Stoichiometry in Aqueous Solutions

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Questions and Answers

In a reaction involving glucose and oxygen, if 10 grams of glucose produces 0.33 moles of water, how many grams of water are produced?

  • 12.0 grams
  • 8.34 grams
  • 3.0 grams
  • 5.94 grams (correct)

What is the limiting reactant when 0.5 mole of HCl is reacted with 0.7 grams of NaOH, given the reaction HCl + NaOH → H2O + NaCl?

  • NaOH
  • NaCl
  • HCl (correct)
  • Water

How would you calculate the percent composition of lithium in Li2O?

  • (30 / 7) x 100
  • (2 / 7) x 100
  • (16 / 30) x 100
  • (7 x 2 / 30) x 100 (correct)

What mass of CO2 is produced when 0.055 moles of glucose are completely combusted?

<p>14.52 grams (B)</p> Signup and view all the answers

What does the term 'molecular weight' refer to in the context of percent composition?

<p>The total weight of all elements in a compound (D)</p> Signup and view all the answers

If a compound has a molecular weight of 30.0 and contains 2 carbon atoms, what is the percent composition of carbon in that compound?

<p>80.0% (B)</p> Signup and view all the answers

In the balanced equation representation, what role do the coefficients of A and B represent?

<p>The stoichiometric ratios in the reaction (D)</p> Signup and view all the answers

What is the percent composition of hydrogen in H2O?

<p>11.1% (A)</p> Signup and view all the answers

Calculate the number of grams of H2O produced when 3.3 moles of NH3 are reacted with excess oxygen.

<p>59.46 g (A)</p> Signup and view all the answers

When 12 grams of O2 are used in a reaction that produces NO, how many grams of NO can be produced?

<p>9.00 g (C)</p> Signup and view all the answers

What is the molecular weight (MWt.) of propylene, C3H6?

<p>46.0 amu (B)</p> Signup and view all the answers

If 15 moles of H2O are produced, how many moles of H2 are consumed in the reaction 2 H2 + O2 -> 2 H2O?

<p>10 moles (D)</p> Signup and view all the answers

Which of the following is the primary purpose of stoichiometry in chemical reactions?

<p>To solve mass relationships (C)</p> Signup and view all the answers

In the reaction 4NH3 + 5O2 --> 6H2O + 4NO, what is the limiting reactant when 3 moles of NH3 and 5 moles of O2 are present?

<p>NH3 (B)</p> Signup and view all the answers

How many grams of O2 are produced when 2 moles of NO are formed in the reaction 4NH3 + 5O2 --> 6H2O + 4NO?

<p>8 g (B)</p> Signup and view all the answers

If the molecular weight of H2O is approximately 18.02 amu, how many grams would be present in 5 moles of H2O?

<p>90.10 g (D)</p> Signup and view all the answers

Which ions indicate that a precipitation reaction has occurred?

<p>Ag+ and Cl- (A)</p> Signup and view all the answers

Which of the following compounds contains ions that will always be soluble in water?

<p>K2SO4 (A)</p> Signup and view all the answers

What type of reaction occurs when an acid neutralizes a base?

<p>Acid-base Reaction (D)</p> Signup and view all the answers

Among the compounds listed, which is considered insoluble in water?

<p>AgCl (B)</p> Signup and view all the answers

Which of the following statements is true regarding heat of reaction?

<p>The heat of combustion is associated with exothermic reactions. (B)</p> Signup and view all the answers

Which of these ions is associated with a gas forming reaction?

<p>H+ (D)</p> Signup and view all the answers

Which combination of ions will result in no reaction when mixed in solution?

<p>Na+ and Cl- (C)</p> Signup and view all the answers

What is the defining characteristic of an ionic compound that is soluble in water?

<p>It must dissociate into ions when dissolved. (A)</p> Signup and view all the answers

Flashcards

Avogadro's number

The number of molecules in 1 mole of any substance. It's a constant value used to convert between moles and the number of molecules.

