Volumetric Analysis and Concentrations
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A titration is a laboratory procedure where a measured volume of one solution is added to a known volume of another solution until the reaction is ______.

complete

The ______ flask is designed to contain a definite volume of solution.

volumetric

The last few cm3 of water must be added carefully so that the bottom of the meniscus rests on the ______ mark.

calibration

A ______ is used to deliver an exact volume of solution.

<p>pipette</p> Signup and view all the answers

Before use, graduated cylinders should always be rinsed with ______ water.

<p>deionised</p> Signup and view all the answers

The liquid is allowed to run into a beaker until the bottom of the ______ is level with the graduation mark.

<p>meniscus</p> Signup and view all the answers

A solution is a completely perfect mixture of a ______ and a solvent.

<p>solute</p> Signup and view all the answers

The tip of the pipette is touched against the side of a glass ______ to remove the drop adhering to the tip.

<p>beaker</p> Signup and view all the answers

The concentration of a solution is the amount of ______ that is dissolved in a given volume of solution.

<p>solute</p> Signup and view all the answers

It is allowed to discharge slowly into a ______ flask, keeping the tip of the pipette in contact with the side.

<p>conical</p> Signup and view all the answers

10% NaCl w/w means that there are 10 g of sodium chloride per 100 g of ______.

<p>solution</p> Signup and view all the answers

Before use, the pipette should be rinsed with ______ water to remove contaminants.

<p>deionised</p> Signup and view all the answers

The conical flask should not be washed out with the ______ it is to contain.

<p>solution</p> Signup and view all the answers

1 ppm is equivalent to 1 mg of solute per million ______.

<p>mg</p> Signup and view all the answers

To standardise hydrochloric acid solution, approximately 50 cm3 of the ______ acid solution is poured into a clean dry beaker.

<p>hydrochloric</p> Signup and view all the answers

The molarity of a solution is the number of moles of solute per litre of ______.

<p>solution</p> Signup and view all the answers

When filling the burette, ensure that there are no air ______ in the nozzle.

<p>bubbles</p> Signup and view all the answers

0.85% w/v means that there are 0.85 g NaCl per 100 cm3 of the ______.

<p>solution</p> Signup and view all the answers

A 1 M (one molar) solution contains one mole of the solute dissolved in one litre of ______.

<p>solution</p> Signup and view all the answers

Add 2-3 drops of ______ orange indicator to the sodium carbonate solution in the conical flask.

<p>methyl</p> Signup and view all the answers

To make a 0.85% w/v solution of NaCl, you would need to dissolve ______ g of NaCl in 250 cm3 of solution.

<p>2.125</p> Signup and view all the answers

White crystals are formed in the ______ dish.

<p>evaporating</p> Signup and view all the answers

To determine the concentration of ______ in vinegar.

<p>ethanoic acid</p> Signup and view all the answers

Add 3 drops of ______ indicator to the conical flask.

<p>phenolphthalein</p> Signup and view all the answers

At the end point, the phenolphthalein changes from pink to ______.

<p>colourless</p> Signup and view all the answers

Weigh accurately approximately ______ g of hydrated sodium carbonate into a beaker.

<p>1.5</p> Signup and view all the answers

Titrate the sodium carbonate solution against ______ M hydrochloric acid.

<p>0.1</p> Signup and view all the answers

Methyl orange changes from yellow to ______ at the end point.

<p>red/pink</p> Signup and view all the answers

A batch of washing soda crystals had lost some of its water by a process called ______.

<p>efflorescence</p> Signup and view all the answers

A chemist was required to determine the percentage water of ______ in the crystals.

<p>crystallisation</p> Signup and view all the answers

The mean volume of the hydrochloric acid solution required to reach the ______ was 21.6 cm3.

<p>end point</p> Signup and view all the answers

A number of 25.0 cm3 portions of this solution were titrated with a previously ______ hydrochloric acid solution.

