Polymers
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Questions and Answers

What is the primary mechanism governing the increase in chain length in addition polymerisation?

  • Bifunctional species
  • Free radical mechanism (correct)
  • Condensation reaction
  • Ionic species
  • What type of compounds are used as monomers in addition polymerisation?

  • Unsaturated compounds (correct)
  • Alkynes
  • Aromatic compounds
  • Saturated hydrocarbons
  • Which type of polymerisation involves the formation of a distinct functionalised species in each step?

  • Copolymerisation
  • Condensation polymerisation
  • Step-growth polymerisation (correct)
  • Addition polymerisation
  • What is the outcome of each step in step-growth polymerisation?

    <p>A bifunctional species</p> Signup and view all the answers

    Which type of polymerisation results in a significant increase in chain length?

    <p>Addition polymerisation</p> Signup and view all the answers

    What is an example of a reaction that involves the addition of molecules of the same monomer?

    <p>Polymerisation of ethene to polythene</p> Signup and view all the answers

    What is the characteristic of Cross-linked or Network Polymers?

    <p>They are formed from bifunctional and trifunctional monomers.</p> Signup and view all the answers

    What type of polymerisation is involved in the formation of polythene from ethene?

    <p>Addition Polymerisation</p> Signup and view all the answers

    What is the characteristic of Addition Polymers?

    <p>No part from the monomer units are lost during polymerisation.</p> Signup and view all the answers

    What is the type of polymer formed by the polymerisation of two different monomers?

    <p>Copolymer</p> Signup and view all the answers

    What is the catalyst used in the formation of Buna-S?

    <p>Na</p> Signup and view all the answers

    What is the type of polymerisation involved in the formation of Bakelite?

    <p>Condensation Polymerisation</p> Signup and view all the answers

    What is the primary characteristic of Melamine-Formaldehyde polymer that makes it suitable for producing unbreakable crockery?

    <p>Its ability to undergo cross-linking</p> Signup and view all the answers

    Which type of polymerisation reaction is characterized by the formation of a distinct functionalized species in each step?

    <p>Step-growth polymerisation</p> Signup and view all the answers

    What is the primary difference between cis-polyisoprene and trans-polyisoprene?

    <p>The spatial arrangement of the polymer chain</p> Signup and view all the answers

    Which type of polymerisation reaction involves the reaction of two or more different monomeric species?

    <p>Copolymerisation</p> Signup and view all the answers

    What is the primary reason for the elasticity of natural rubber?

    <p>The coiled structure of the polymer chain</p> Signup and view all the answers

    Which type of polymerisation reaction is used to produce phenol-formaldehyde polymers?

    <p>Condensation polymerisation</p> Signup and view all the answers

    What is the primary mechanism governing the formation of polymers in addition polymerisation?

    <p>Chain initiation and propagation</p> Signup and view all the answers

    What is the characteristic of Low Density Polythene (LDP)?

    <p>Chemical inertness and high flexibility</p> Signup and view all the answers

    What is the primary outcome of each step in addition polymerisation?

    <p>Increase in chain length</p> Signup and view all the answers

    Which of the following is an example of an addition polymer?

    <p>Low Density Polythene</p> Signup and view all the answers

    What is the role of benzoyl peroxide in addition polymerisation?

    <p>Initiator of the chain reaction</p> Signup and view all the answers

    Which type of polymerisation is characterised by the formation of a free radical?

    <p>Addition polymerisation</p> Signup and view all the answers

    What is the primary difference between addition and condensation polymerisation?

    <p>Type of species formed in each step</p> Signup and view all the answers

    What is the primary difference between High Density Polythene (HDP) and Low Density Polythene (LDP)?

    <p>Conditions of polymerisation</p> Signup and view all the answers

    Which type of polymerisation is used to produce polymers with high molecular weights?

    <p>Addition polymerisation</p> Signup and view all the answers

    What is the outcome of chain termination in addition polymerisation?