Molar mass

The mass of 1 mole of a substance, expressed in grams per mole (g/mol). It's calculated by adding the atomic weights of all atoms in the molecule.

Limiting reactant

The amount of reactant that is completely consumed in a chemical reaction, limiting the amount of product that can be formed.

Percent yield

The ratio of the actual yield of a product to the theoretical yield, expressed as a percentage.

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Stoichiometry

Using the coefficients in a balanced chemical equation to calculate the amounts of reactants and products involved in a reaction.

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Enthalpy of reaction

The amount of heat released or absorbed during a chemical reaction.

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Solubility rules

Predicting whether a reaction will occur in an aqueous solution, based on the formation of a precipitate, gas, or weak electrolyte.

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Exothermic reaction

A reaction that produces heat, increasing the temperature of the surroundings.

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Endothermic reaction

A reaction that absorbs heat from the surroundings, decreasing the temperature.

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Gram-to-Gram Conversion

A process that converts grams of one substance to grams of another using molar masses and stoichiometric coefficients.

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Percent Composition

The percentage of the total mass of a compound that is contributed by each element.

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Theoretical Yield

The maximum amount of product that can be formed from a given amount of reactants.

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Combustion Reaction

A reaction in which a substance reacts rapidly with oxygen, releasing energy in the form of heat and light.

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Decomposition Reaction

The process of breaking down a compound into its constituent elements.

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Redox Reaction

A chemical reaction that involves the transfer of electrons between two or more reactants.

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Precipitation Reaction

A chemical reaction where two or more ions combine to form an insoluble solid, which then precipitates out of the solution.

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Gas Evolution Reaction

A chemical reaction where two ions combine to form a gas that escapes from the reaction mixture as bubbles.

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Neutralization Reaction

A chemical reaction between an acid and a base, usually resulting in the formation of salt and water.

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Heat of Reaction

The heat released or absorbed in a chemical reactions.

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Heat of Combustion

The heat released or absorbed in a combustion reaction.

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Study Notes

Stoichiometry & Chemical Reactions in Aqueous Solution

  • Learning Objectives: Students will be able to solve stoichiometric problems, calculate percent composition, understand limiting reactants, understand heat of reaction, and predict if ions react in aqueous solutions.

Moles and Molecular Scale

  • Moles provide a link between the molecular and macroscopic scales.
  • One mole of any substance contains the same number of molecules as Avogadro's number.
  • Mole relates grams of a substance to the number of molecules using molar mass.

Stoichiometric Calculations

  • Example: 2H₂(g) + O₂(g) → 2H₂O(l)
  • Mass (amu): 4.0 amu H₂ + 32.0 amu O₂ = 36.0 amu H₂O
  • Amount (mol): 2 mol H₂ + 1 mol O₂ = 2 mol H₂O
  • Mass (g): 4.0 g H₂ + 32.0 g O₂ = 36.0 g H₂O

Limiting Reactants

  • Limiting reactant: The reactant used up first in a reaction.
  • Excess reactant: The reactant left over after the reaction completes.
  • The limiting reactant determines the maximum amount of product formed.

Heat of Reaction

  • Exothermic reaction: A reaction that releases heat.
  • Endothermic reaction: A reaction that absorbs heat.
  • Heat of reaction is proportional to the amount of material.

Percent Composition

  • Percent composition: The percentage of each element in a compound.
  • Formula: (% element) = [(number of atoms)(atomic weight)] / (molecular weight of compound) × 100

Predicting Reactions in Aqueous Solutions

  • Many ionic compounds are soluble in water.
  • Ions can react in aqueous solutions under specific conditions: formation of an insoluble solid (precipitate), formation of a gas, neutralization reaction, or redox reaction.

Solubility Rules

  • Common compounds containing Na⁺, K⁺, or NH₄⁺ are soluble in water.
  • Nitrates and acetates are soluble in water.
  • Most chlorides and sulfates are soluble in water (exceptions exist).
  • Most carbonates, phosphates, sulfides, and hydroxides are insoluble in water (exceptions exist).

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