Valence Electrons and Chemical Bonding

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Questions and Answers

Why are valence electrons crucial in chemical bonding?

  • They define the element's atomic number.
  • They determine the mass of an atom.
  • They dictate how atoms interact and form bonds. (correct)
  • They determine the number of neutrons in an atom.

How does the transfer of electrons between atoms lead to the formation of an ionic bond?

  • By forming charged ions that are held together by electrostatic forces. (correct)
  • By establishing a covalent bond through the equal sharing of electrons.
  • By creating a shared pool of electrons between atoms.
  • By inducing a temporary dipole moment in adjacent atoms.

Which property distinguishes covalent compounds from ionic compounds?

  • Better electrical conductivity in aqueous solutions.
  • Greater solubility in polar solvents.
  • Lower melting and boiling points. (correct)
  • Higher melting and boiling points.

What determines the shape of a molecule according to the VSEPR theory?

<p>The arrangement of atoms and the repulsion between electron pairs. (D)</p> Signup and view all the answers

In organic chemistry, why is carbon able to form a wide variety of compounds?

<p>Carbon forms covalent bonds and can establish single, double, or triple bonds. (B)</p> Signup and view all the answers

What is the significance of resonance structures in molecules like benzene?

<p>Resonance structures show that electrons are delocalized over multiple atoms, increasing stability. (C)</p> Signup and view all the answers

How does electronegativity difference influence the type of chemical bond formed between two atoms?

<p>A high electronegativity difference leads to ionic bonds. (A)</p> Signup and view all the answers

How does atomic size affect the strength and reactivity of chemical bonds?

<p>Smaller atoms form stronger bonds, leading to higher reactivity in compounds. (B)</p> Signup and view all the answers

Which of the following statements accurately describes the trend of ionization energy in the periodic table?

<p>Ionization energy increases across a period and decreases down a group. (A)</p> Signup and view all the answers

How does understanding periodic trends contribute to predicting chemical reactivity?

<p>Periodic trends reveal how easily elements lose or gain electrons, influencing their reactivity. (D)</p> Signup and view all the answers

Which definition of an acid or base is most applicable in non-aqueous organic reactions?

<p>Lewis definition. (C)</p> Signup and view all the answers

How do buffer systems prevent drastic pH changes in chemical and biological systems?

<p>By neutralizing added acids or bases. (D)</p> Signup and view all the answers

Which of the following is a key role of catalysts in organic reactions?

<p>To lower the activation energy of the reaction. (C)</p> Signup and view all the answers

What role do functional groups play in determining the chemical behavior of organic molecules?

<p>Functional groups dictate how molecules interact in chemical reactions, affecting properties like solubility and reactivity. (D)</p> Signup and view all the answers

What is the role of intermediates in a reaction mechanism?

<p>To form temporarily as unstable species during the reaction. (A)</p> Signup and view all the answers

In an SN2 reaction, which factor is most important in determining the reaction rate?

<p>The concentration of the substrate and nucleophile. (A)</p> Signup and view all the answers

How does an E1 reaction mechanism differ from an E2 reaction mechanism?

<p>E1 reactions involve a carbocation intermediate, while E2 reactions occur in a single step. (D)</p> Signup and view all the answers

What is a defining characteristic of amino acids?

<p>They contain both an amino group and a carboxyl group attached to a central carbon. (C)</p> Signup and view all the answers

How do the R-groups of amino acids contribute to the overall structure and function of proteins?

<p>They determine the chemical properties and folding of the protein, influencing its function. (B)</p> Signup and view all the answers

What type of amino acids are typically found in the interior of proteins?

<p>Hydrophobic amino acids. (C)</p> Signup and view all the answers

Which level of protein structure is most directly determined by the sequence of amino acids?

<p>Primary structure. (C)</p> Signup and view all the answers

How are alpha-helices and beta-sheets stabilized in the secondary structure of proteins?

<p>By hydrogen bonds between the carbonyl and amide groups of the protein backbone. (A)</p> Signup and view all the answers

What types of interactions primarily stabilize the tertiary structure of a protein?

<p>Hydrogen bonds, hydrophobic interactions, ionic bonds, disulfide bonds, and van der Waals forces between R-groups. (C)</p> Signup and view all the answers

If a protein consists of multiple polypeptide subunits, at which level of protein structure are these subunits arranged?

<p>Quaternary. (D)</p> Signup and view all the answers

What is the central dogma of molecular biology regarding the flow of genetic information?

<p>DNA → RNA → Protein. (C)</p> Signup and view all the answers

Which enzyme is primarily responsible for synthesizing mRNA during transcription?

<p>RNA polymerase. (A)</p> Signup and view all the answers

What is the function of tRNA in translation?

<p>To carry amino acids to the ribosome for protein assembly. (C)</p> Signup and view all the answers

What is the role of DNA ligase in DNA replication?

<p>To seal gaps between Okazaki fragments on the lagging strand. (A)</p> Signup and view all the answers

What is the significance of the semi-conservative model of DNA replication?

<p>Each new DNA molecule contains one original strand and one newly synthesized strand. (B)</p> Signup and view all the answers

Flashcards

Protons

Positively charged particles in the nucleus, defining an element's identity.

Neutrons

Neutral particles in the nucleus, contributing to atomic mass.

Electrons

Negatively charged particles orbiting the nucleus, crucial for chemical bonding.

Ionic Bond

Bonds formed when electrons are transferred, creating charged ions.

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Cation

Positively charged ion formed when an atom loses electrons.

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Anion

Negatively charged ion formed when an atom gains electrons.

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Covalent Bond

Bonds formed when atoms share electrons to achieve stability.

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Single bond

Atoms share one pair of electrons.

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Double bond

Atoms share two pairs of electrons.

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Triple bond

Atoms share three pairs of electrons.

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VSEPR Theory

A theory that predicts molecular shape based on electron pair repulsion.

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Covalent Bonds

Carbon, the backbone of organic compounds, forms these bonds.

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Functional Groups

Specific groups of atoms within molecules that determine chemical behavior.

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Alcohol

Contains an -OH group. Polar and capable of hydrogen bonding.

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Across a Period: Radius Trend

Atomic radius decreases across a period due to increasing what?

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Down a Group: Radius Trend

Atomic radius increases down a group due to adding what?

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Electronegativity

Element's ability to attract electrons in a chemical bond.

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Ionization Energy

Energy required to remove an electron from a neutral atom.

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Electron Affinity

Energy released when an atom gains an electron.

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Metallic Character

Metals tend to lose electrons and form what ions?

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Acids (Arrhenius)

Substances that increase H+ concentration in aqueous.

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Bases (Arrhenius)

Substances that increase OH- concentration in aqueous.

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Acids (Bronsted-Lowry)

Proton donors release what ions?

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pH

Measures the acidity or basicity of a solution.

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Buffer Systems

Buffers maintain a stable __ by neutralizing acids or bases.

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Intermediates

Temporary, unstable species formed during a reaction.

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Transition States

High-energy states that exist momentarily as reactants convert into products.

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Catalysts

Speed up reactions by lowering activation energy.

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