Viscoelasticity and Polymer Types

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Questions and Answers

What defines elastic deformation in materials?

  • Permanent change in shape under load
  • Inability to return to original shape
  • Recovery of shape after the removal of load (correct)
  • Deformation dependent on the duration of load

How is stress defined in the context of materials?

  • Force applied to a material per unit length
  • Force applied to a material per unit mass
  • Force applied to a material per unit area (correct)
  • Force applied to a material per unit volume

What does Hooke's law enable us to define for materials?

  • Shear modulus
  • Young’s modulus (correct)
  • Viscosity coefficient
  • Strain rate

Which statement is true regarding Newtonian fluids?

<p>Stress is proportional to the strain rate but independent of strain (D)</p> Signup and view all the answers

At what conditions do polymers exhibit elastic behavior?

<p>Low temperatures and high rates of strain (A)</p> Signup and view all the answers

How do polymers behave at high temperatures and low rates of strain?

<p>They behave in a viscous manner (D)</p> Signup and view all the answers

What characterizes the elastic properties of polymer fibers?

<p>They are highly anisotropic (D)</p> Signup and view all the answers

In terms of stress and strain, how is Young's modulus (E) expressed?

<p>E = stress/strain (D)</p> Signup and view all the answers

Flashcards

Stress

The force applied to a material per unit area. Measured in N/m².

Strain

The relative deformation of a material when forces are applied. Measured as a ratio of change in length to original length.

Elastic Deformation

A material's ability to stretch or deform under an applied force and return to its original shape once the force is removed.

Hooke's Law

A relationship in which stress is directly proportional to strain. This means the more you stretch a material, the more force is required to stretch it further.

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Young's Modulus

A material's resistance to deformation. Higher Young's modulus means the material is stiffer.

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Viscoelastic Material

A material that exhibits both elastic and viscous properties, meaning it can deform like a solid and flow like a liquid. Their behavior depends on temperature and strain rate.

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Newtonian Fluid

Liquids that exhibit a linear relationship between stress and strain rate. The viscosity is constant regardless of the strain rate.

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Viscosity

The ability of a material to resist flow. Higher viscosity means the material flows slower.

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Study Notes

Viscoelasticity

  • Elastic deformation is temporary deformation under external force, reverting to original shape upon force removal.
  • Stress is force applied per unit area (N/m²).
  • Strain is relative deformation in a material (e = dl/l).
  • Hooke's Law states stress is proportional to strain (σ = Ee), useful for low strains in polymers. Young's Modulus (E) quantifies this relationship (E = stress/strain).
  • Newtonian fluids obey Newton's Law: stress is proportional to strain rate (σ = η(de/dt)), where η is viscosity. This relationship is independent of strain.

Polymer Types

  • Elastomers have a Young's Modulus range of ~10⁶-10⁷ Pa.
  • Semi-crystalline polymers have a Young's Modulus range of ~10⁸-10⁹ Pa.
  • Glassy polymers have a Young's Modulus ~10⁹ Pa.
  • Polymer fibers parallel to the fiber axis have a Young's Modulus of ~10¹¹ Pa. Perpendicular direction have a Young's Modulus of ~10⁹ Pa.

Viscoelasticity of Polymers

  • Polymer behavior is intermediate between elastic solids and viscous liquids.
  • At high strain rates and low temperatures, polymers display elastic properties.
  • At low strain rates and high temperatures, polymers exhibit viscous behaviour (flowing like liquids).
  • Polymers are thus viscoelastic: exhibiting aspects of both viscous and elastic behavior.

Time-Dependent Behavior

  • Creep: Constant stress applied, initial rapid strain increase followed by gradual decrease. Deformation persists.
  • Stress relaxation: Constant strain maintained, stress gradually decreases over time.
  • Constant stress rates: Stress-strain relationship varies over time while deforming.
  • Constant strain rates: Stress-strain relationship changes over time while deforming.

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