<p>standardised</p> Signup and view all the answers

The balance equation for the titration reaction is: 2HCl + Na2CO3 → 2NaCl + H2O + ______.

<p>CO2</p> Signup and view all the answers

To calculate the concentration of sodium carbonate, the volume and molarity of the ______ solution are used.

<p>HCl</p> Signup and view all the answers

The chemist should have added the sample to a ______ of deionised water to dissolve it properly.

<p>beaker</p> Signup and view all the answers

Add the hydrochloric acid drop by ______ to accurately detect the end point of the titration.

<p>drop</p> Signup and view all the answers

The formula for hydrated sodium carbonate is Na2CO3.x H2O, where x represents the number of ______ molecules.

<p>water</p> Signup and view all the answers

The balanced equation for the titration reaction indicates that 2 moles of hydrochloric acid react with 1 mole of ______.

<p>sodium carbonate</p> Signup and view all the answers

To prepare a 0.05 M primary standard solution, the student must accurately measure a known mass of pure anhydrous ______.

<p>sodium carbonate</p> Signup and view all the answers

The exact mass of anhydrous sodium carbonate required to prepare the solution was calculated to be ______ grams.

<p>2.65</p> Signup and view all the answers

The indicator used for this titration is ______, which changes from orange to red at the end point.

<p>Methyl Orange</p> Signup and view all the answers

The mean titre during the titration was measured to be ______ cm3.

<p>20.8</p> Signup and view all the answers

The student used a pipette filler to avoid the solution getting into their ______ for hygiene reasons.

<p>mouth</p> Signup and view all the answers

The concentration of hydrochloric acid solution can be calculated by using the formula ______.

<p>Va x Ma = Vb x Mb</p> Signup and view all the answers

Study Notes

Volumetric Analysis

  • Volumetric analysis is a quantitative method using solution reactions
  • Solutions react with each other, used to determine concentrations of solutions accurately.

Expressing Concentrations of Solutions

  • Solution: A perfect mixture of solute and solvent (homogeneous)
  • Concentration: Amount of solute dissolved in a given volume of solution.
  • Different ways to express concentration:

Percentage of Solute

  • Weight per weight (w/w): Grams of solute per 100 grams of solution (g/100g)
    • Example: 10% NaCl w/w means 10g NaCl in 100g solution
  • Weight per volume (w/v): Grams of solute per 100 cm³ of solution (g/100cm³)
    • Example: 10% w/v NaCl means 10g NaCl in 100 cm³ solution
  • Volume per volume (v/v): Volume of solute per 100 cm³ of solution (cm³/100cm³)
    • Example: 10% v/v ethanol means 10 cm³ ethanol in 100 cm³ solution

Moles of Solute per Litre (Molarity)

  • Molarity: Moles of solute per litre of solution (M)
    • 1M solution contains 1 mole of solute in 1 litre of solution.
  • Convert between moles/litre and grams/litre using molar mass.

Parts per Million (ppm)

  • Used for very dilute solutions
  • 1 ppm = 1 mg/L

Dilution of Solutions

  • Number of moles of solute remains constant during dilution.
  • M1V1 = M2V2 (where M1 and V1 are initial molarity and volume, and M2 and V2 are final molarity and volume).

Titrations

  • Procedure to measure the exact volume of one solution that reacts completely with a known volume of a second solution.

Standard Solutions

  • Solutions with known concentrations.
  • Primary standard solutions are pure, stable, easily soluble, and have a high molar mass, and undergo complete and rapid reactions.

Reaction Between a Solution and a Solid

  • Calculate the mass of Mg that reacts with a given volume and concentration of sulfuric acid (H2SO4).

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Volumetric Analysis PDF

Description

Test your knowledge on volumetric analysis and the various ways to express concentrations of solutions. This quiz covers percentage calculations and molarity concepts, essential for understanding solution chemistry. Enhance your skills in quantitative chemical analysis today!

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