Titration indicator selection

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Questions and Answers

During the titration of 50 mL of 0.1 M sodium hydroxide with 25 mL of acetic acid, which indicator from the table is most appropriate to use?

  • Methyl orange, because the pH at equivalence point is equal to 7
  • Methyl orange, because the pH at equivalence point is less than 7
  • Phenolphthalein, because the pH at equivalence point is equal to 7
  • Phenolphthalein, because the pH at equivalence point is greater than 7 (correct)

Why is it important to select an appropriate indicator for acid-base titrations?

  • To ensure the reaction proceeds at a measurable rate.
  • To prevent the formation of unwanted byproducts.
  • To catalyze the neutralization reaction.
  • To ensure a sharp color change occurs near the equivalence point. (correct)

What is the key factor to consider when choosing an indicator for a titration?

  • The pH range where the indicator changes color. (correct)
  • The speed at which the indicator changes color.
  • The molar mass of the indicator.
  • The color of the indicator in its acidic form.

What would be the impact of using an indicator with a color change range that does NOT include the equivalence point pH in a titration?

<p>The accuracy of the titration will be compromised. (A)</p> Signup and view all the answers

In a titration of a strong acid with a strong base, which of the following indicators would be most suitable?

<p>An indicator that changes color around pH 7. (A)</p> Signup and view all the answers

Calculate the number of moles of sodium hydroxide used in the titration described in the image.

<p>0.005 moles (D)</p> Signup and view all the answers

50 mL of 0.1 M sodium hydroxide is used to titrate 25 mL of acetic acid. What can you infer about the concentration of the acetic acid?

<p>The concentration of acetic acid is greater than 0.1 M. (B)</p> Signup and view all the answers

During a titration, a student observes that the indicator changes color before the expected equivalence point. What is the most likely cause of this error?

<p>The indicator was added in excess. (C)</p> Signup and view all the answers

What type of reaction takes place during an acid-base titration?

<p>Neutralization reaction (B)</p> Signup and view all the answers

Which of the following best describes the equivalence point in an acid-base titration?

<p>The point at which the acid and base are completely reacted in stoichiometric proportions. (B)</p> Signup and view all the answers

Consider a weak acid being titrated with a strong base. At what point in the titration is the concentration of the weak acid equal to the concentration of its conjugate base?

<p>At the half-equivalence point (C)</p> Signup and view all the answers

What is the purpose of standardizing a titrant?

<p>To accurately determine its concentration (B)</p> Signup and view all the answers

If the concentration of the NaOH titrant is not accurately known, how will this affect the titration results?

<p>The calculated concentration of the analyte will be inaccurate. (D)</p> Signup and view all the answers

What type of error is introduced if the tip of the burette is not completely filled before starting a titration?

<p>Systematic error (B)</p> Signup and view all the answers

During a titration, a student overshoots the endpoint, adding too much titrant. What is the best course of action?

<p>Start the titration over from the beginning. (D)</p> Signup and view all the answers

In the titration described, what piece of lab equipment is crucial for the accurate delivery of the titrant?

<p>Burette (A)</p> Signup and view all the answers

Why is it important to gently swirl or stir the solution in the flask during a titration?

<p>To ensure thorough mixing of the reactants (A)</p> Signup and view all the answers

What does a titration curve typically show?

<p>The change in pH as the titrant is added. (C)</p> Signup and view all the answers

Which of the following is a primary standard suitable for standardizing a sodium hydroxide solution?

<p>Potassium hydrogen phthalate (KHP) (C)</p> Signup and view all the answers

During a titration experiment, distilled water is used to rinse the walls of the Erlenmeyer flask. What effect does this have on the titration?

<p>It ensures all the analyte reacts, without changing the number of moles present. (C)</p> Signup and view all the answers

Flashcards

What is an indicator?

A chemical substance that indicates the acidity or alkalinity of a solution through color change.

Which indicator is suitable for the titration of sodium hydroxide with acetic acid?

Phenolphthalein is suitable, because the pH value will be greater than 7 for the neutral solution.

What is Indicator range?

The pH range over which the indicator changes color.

Study Notes

  • 50 ml of sodium hydroxide with a concentration of 0.1 M was titrated with 25 ml of acetic acid
  • The question is: Using the following table, what is the appropriate indicator for the titration?

Indicators

  • Phenolphthalein indicator range: 8.3-10
  • Methyl orange indicator range: 3.1-4.4

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