Types of Hydrogen Bonding in Chemistry

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Questions and Answers

Which of the following best describes the primary goal of atoms when forming chemical bonds?

  • To become more reactive
  • To increase their atomic mass
  • To achieve a stable noble gas electron configuration (correct)
  • To change their atomic number

Covalent bonds are formed by the transfer of electrons between atoms.

False (B)

What is the name given to the notation developed by G.N. Lewis to represent valence electrons in an atom?

Lewis symbols or electron dot symbols

The bond formed by the sharing of electrons contributed equally by both combining atoms is called a ______ bond.

<p>covalent</p> Signup and view all the answers

Match each chemical bond type with its description:

<p>Ionic bond = Electrons are transferred from one atom to another Covalent bond = Electrons are shared equally between atoms Coordinate bond = Electrons are shared, with one atom contributing both electrons</p> Signup and view all the answers

Which of the following elements has the most valence electrons?

<p>Fluorine (A)</p> Signup and view all the answers

Covalent compounds are generally good conductors of electricity.

<p>False (B)</p> Signup and view all the answers

What is the Lewis symbol for Nitrogen?

<p>N with five dots around it</p> Signup and view all the answers

The formation of a covalent bond involves the ______ of electrons between atoms.

<p>sharing</p> Signup and view all the answers

Match the following properties with their corresponding type of compound:

<p>High melting point = Covalent compound Poor conductor of electricity = Ionic compound Generally gaseous or liquid at room temperature = Covalent compound Usually soluble in water = Ionic compound</p> Signup and view all the answers

A coordinate covalent bond is formed when both atoms contribute one electron to the shared pair.

<p>False (B)</p> Signup and view all the answers

Which of the following is NOT a characteristic of covalent compounds?

<p>High melting and boiling points (D)</p> Signup and view all the answers

Which of the following is NOT a characteristic of covalent compounds?

<p>Good conductors of electricity (B)</p> Signup and view all the answers

The formation of a water molecule (Hâ‚‚O) involves the sharing of electrons between one hydrogen atom and one oxygen atom.

<p>False (B)</p> Signup and view all the answers

In a coordinate covalent bond, the atom donating the electron pair is called the ______.

<p>donor</p> Signup and view all the answers

What is the primary difference between the formation of a hydrogen chloride molecule (HCl) and a water molecule (Hâ‚‚O)?

<p>In HCl, one hydrogen atom shares one electron with one chlorine atom. In Hâ‚‚O, one oxygen atom shares two electrons with two hydrogen atoms.</p> Signup and view all the answers

Why is the formation of ammonia-boron trifluoride an example of a coordinate covalent bond?

<p>Ammonia has a lone pair of electrons on the nitrogen atom, which it donates to the boron atom in BF3, which has an incomplete octet. This sharing of electrons forms a coordinate covalent bond.</p> Signup and view all the answers

Match the following types of covalent bonds with their descriptions:

<p>Non-polar covalent bond = Sharing of electrons between atoms of different elements Polar covalent bond = Sharing of electrons between atoms of the same element</p> Signup and view all the answers

Which of the following statements is true about ionic compounds?

<p>They have high density (B)</p> Signup and view all the answers

What are the two main factors that determine whether a bond will be ionic or covalent?

<p>Electronegativity difference and the number of valence electrons.</p> Signup and view all the answers

Ionic compounds are typically better conductors of electricity than covalent compounds.

<p>True (A)</p> Signup and view all the answers

Covalent compounds are typically good conductors of electricity in their solid state.

<p>False (B)</p> Signup and view all the answers

Which of the following factors is most favorable for the formation of a covalent bond?

<p>Similar electronegativity values of the atoms (D)</p> Signup and view all the answers

The electrostatic attraction between a partially positive hydrogen atom and a highly electronegative atom in the same or different molecule is called a ______ bond.

<p>hydrogen</p> Signup and view all the answers

Explain why ammonia (NH₃) has a higher boiling point than hydrogen chloride (HCl) despite having similar molecular weights.

<p>Ammonia (NH₃) forms hydrogen bonds due to the presence of a highly electronegative nitrogen atom and a hydrogen atom. These hydrogen bonds are strong intermolecular interactions, leading to a higher boiling point. However, hydrogen chloride (HCl) does not form hydrogen bonds because chlorine is less electronegative than nitrogen. Therefore, HCl's intermolecular forces are weaker, leading to a lower boiling point.</p> Signup and view all the answers

Match the following properties with the corresponding bond type:

<p>High melting and boiling points = Ionic bond Poor conductors of electricity in the solid state = Covalent bond Soluble in water, insoluble in organic solvents = Ionic bond Directional in nature = Covalent bond</p> Signup and view all the answers

Which of the following is NOT a property of covalent compounds?

<p>Good conductors of electricity in the solid state (D)</p> Signup and view all the answers

What is the dipole moment, and how is it related to the polarity of a molecule?

<p>Dipole moment (μ) is a measure of the polarity of a molecule. It is a vector quantity that indicates the magnitude and direction of the separation of positive and negative charges within a molecule. A larger dipole moment indicates a more polar molecule.</p> Signup and view all the answers

A coordinate covalent bond is a weak type of bond with similar characteristics to an ionic bond.

<p>False (B)</p> Signup and view all the answers

Intermolecular hydrogen bonds occur between atoms of the same molecule.

