Chemical Equilibrium

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Questions and Answers

What is the correct equilibrium constant expression for the reaction C(s) + CO2(g) ⇌ 2CO(g)?

  • (1-x)/(2x)^2
  • (1+x)/(2x)^2
  • (2x)/(1-x)^2 (correct)
  • (2x)/(1+x)^2

What is Le-Chatelier's principle?

  • A system in equilibrium readjusts itself to counteract the effect of the change (correct)
  • A system in equilibrium gets disturbed when concentration, temperature or pressure is changed
  • The equilibrium constant remains constant even if the concentration, temperature or pressure is changed
  • A change in concentration, temperature or pressure has no effect on the system

For a reaction in which the number of moles of products is greater than that of reactants, what is the effect of increasing pressure on the system?

  • Reaction becomes irreversible
  • Equilibrium shifts towards the reactants (correct)
  • No effect on the equilibrium
  • Equilibrium shifts towards the products

What happens to the equilibrium when a system is subjected to a change in concentration, temperature or pressure?

<p>The equilibrium gets disturbed and the system readjusts itself to its original state (B)</p> Signup and view all the answers

What is the significance of Le-Chatelier's principle?

<p>It is used to predict the effect of change in concentration, temperature or pressure on a system in equilibrium (D)</p> Signup and view all the answers

What happens to the melting point of sulphur at higher pressure?

<p>It increases (D)</p> Signup and view all the answers

What is the effect of high temperature on the solubility of NH4Cl?

<p>Solubility increases (A)</p> Signup and view all the answers

What happens to the boiling point of water at higher pressure?

<p>It increases (D)</p> Signup and view all the answers

What is the effect of an increase in temperature on the solubility of CaCl2?

<p>Solubility decreases (C)</p> Signup and view all the answers

What is the purpose of flash evaporation in concentrating certain aqueous solutions?

<p>To concentrate the solution quickly (B)</p> Signup and view all the answers

What happens to the volume when sulphur melts?

<p>It increases (B)</p> Signup and view all the answers

What is the effect of increasing the pressure in the reaction: 2 NO + O2 ⇌ 2 NO2 + 27.8 kcal?

<p>The reaction will shift in the forward direction (C)</p> Signup and view all the answers

In the reaction N2 + 3H2 ⇌ 2 NH3 + 22 kcal, what will be the effect of increasing the temperature?

<p>The reaction will shift in the reverse direction (C)</p> Signup and view all the answers

In the reaction PCl5 ⇌ PCl3 + Cl2 - 15 kcal, what will be the effect of adding more PCl5?

<p>The reaction will shift in the reverse direction (A)</p> Signup and view all the answers

In the reaction Ice ⇌ Water - x kcal, what will be the effect of increasing the pressure?

<p>More water will be formed (A)</p> Signup and view all the answers

What is the significance of Le-Chatelier's principle in chemical and physical systems?

<p>It has a great significance in chemical, physical systems, and everyday life in a state of equilibrium (A)</p> Signup and view all the answers

In the reaction 2 NO + O2 ⇌ 2 NO2 + 27.8 kcal, what will be the effect of increasing the volume of the container?

<p>The reaction will shift in the reverse direction (D)</p> Signup and view all the answers

If a system is in equilibrium and the concentration of one of the reactants is increased, what will happen to the equilibrium?

<p>The equilibrium will shift to the right. (C)</p> Signup and view all the answers

What is the significance of the value of 'a' in the equilibrium constant expression?

<p>It is the molar concentration of the component in solution. (D)</p> Signup and view all the answers

A system is in equilibrium and the pressure is increased. What will happen to the equilibrium?

<p>The equilibrium will shift to the direction of fewer moles of gas. (A)</p> Signup and view all the answers

What is the purpose of Le-Chatelier's principle?

<p>To predict the effect of changes in concentration, temperature or pressure on a system in equilibrium. (A)</p> Signup and view all the answers

For a reaction in which the number of moles of products is less than that of reactants, what is the effect of increasing pressure on the system?

<p>The equilibrium will shift to the left. (A)</p> Signup and view all the answers

What is the correct equilibrium constant expression for the reaction NH4HS(s) ⇌ NH3(g) + H2S(g)?

<p>K = $P_{NH3}P_{H2S} / (1-x)$ (A)</p> Signup and view all the answers

What is the effect of increasing the pressure on the equilibrium position of the reaction A + B ⇌ C + D, where Δn = (c + d) - (a + b) = -ve?

<p>The equilibrium position shifts to the right. (A)</p> Signup and view all the answers

What is the effect of increasing the concentration of C and/or D on the equilibrium position of the reaction A + B ⇌ C + D, where Δn = (c + d) - (a + b) = 0?

<p>The equilibrium position shifts to the left. (D)</p> Signup and view all the answers

What is the effect of adding a catalyst to the equilibrium position of the reaction A + B ⇌ C + D?

<p>The equilibrium position remains unchanged. (C)</p> Signup and view all the answers

What is the effect of increasing the temperature on the equilibrium constant of the reaction 2SO2 + O2 ⇌ 2SO3 + 45 kcal, where ΔH = -ve?

<p>The equilibrium constant decreases. (C)</p> Signup and view all the answers

What is the effect of increasing the pressure on the equilibrium position of the reaction 2NO ⇌ N2 + O2, where Δn = 0?

<p>The equilibrium position remains unchanged. (A)</p> Signup and view all the answers

What is the effect of increasing the concentration of A and/or B on the equilibrium position of the reaction A + B ⇌ C + D, where Δn = (c + d) - (a + b) = +ve?

<p>The equilibrium position shifts to the right. (B)</p> Signup and view all the answers

What is the effect of increasing the pressure on the reaction 2 NO + O2 ⇌ 2 NO2 + 27.8 kcal?

<p>The reaction will shift towards the products. (B)</p> Signup and view all the answers

In the reaction N2 + 3H2 ⇌ 2 NH3 + 23 kcal, what will be the effect of adding more N2?

<p>The reaction will shift towards the products. (D)</p> Signup and view all the answers

What is the effect of increasing the temperature on the reaction PCl5 ⇌ PCl3 + Cl2 - 15 kcal?

<p>The reaction will shift towards the reactants. (B)</p> Signup and view all the answers

In the Ice ⇌ Water - x kcal reaction, what will be the effect of increasing the pressure?

<p>The reaction will shift towards the ice. (C)</p> Signup and view all the answers

What is the effect of increasing the volume of the container on the reaction 2 NO + O2 ⇌ 2 NO2 + 27.8 kcal?

<p>The reaction will shift towards the reactants. (B)</p> Signup and view all the answers

What is the effect of adding more PCl5 on the reaction PCl5 ⇌ PCl3 + Cl2 - 15 kcal?

<p>The reaction will shift towards the products. (C)</p> Signup and view all the answers

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