Stoichiometry and Chemical Reactions
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Questions and Answers

Using the ideal gas law, what is the pressure (in atmospheres) exerted by 3 moles of a gas at a temperature of 22.4 L and 273.15 K?

  • 1.0 atm
  • 9.0 atm
  • 6.0 atm
  • 3.0 atm (correct)

Which of the following statements correctly describes the relationship between variables in Charles's Law?

  • Pressure and temperature are directly proportional at constant volume and number of moles.
  • Volume and temperature are inversely proportional at constant pressure and number of moles.
  • Volume and temperature are directly proportional at constant pressure and number of moles. (correct)
  • Pressure and volume are directly proportional at constant temperature and number of moles.

A gas in a sealed container has a pressure of 3.00 atm, a volume of 10.0 L, and a temperature of 300.0 K. If the volume is increased to 15.0 L and the temperature is lowered to 200.0 K, what is the new pressure?

  • 1.33 atm (correct)
  • 4.50 atm
  • 1.00 atm
  • 2.00 atm

What change will increase the root mean square speed of $N_2$ gas?

<p>Increasing the temperature of the gas. (D)</p> Signup and view all the answers

In the van der Waals equation of state for real gases, what does the parameter 'b' account for?

<p>The volume excluded by gas molecules. (B)</p> Signup and view all the answers

A compound is composed of 92.2% carbon and 7.8% hydrogen by mass. What is the empirical formula of this compound?

<p>CH (C)</p> Signup and view all the answers

A compound containing carbon and hydrogen has an empirical formula of CH3 and a molecular mass of approximately 30.08 g/mol. What is its molecular formula?

<p>C2H6 (E)</p> Signup and view all the answers

Given the unbalanced reaction: C2H2(g) + O2(g) → CO(g) + H2O(g), what is the coefficient in front of O2(g) when the equation is balanced?

<p>5/2 (A)</p> Signup and view all the answers

Consider the reaction: Ag+(aq) + NaCl(aq) → AgCl(s) + Na+(aq). Which ion is the spectator ion?

<p>Na+(aq) (B)</p> Signup and view all the answers

What is the oxidation state of nitrogen in NaNO3?

<p>+5 (A)</p> Signup and view all the answers

In the unbalanced combustion reaction: C2H2(g) + O2(g) → CO(g) + H2O(g), which reactant acts as the reducing agent?

<p>C2H2(g) (A)</p> Signup and view all the answers

Given the reaction: 2 H2(g) + O2(g) → 2 H2O(g), if 8.08 g of H2(g) reacts with excess O2(g) to produce 54.06 g of H2O(g), what is the percent yield of the reaction?

<p>85.0% (D)</p> Signup and view all the answers

Consider the reaction: 2 C2H2(g) + 5 O2(g) → 4 CO2(g) + 2 H2O(g). If 13.02 g of C2H2(g) is combusted in excess oxygen, what mass of CO2(g) will be produced?

<p>44.0 g CO2 (A)</p> Signup and view all the answers

Flashcards

Avogadro's Law

Relates moles and volume of a gas at constant temperature and pressure.

Boyle's Law

Relates pressure and volume of a gas at constant temperature.

Charles's Law

Relates volume and temperature of a gas at constant pressure.

Moles and volume relationship

Volume is directly proportional to the number of moles.

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Pressure and temperature relationship

Pressure is directly proportional to temperature.

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Empirical Formula

The simplest whole-number ratio of atoms in a compound.

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Molecular Formula

The actual number of atoms of each element in a molecule.

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Molarity (M)

Moles of solute per liter of solution (mol/L).

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Dilution

The process of reducing the concentration of a solution by adding more solvent.

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Mass Percent

Ratio of the mass of the solute to the total mass of the solution, expressed as a percentage.

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Spectator Ion

An ion that does not participate in the reaction and remains unchanged in the solution.

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Oxidation State

A number that represents the hypothetical charge an atom would have if all bonds were completely ionic.

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Reducing Agent

A reactant that donates electrons to another species, causing it to be reduced in a redox reaction.

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Study Notes

  • A compound is 92.2% Carbon and 7.8% Hydrogen by mass.
  • The empirical formula for the compound is C2H2.
  • A compound containing carbon and hydrogen with an empirical formula of CH3 has a molecular mass of about 30.08 g/mole.
  • C2H6 is the molecular formula.
  • Molarity of H2O in 1.00 L of pure water, assuming a density of 1.00 g/mL, needs to be calculated.
  • 50.0 mL of a 10.0 M HNO3(aq) solution is diluted to a final volume to obtain a 2.0 M HNO3(aq) solution, this requires calculation.
  • A 2.500 M solution of propylene glycol (MM=76.09 g/mol) in water has a density of 1.030 g/mL.
  • The mass percent of propylene glycol in water needs to be calculated.

Balancing the reactions

  • The coefficient in front of O2(g) after balancing the reaction C2H2(g) + O2(g) -> CO(g) + H2O(g) should be provided.
  • The spectator ion in the reaction Ag+(aq) + NaCl(aq) -> AgCl(s) + Na+(aq) can be either: Ag+(aq), NaCl(aq), AgCl(s), Na+(aq), or Cl-(aq).
  • The oxidation state of nitrogen in NaNO3 must be determined.
  • In the unbalanced combustion reaction C2H2(g) + O2(g) -> CO(g) + H2O(g), the reducing agent is one of the following: carbon, hydrogen, or oxygen.
  • Alternatively, there might be no reducing agent in this unbalanced combustion reaction.
  • 8.08 g of H2(g) reacts with an excess of O2(g) to form 54.06 g of H2O(g) in the reaction 2 H2(g) + O2(g) -> 2 H2O(g).
  • The percent yield for this reaction needs to be determined.
  • A 20.00 mL sample of aqueous HCl is titrated with 15.00 mL of 0.100 M NaOH(aq).
  • The molarity of the HCl solution in mM must be calculated.
  • Given the balanced reaction 2 C2H2(g) + 5 O2(g) -> 4 CO2(g) + 2 H2O(g), 13.02 g of C2H2(g) is combusted in the presence of excess oxygen.
  • The mass of CO2(g) produced needs to be determined.
  • The pressure in atmospheres needs to be calculated for two moles of gas at 273.15 K in a container with a volume of 11.2 liters.

Matching Gas Laws

  • Avogadro's Law describes the relationship between moles and volume.
  • Boyle's Law describes the relationship between pressure and volume.
  • Charles's Law describes the relationship between volume and temperature.

Proportionality matching

  • Moles and volume are directly proportional.
  • Pressure and temperature are directly proportional.
  • Volume and temperature are directly proportional.
  • Moles and pressure are inversely proportional.
  • A gas sample has a volume of 20.5 L at 300.0 K and 2.00 atm.
  • The volume of the gas at 1.00 atm and 150.0 K must be determined.
  • The root mean squared speed of He(g) in the room, if the temperature of the room is 30.0 °C must be determined.
  • For a 2.00 mol sample of Cl2(g) at 300.0 K and a pressure of 2.00 atm, the van der Waals' volume (in liters) must be calculated.
  • For Cl2(g), a = 6.49 L² atm/mol² and b = 0.0652 L/mol
  • The van der Waals equation is given by [P + a(n/V)^2](V-nb) = nRT
  • The value of the $b$ parameter increases, the van der Waals' volume becomes less than the ideal volume under conditions of constant temperature and constant moles in the van der Waals equation..

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Description

Calculations based on balancing equations. Includes empirical and molecular formulas. Also covers molarity, dilutions, and mass percent calculations in solutions.

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