Understanding Rate of Reaction

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Questions and Answers

A chemist observes that increasing the temperature of a reaction increases the rate of the reaction. According to collision theory, which statement BEST explains this observation?

  • At higher temperatures, reactant particles are more likely to collide with sufficient energy to overcome the activation energy barrier. (correct)
  • Increasing the temperature introduces a catalyst, which lowers the activation energy.
  • At higher temperatures, reactant particles are more likely to collide with the correct orientation.
  • At higher temperatures, the concentration of reactants increases, leading to more frequent collisions.

A student conducts an experiment where they react marble chips (calcium carbonate) with hydrochloric acid. Which of the following changes would NOT increase the rate of reaction?

  • Increasing the concentration of the hydrochloric acid.
  • Adding a catalyst to the reaction mixture.
  • Lowering the temperature of the reaction. (correct)
  • Decreasing the size of the marble chips.

Consider a reaction in which two molecules must collide with a specific orientation to react. Which of the following would MOST effectively increase the rate of this reaction?

  • Increasing the concentration of the reactants while decreasing the temperature.
  • Decreasing the concentration of the reactants while increasing the temperature.
  • Decreasing the surface area of the reactants.
  • Introducing a catalyst that aligns the molecules in the correct orientation. (correct)

In a chemical reaction, only a small fraction of collisions leads to product formation. What is the primary reason for this?

<p>Most collisions do not occur with sufficient energy or correct orientation. (D)</p> Signup and view all the answers

A reaction is carried out in two trials. In the first trial, the reaction is complete in 60 seconds. In the second trial, with a change to the reaction conditions, it is complete in 30 seconds. What can be concluded about the rate of reaction in the second trial, compared to the first?

<p>The rate of reaction in the second trial is twice that of the first trial. (A)</p> Signup and view all the answers

Which of the following scenarios would MOST likely lead to an increase in the number of successful collisions in a chemical reaction?

<p>Increasing both the temperature and the concentration of reactants. (D)</p> Signup and view all the answers

A student is investigating the rate of reaction between zinc granules and sulfuric acid. They conduct several experiments, changing one variable at a time. Which change would NOT increase the rate of hydrogen gas production?

<p>Diluting the sulfuric acid with distilled water. (C)</p> Signup and view all the answers

A chemical company wants to optimize a reaction in a large industrial reactor. According to collision theory, which combination of factors would BEST achieve this?

<p>High temperature, high concentration of reactants, fine particle size, presence of an effective catalyst. (D)</p> Signup and view all the answers

Why does increasing the surface area of a solid reactant typically increase the rate of a chemical reaction?

<p>It provides more sites for collisions to occur. (C)</p> Signup and view all the answers

Two reactions are performed: Reaction A has a high activation energy, and Reaction B has a low activation energy. Assuming all other factors are equal, which of the following statements is most likely true?

<p>Reaction B will occur at a faster rate than Reaction A. (B)</p> Signup and view all the answers

Flashcards

Rate of Reaction

Measures how fast reactants become products.

Collision Requirement

Particles must come into contact for reaction.

Energy Requirement

Particles need enough energy to break bonds.

Orientation Requirement

Particles must align correctly for new bonds.

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Successful Collision

Collisions that meet energy, orientation needs.

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Increased Reaction Rate

Increases successful collisions per second.

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Factors Affecting Reaction Rate

Temperature, surface area, concentration, catalysts.

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Time vs Rate

As reaction time goes down, rate increases.

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Study Notes

  • Rate of reaction refers to how quickly reactants turn into products.
  • A chemical reaction needs colliding particles.
  • For a chemical reaction to occur these steps must be met.
  • Particles must collide with each other.
  • Particles must collide with sufficient energy to break bonds between reactants.
  • Particles must collide with the correct orientation, enabling reactant bonds to break and new bonds to form.
  • Meeting the above steps leads to a successful collision.
  • Most collisions do not end in a chemical reaction.
  • Reactions need successful collisions to occur.
  • Increasing the number of successful collisions per second increases the rate of reaction.
  • Factors that affect the reaction rate: temperature, surface area, concentration, and catalysts.
  • As reaction time decreases, the reaction rate increases.

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