Structural Isomerism in Chemistry

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5 Questions

What is the classical example of structural isomerism mentioned in the text?

Cyanate ion O=C=N− and fulminate ion C−≡N+−O−

Which term was formerly used for the same concept as structural isomer?

Metamer

What distinguishes stereoisomerism from structural isomerism?

Relative spatial arrangement of atoms

Which type of isomerism concerns the most radical differences in atomic bonding and arrangement?

Structural isomerism

What do enantiomers represent in terms of spatial arrangement?

Mirror images of each other

Study Notes

Types of Isomerism

  • Butane and isobutane are classical examples of structural isomerism.
  • The term 'metamerism' was formerly used to describe structural isomerism.

Stereoisomerism vs Structural Isomerism

  • Stereoisomerism differs from structural isomerism in that it involves a difference in spatial arrangement of atoms, while maintaining the same bond sequence.
  • Structural isomerism, on the other hand, involves a difference in bond sequence, leading to distinct molecules.

Types of Isomerism

  • Structural isomerism concerns the most radical differences in atomic bonding and arrangement.

Enantiomers

  • Enantiomers represent non-superimposable mirror images of each other in terms of spatial arrangement.

Test your knowledge of structural isomers in chemistry with this quiz. Identify compounds with the same molecular formula but distinct structural arrangements of atoms and bonds.

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