Strong Acids and Bases

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Questions and Answers

Which of the following is not considered one of the seven common strong acids?

  • Nitric acid (HNO3)
  • Sulfuric acid (H2SO4)
  • Hydrochloric acid (HCl)
  • Acetic acid (CH3COOH) (correct)

Why is H2SO4 categorized differently from HCl, HNO3, HBr, HI, HClO3, and HClO4?

  • It contains sulfur, giving it unique properties.
  • It is a weak acid, unlike the others.
  • It does not fully ionize in solution.
  • It is a diprotic acid, while the others are monoprotic. (correct)

In a solution of a strong monoprotic acid, what is the relationship between the concentration of the acid and the concentration of $H^+$ ions?

  • The $H^+$ concentration is equal to the square root of the original acid concentration.
  • The $H^+$ concentration is the same as the original acid concentration. (correct)
  • The $H^+$ concentration is half of the original acid concentration.
  • The $H^+$ concentration is negligible compared to the original acid concentration.

What is the pH of a 0.001 M solution of hydrobromic acid (HBr)?

<p>3 (A)</p> Signup and view all the answers

An aqueous solution of $HClO_4$ has a pH of 2. What is the concentration of the acid?

<p>0.01 M (C)</p> Signup and view all the answers

Which of the following is a characteristic of strong bases in aqueous solution?

<p>They completely dissociate into ions. (C)</p> Signup and view all the answers

Identify which of the following compounds is not a strong base?

<p>NH3 (C)</p> Signup and view all the answers

A solution is labeled as 0.50 M KOH. What does this indicate about the composition of the solution?

<p>It contains 0.50 M $K^+$ ions and 0.50 M $OH^−$ ions. (A)</p> Signup and view all the answers

The pH of a solution of NaOH is 12. What is the concentration of $H^+$ ions in this solution?

<p>$1 \times 10^{-12} \text{ M}$ (D)</p> Signup and view all the answers

The pH of a solution of Ca(OH)2 is 11. What is the pOH of this solution?

<p>3 (C)</p> Signup and view all the answers

A solution of KOH has a pH of 11.89. What is the concentration of the solution?

<p>$7.8 \times 10^{-3} \text{ M}$ (D)</p> Signup and view all the answers

For a solution of $Ca(OH)_2$ to have a pH of 11.68, what must be the concentration of the $Ca(OH)_2$?

<p>$2.38 \times 10^{-3} \text{ M}$ (C)</p> Signup and view all the answers

Calculate the pH of a 0.050 M solution of nitric acid ($HNO_3$).

<p>1.30 (B)</p> Signup and view all the answers

Determine the concentration of $H^+$ in a solution of hydroiodic acid (HI) with a pH of 1.7.

<p>$2.0 \times 10^{-2} \text{ M}$ (C)</p> Signup and view all the answers

What is the $OH^-$ concentration in a solution of 0.005 M NaOH?

<p>0.005 M (C)</p> Signup and view all the answers

Flashcards

Strong Acids

Acids that completely ionize in solution, donating all their protons (H⁺).

Examples of Common Strong Acids

HCl, HNO3, H2SO4, HBr, HI, HClO3, HClO4

[H+] in Strong Monoprotic Acids

For strong monoprotic acids, the concentration of H+ ions is equal to the initial concentration of the acid.

Common Strong Bases

Ionic hydroxides of alkali metals (NaOH, KOH, etc.) and heavier alkaline earth metals [Sr(OH)2].

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pH Calculation Formula

pH = -log[H+]

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Complete Dissociation (Acids/Bases)

This occurs when acids completely dissociate into ions in aqueous solution.

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Ca(OH)₂ Dissociation

A strong base that produces two hydroxide ions (OH-) when it dissociates.

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Monoprotic Acid

Acids that donate one proton (H⁺) per molecule.

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Study Notes

Strong Acids

  • Seven common strong acids exist, including six monoprotic acids and one diprotic acid.
  • Common strong acids are:
  • HCl - hydrochloric acid
  • HNO₃ – nitric acid
  • H₂SO₄ – sulfuric acid
  • HBr - hydrobromic acid
  • HClO₃ – chloric acid
  • HI - hydroiodic acid
  • HClO₄ – perchloric acid
  • For a strong monoprotic acid, [H+] equals the original concentration of the acid.
  • Nitric acid (HNO₃) is a strong, monoprotic acid, so the original acid concentration equals the concentration of hydrogen ions.
  • pH of a 0.040 M solution of HClO₄ is 1.40.
  • [H+] = 0.040 M
  • pH = -log[H+]
  • pH = -log(0.040)= 1.40
  • An aqueous solution of HNO3 has a pH of 2.34, and the concentration of the acid is 4.57 × 10-3 M.
  • pH = -log[H+]
  • 2.34 = -log[H+]
  • 10^-2.34 = [H+]= 0.00457 M

Strong Bases

  • Most common strong bases are the ionic hydroxides of alkali metals (NaOH, KOH, etc.)
  • Ionic hydroxides of the heavier alkaline metals, such as Sr(OH)₂, are also strong bases.
  • Strong bases completely dissociate into ions in aqueous solution.
  • A solution labeled 0.30 M NaOH consists of 0.30 M Na⁺(aq) and 0.30 M OH⁻(aq).

Calculating the pH of a Strong Base

  • The pH of a 0.028 M solution of NaOH is 12.45.
  • (H+)(0.028 M OH) = 1.0 × 10⁻¹⁴
  • [H+] = 3.57 × 10⁻¹³ M
  • -log (3.57 × 10⁻¹³) = pH
  • Ca(OH)₂ dissociates to produce two OH- ions.
  • The pH of a 0.0011 M solution of Ca(OH)2 is 11.34.
  • (H+)(2 × 0.0011 M OH-) = 1.0×10⁻¹⁴
  • [H+] = 4.55 × 10⁻¹² M
  • -log (4.55 × 10⁻¹²) = pH
  • The concentration of a solution of KOH is 7.8 x 10^-3 if the pH is 11.89.
  • KOH is a strong base that dissociates to produce one OH-
  • The concentration of a solution of Ca(OH)₂ is 2.38 × 10⁻³ M if the pH is 11.68
  • Ca(OH)₂ is a strong base that dissociates to produce two OH-

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