<p>False (B)</p> Signup and view all the answers

Which of the following substances exhibits intramolecular hydrogen bonding?

<p>o-nitrophenol (C)</p> Signup and view all the answers

What is the key difference between covalent bonds and hydrogen bonds?

<p>Covalent bonds involve the sharing of electrons between atoms, forming a strong bond. Hydrogen bonds are weaker intermolecular forces that arise from the attraction between a partially positive hydrogen atom and a highly electronegative atom.</p> Signup and view all the answers

The strength of a hydrogen bond is influenced by the ______ of the highly electronegative atom.

<p>electronegativity</p> Signup and view all the answers

Which of the following is an example of a compound that exhibits intermolecular hydrogen bonding?

<p>hydrogen fluoride (HF) (B)</p> Signup and view all the answers

Match the following types of bonds with their descriptions:

<p>Covalent bond = Formed by sharing electrons between atoms Hydrogen bond = Electrostatic attraction between a partially positive hydrogen atom and a highly electronegative atom Ionic bond = Formed by the transfer of electrons between atoms</p> Signup and view all the answers

Why is hydrogen bonding important in water?

<p>Hydrogen bonding is responsible for the unique properties of water, such as its high boiling point, high surface tension, and ability to act as a solvent.</p> Signup and view all the answers

In ______ hydrogen bonding, a ring structure is formed within the same molecule.

<p>intramolecular</p> Signup and view all the answers

Flashcards

Intermolecular Hydrogen Bonding

Hydrogen bond between different polar molecules.

Intramolecular Hydrogen Bonding

Hydrogen bond within the same molecule.

Difference between H-bond types

Intermolecular bonds are between different molecules, intramolecular are within one molecule.

Covalent Bond

Bond formed by sharing electrons between atoms.

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Hydrogen Bonding Strength

Depends on the electronegativity of the bonding atom.

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Example of Intermolecular Bonds

H₂O, HF, NH₃ show intermolecular hydrogen bonding.

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Example of Intramolecular Bonds

Ortho-nitrophenol illustrates intramolecular hydrogen bonding.

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Hydrogen Bond Definition

Electrostatic attraction between partially positive hydrogen and highly electronegative atom.

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Electron dot representation

A visual representation of an atom's valence electrons using dots around the element symbol.

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Valence electrons

Electrons in the outermost shell of an atom, involved in forming bonds.

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Lewis symbol

A simplified representation of an element showing its valence electrons as dots around the symbol.

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Hydrogen

The simplest element with 1 valence electron and symbol H.

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Covalent compounds

Compounds formed by the sharing of electrons between atoms, often displaying characteristic properties.

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Properties of covalent compounds

Usually gases or liquids at room temperature, low melting points, poor conductors, and vary in solubility.

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Formation of hydrogen chloride (HCl)

Formed when hydrogen shares its electron with chlorine, completing both their outer shells.

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Formation of water (Hâ‚‚O)

Occurs when two hydrogen atoms bond with one oxygen atom, each sharing electrons for stability.

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Chemical Bond

The association between atoms in a molecule via chemical forces.

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Ionic Bond

A bond formed by the transfer of electrons from one atom to another.

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Inert Gas Configuration

The stable arrangement of electrons similar to noble gases.

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Insulators

Materials that are poor conductors of electricity in solid state.

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Hydrogen Bond

Attraction between a positively charged hydrogen atom and an electronegative atom.

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Coordinate Covalent Bond

A strong bond formed by one atom donating both electrons to another atom.

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Boiling Point Comparison

NH₃ has a higher boiling point than HCl due to hydrogen bonding.

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Dipole Moment

A measure of the polarity of a polar covalent bond or molecule.

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Covalent Bond Properties

Covalent compounds are gases or liquids at room temp with low melting points.

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Factors for Covalent Bond Formation

Less electronegativity difference; valence electrons are 4-7.

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Common Traits of Covalent Compounds

Soft, poor conductors and generally insoluble in polar solvents.

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Carbon Dioxide Formation

COâ‚‚ forms when carbon shares electrons with oxygen.

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Donor Atom

The atom that provides the electron pair in a coordinate bond.

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Acceptor Atom

The atom that receives the electron pair in a coordinate bond.

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Non-Polar Covalent Bond

A bond formed by equal sharing of electrons between identical atoms.

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Polar Covalent Bond

A bond formed by unequal sharing of electrons between different elements.

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Ionic Compounds

Formed from cations and anions; generally crystalline with high densities.

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Study Notes

Types of Hydrogen Bonding

  • Two types of hydrogen bonding occur in molecules: intermolecular and intramolecular.
  • Intermolecular hydrogen bonding: A hydrogen bond formed between two different polar molecules (either the same or different substances). This type of bonding is present in water, hydrogen fluoride, and ammonia.
  • Intramolecular hydrogen bonding: A hydrogen bond formed between atoms within the same molecule. This type of bonding involves only one molecule and results in a ring formation. Examples include ortho-fluorophenol, ortho-nitroaniline, and o-nitrophenol.

Key Points About Hydrogen Bonding

  • Hydrogen bonding is a special type of dipole-dipole interaction.
  • The strength of the hydrogen bond depends on the electronegativity of the highly electronegative atom to which the hydrogen is bonded.
  • Examples of molecules exhibiting significant intermolecular hydrogen bonding include p-nitrophenol.

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