Super Plasticizers: SMF vs SNF
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Questions and Answers

What is the purpose of using water-reducing admixtures or plasticizers in concrete?

  • To increase the water-cement ratio
  • To reduce the strength of concrete
  • To achieve higher strength by decreasing the water-cement ratio at the same workability (correct)
  • To decrease the workability of concrete
  • What is the function of plasticizers in concrete with respect to the heat of hydration?

  • Have no effect on heat of hydration
  • Decrease heat of hydration (correct)
  • Accelerate heat of hydration
  • Increase heat of hydration
  • Which type of compound are plasticizers based on?

  • Finely ground solid materials
  • Water-soluble compounds
  • Metallic salts
  • Organic polymers (correct)
  • How do plasticizers affect the workability of concrete?

    <p>Increase workability</p> Signup and view all the answers

    Which purpose do plasticizers serve in relation to cement content?

    <p>Decrease cement content to reduce heat of hydration</p> Signup and view all the answers

    What is the relationship between water reduction and strength of concrete?

    <p>Reducing water-cement ratio enhances strength</p> Signup and view all the answers

    Which type of polymer are plasticizers typically derived from?

    <p>Natural polymers</p> Signup and view all the answers

    What is the impact of using plasticizers on cracks in young concrete?

    <p>Decrease likelihood of cracks through increased strength</p> Signup and view all the answers

    How do plasticizers affect the water-cement ratio and workability simultaneously?

    <p>Decrease water-cement ratio while maintaining workability</p> Signup and view all the answers

    What is one common material that is used as a plasticizer in concrete?

    <p>Lignosulphonates</p> Signup and view all the answers

    Study Notes

    Super Plasticizers

    • Sulphonated melamine formaldehyde condensates (SMF) provide 16-25% water reduction with little or no retardation, giving a good finish and no staining in white concrete.
    • Sulphonated naphthalene formaldehyde condensates (SNF) offer 16-25% water reduction, but tend to increase the entrapment of larger, unstable air bubbles, with retardation more than SMF but not exceeding 90 minutes.
    • Polycarboxylate ether superplasticizers (PCE) give 20-35% water reduction, are relatively expensive but powerful, and require a lower dose due to high efficiency.

    Accelerators

    • Accelerators increase the rate of hydration of hydraulic cement, shorten the time of set-in concrete, and increase the rate of hardening or strength development.
    • Calcium chloride is the most effective accelerator, but its use is limited due to acceleration of corrosion of steel reinforcement and decrease in resistance of cement paste in a sulfate environment.
    • Chloride-free accelerators are based on salts of nitrate, nitrite, formate, and thiocyanate.
    • WRA (Workability Retention Agent) increases initial concrete compressive strength by 10% and achieves higher concrete density, making it less permeable and more durable.

    Mechanisms of Super Plasticizers

    • Dispersion: Surface active agents alter the physical-chemical forces at the interface, adsorbing on cement particles, giving them a negative charge, and causing repulsion and disintegration, making free water available for workability.
    • Lubrication: Organic agents lubricate the mix, reducing friction and increasing workability.
    • Retardation: A thin layer forms over cement particles, protecting them from hydration and increasing the setting time, with most normal plasticizers giving 30-90 minutes of retardation.

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    Description

    Learn about the commonly used super plasticizers in concrete - Sulphonated melamine formaldehyde condensates (SMF) and Sulphonated naphthalene formaldehyde condensates (SNF). Compare their water reduction percentages, effects on retardation, air bubble entrapment, and appearance in concrete.

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