    <p>Formation of a polymeric product</p> Signup and view all the answers

    What is the primary mechanism governing the increase in chain length in condensation polymerisation?

    <p>Formation of bifunctional species</p> Signup and view all the answers

    Which type of polymerisation is characterised by the formation of a polymer with a high molecular weight in a single step?

    <p>Addition polymerisation</p> Signup and view all the answers

    What is the primary characteristic of polymers formed through addition polymerisation?

    <p>No part of the monomer units are lost during polymerisation.</p> Signup and view all the answers

    What is the primary difference between homopolymers and copolymers?

    <p>The number of monomeric species used in their formation.</p> Signup and view all the answers

    What is the primary characteristic of Cross-linked or Network Polymers?

    <p>They contain strong covalent bonds between various linear chains.</p> Signup and view all the answers

    What is the primary mechanism of chain growth in addition polymerisation?

    <p>The repeated addition of monomers possessing double or triple bonds.</p> Signup and view all the answers

    Which type of polymerisation is involved in the formation of polythene from ethene?

    <p>Addition polymerisation</p> Signup and view all the answers

    What is the primary characteristic of polymers formed through condensation polymerisation?

    <p>They are formed by the condensation of bifunctional and trifunctional monomers.</p> Signup and view all the answers

    Study Notes

    Types of Polymerisation Reactions

    • Polymerisation reactions can be classified into three types: Addition, Condensation, and Copolymerisation
    • Addition polymerisation involves the addition of monomers to form a polymer, resulting in an increase in chain length
    • Condensation polymerisation involves the formation of a polymer through the condensation of monomers, resulting in the loss of a small molecule such as water or methanol
    • Copolymerisation involves the polymerisation of two or more different monomers to form a copolymer

    Addition Polymerisation

    • Addition polymerisation involves the addition of monomers to form a polymer, resulting in an increase in chain length
    • The mechanism of addition polymerisation involves three steps: initiation, propagation, and termination
    • Initiation involves the formation of a free radical, which then reacts with a monomer to form a larger radical
    • Propagation involves the repeated addition of monomers to the growing radical chain
    • Termination involves the combination of two radicals to form the final polymer product

    Homopolymers and Copolymers

    • Homopolymers are formed by the polymerisation of a single monomer species
    • Examples of homopolymers include polythene, polypropylene, and polyacrylonitrile
    • Copolymers are formed by the polymerisation of two or more different monomers
    • Examples of copolymers include Buna-S and Buna-N

    Chain Growth and Step Growth

    • Chain growth polymerisation involves the addition of monomers to form a polymer, resulting in an increase in chain length
    • Step growth polymerisation involves the formation of a polymer through the condensation of monomers, resulting in the loss of a small molecule such as water or methanol
    • Chain growth polymerisation can take place through the formation of either free radicals or ionic species
    • Step growth polymerisation is also known as condensation polymerisation

    Characteristics of Polymers

    • Polymers can be classified based on their molecular structure, such as branched-chain, linear, and cross-linked polymers
    • Branched-chain polymers are formed from monomers with multiple functional groups
    • Linear polymers are formed from monomers with a single functional group
    • Cross-linked polymers are formed from bifunctional and trifunctional monomers
    • Cross-linked polymers contain strong covalent bonds between various linear chains

    Examples of Polymers

    • Low density polythene (LDP) is a branched-chain polymer formed from the polymerisation of ethene under high pressure and temperature
    • High density polythene (HDP) is a linear polymer formed from the polymerisation of ethene in a hydrocarbon solvent
    • Polyacrylonitrile (PAN) is a polymer formed from the polymerisation of acrylonitrile
    • Polytetrafluoroethene (PTFE) is a polymer formed from the polymerisation of tetrafluoroethene
    • Bakelite and Melamine are examples of cross-linked polymers

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    Description

    Test your knowledge of different types of polymers, including branched-chain, cross-linked, and addition polymers. Learn about their characteristics, formation, and examples. Identify the differences between various classes of polymers.

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