Effect

  • X-rays scattered by free/nearly free electrons undergo a change in wavelength dependent on the scattering angle

Classical Predictions for Compton Effect

  • Oscillating electromagnetic waves effect on elections:
  • Oscillations in electrons: re-radiation occurs in all directions
  • Radiation pressure accelerates electrons in the direction of the waves
  • Different electrons will move at differing speeds post interaction
  • Scattered wave frequency should show a distribution of Doppler-shifted values

Compton Shift Equation

  • Photon is treated as a particle with energy E = hf₀ = hc/λ₀ and zero rest energy
  • During scattering, total energy and total linear momentum of the system are conserved

Variables

  • λ₀ = wavelength of the incident photon
  • p₀ = h/λ₀ = momentum of the incident photon
  • E₀ = hc/λ₀ = energy of the incident photon
  • λ' = wavelength of the scattered photon
  • p' = h/λ' = momentum of the scattered photon
  • E' = hc/λ' = energy of the scattered photon

Conservation Equations

  • Conservation of energy: E₀ = E' + K
  • Conservation of momentum:
  • x-component: p₀ = p' cos θ + p cos Ø
  • y-component: 0 = p' sin θ - p sin Ø

Relativistic Equations

  • v is the speed of the electron
  • m is the mass of the electron
  • p = γmv = momentum of the electron where γ = 1 / √(1 - v²/c²)
  • E = √(p²c² + m²c⁴) = total relativistic energy of the electron
  • K = E - mc² = kinetic energy of the electron
  • Compton shift: λ' - λ₀ = h/mc (1 - cos θ)

Photons and Electromagnetic Waves [Dual Nature of Light]

  • Light exhibits diffraction and interference phenomena that are explicable only terms of wave properties
  • Photoelectric effect and Compton Effect can only be explained taking light as photons / particle
  • The true nature of light is describable in terms of any single picture, instead both wave and particle nature have to be considered
  • The particle model & the wave model of light complement each other

de Broglie Hypothesis - Wave Properties of Particles

  • Wavelength associated with particle of mass m moving with velocity v is given by de Broglie wavelength: λ = h/p = h/mv
  • The momentum (p) of an electron accelerated through a potential difference of ΔV is p = mv = √(2meΔV)
  • Frequency of the matter wave associated with the particle is f = E/h, where E is total relativistic energy of the particle

Davisson and Germer Experiment

  • Experimental verification of de-Broglie hypothesis
  • An electron is assumed to act as a wave
  • The experiment determines the wavelength of electron using Bragg's diffraction law and compares it with the de-Broglie's wavelength
  • A beam of electron is produced by a heated filament and accelerated by potential V (Here V = 54 V)
  • This beam of electron is then scattered by a nickel crystal
  • Intensities of the scattered electrons are measured as a function angle φ (φ is the angle betwixt incident beam and scattered beam
  • Bragg's diffraction law: d sin φ = nλ
  • Variable d is the inter-atomic spacing in nickel, equals 0.215 nm
  • Variable n = 1 for the first diffraction maximum, which is at φ = 50°
  • Substituting numbers we obtain
  • The electron wavelength has λ = 0.165 nm
  • Conservation of energy is found by ½ mv² = eV, where v is the velocity of electron
  • The momentum of the electron is p = mv = √(2meV)
  • Wavelength is therefore λ = h/p = h/mv = h / √(2meV)
  • On substitution for V = 54 V: λ = 0.167 nm

Quantum Particle

  • Adding a large number of waves constructively interferes in a small localized region of space a wavepacket, which represents the quantum particle, can be formed

Wavepacket Representation

  • y1 = A cos(k1x - ω1t) and y2 = A cos(k2x - ω2t), where k = 2π/λ, ω = 2πf
  • The resultant wave: y = y1 + y2
  • Rewritten it is expressed as: y = 2A[cos((Δk/2)x - (Δω/2)t) cos(((k1+k2)/2)x - ((ω1+ω2)/2)t)]
  • Where Δk = k1 - k2 and Δω = ω1 - ω2
  • Phase speed vp equals fλ or ω / k, describes with what velocity the individual wave crest of individual waves moves
  • Group speed vg equals (Δω / 2)/ (Δk / 2) which simplifies to Δω / Δk, and describes the speed of the wave packet
  • Relation between group speed (vg) and phase speed (vp): vp = ω / k = fλ therefore ω = k vp
  • But vg = dω / dk = d(kvp) / dk = k (dvp / dk) + vp
  • Simplified: vg = vp - λ (dvp / dλ)
  • Relation between group speed (vg) and particle speed (u): ω = 2πf = 2π (E / h) and k = 2π / λ = 2π / (h / p) = 2πp / h
  • vg = dω / dk = 2π / h dE / dp
  • A classical particle moving with speed u, has kinetic energy E is given by
  • E = ½ mu² = p² / 2m and dE = 2p dp / 2m which simplifies to: dE / dp = p / m = u
  • Simplified result: vg = dω / dk = dE / dp = u
  • Double-slit experiment equation: d sin θ = mλ , where m is the order number and λ is the electron wavelength

Uncertainty Principle

  • Heisenberg uncertainty principle: The act of simultaneuous measurements of a particle's position and momentum is fundamentally impossible
  • It's measured with infinite accuracy in the equation: (Δx) (Δpx) ≥ h/4π
  • The relationship expressing the uncertainty principle is related to the variance of energy and equals: (ΔE) (Δt) ≥ h/4π

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Explore wave-particle duality, de Broglie's hypothesis, and experimental evidence confirming the wave properties of particles. Understand Bragg's diffraction law and the Davisson-Germer experiment. Also, look at the relationship between a matter wave's frequency and a particle's total relativistic energy.

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