Podcast
Questions and Answers
What is thermodynamics primarily the study of?
What is thermodynamics primarily the study of?
- The motion of celestial bodies
- The structure of atoms
- Chemical reactions
- Energy and its behavior (correct)
According to the first law of thermodynamics, what happens to energy?
According to the first law of thermodynamics, what happens to energy?
- It is created
- It is destroyed
- It disappears
- It is transformed (correct)
In the context of thermodynamics, what happens when you put your hand on a cold surface?
In the context of thermodynamics, what happens when you put your hand on a cold surface?
- Heat transfers from your hand to the surface (correct)
- Cold transfers from the surface to your hand
- The surface gets colder
- No heat transfer occurs
What happens to the internal energy of a system that receives heat and performs work?
What happens to the internal energy of a system that receives heat and performs work?
In an isolated system, what can be said about the exchange of energy or matter?
In an isolated system, what can be said about the exchange of energy or matter?
When two or more objects are at different temperatures and are placed in contact, what will happen?
When two or more objects are at different temperatures and are placed in contact, what will happen?
What is required for any type of work to be performed?
What is required for any type of work to be performed?
What is work equal to when a force acts on an object causing displacement?
What is work equal to when a force acts on an object causing displacement?
What happens to the speed of a chemical reaction when the temperature increases?
What happens to the speed of a chemical reaction when the temperature increases?
Which factor can specifically modify the velocity of a reaction?
Which factor can specifically modify the velocity of a reaction?
What is a catalyst?
What is a catalyst?
In what units is the velocity of reaction usually measured?
In what units is the velocity of reaction usually measured?
What is the result of multiplying force and distance?
What is the result of multiplying force and distance?
What is the formula for calculating work?
What is the formula for calculating work?
What does the variable 'm' represent in calculating work using the formula $T=Fm$?
What does the variable 'm' represent in calculating work using the formula $T=Fm$?
What does the formula $E=mc^2$ state?
What does the formula $E=mc^2$ state?
What is the kinetic energy?
What is the kinetic energy?
What is always needed to produce work?
What is always needed to produce work?
What do living things do to survive successfully?
What do living things do to survive successfully?
What is the study of energy?
What is the study of energy?
Flashcards
Thermodynamics
Thermodynamics
The study of energy and its behavior.
First law of thermodynamics
First law of thermodynamics
Energy cannot be created nor destroyed; it transforms.
Concentration of Reactives
Concentration of Reactives
The amount of substance present in a certain volume.
Catalyst
Catalyst
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Work (Physics)
Work (Physics)
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Reaction Rate
Reaction Rate
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Kinetic Energy
Kinetic Energy
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Potential Energy
Potential Energy
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Energy and temperature change
Energy and temperature change
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Scalar magnitude
Scalar magnitude
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Study Notes
Statics - Chapter 2: Vectors
Vector Operations: Addition of Coplanar Forces
- The diagonal of a parallelogram represents the resultant force of two coplanar forces.
- The law of cosines can be used to determine the resultant force $F_R$: $F_R = \sqrt{F_1^2 + F_2^2 - 2F_1F_2\cos(\theta)}$.
- The law of sines can be used to determine the angle $\alpha$: $\frac{F_1}{\sin(\alpha)} = \frac{F_R}{\sin(\theta)}$.
Cartesian Vector Notation
- A 2D force vector can be expressed as $F = F_x i + F_y j$
- The magnitude of the force vector is $F = \sqrt{F_x^2 + F_y^2}$.
- The direction angle is given by $\theta = \tan^{-1}(\frac{F_y}{F_x})$.
Addition of Several Forces
- The resultant force is $F_R = \sum F_x i + \sum F_y j$
- The magnitude of the resultant force is $F_R = \sqrt{(\sum F_x)^2 + (\sum F_y)^2}$.
- The direction angle of the resultant force is $\theta = \tan^{-1}(\frac{\sum F_y}{\sum F_x})$.
Addition of System of 3D Forces
- A 3D force vector can be expressed as $F = F_x i + F_y j + F_z k$
- The magnitude of the force vector is $F = \sqrt{F_x^2 + F_y^2 + F_z^2}$.
Direction Cosines
- Direction cosines satisfy the equation $\cos^2(\alpha) + \cos^2(\beta) + \cos^2(\gamma) = 1$.
- $F_x = F\cos(\alpha)$
- $F_y = F\cos(\beta)$
- $F_z = F\cos(\gamma)$
Unit Vector
- A unit vector is given by $u = \frac{F}{|F|} = \frac{F_x}{|F|}i + \frac{F_y}{|F|}j + \frac{F_z}{|F|}k$
Position Vectors
- A position vector is given by $r = (x_2 - x_1)i + (y_2 - y_1)j + (z_2 - z_1)k$
- The magnitude of the position vector is $r = \sqrt{(x_2 - x_1)^2 + (y_2 - y_1)^2 + (z_2 - z_1)^2}$
Force Vector Directed Along a Line
- The force vector can be expressed as a product of its magnitude and a unit vector along the line of action, $F = F\frac{r}{|r|} = F_u = F\frac{(x_2 - x_1)}{|r|}i + F\frac{(y_2 - y_1)}{|r|}j + F\frac{(z_2 - z_1)}{|r|}k$
Dot Product
- The dot product can be calculated as $A \cdot B = |A||B|\cos(\theta)$.
- In terms of components, $A \cdot B = A_x B_x + A_y B_y + A_z B_z$.
Determining the Angle Between Two Vectors
- The angle $\theta$ between two vectors can be found using $\cos(\theta) = \frac{A \cdot B}{|A||B|} = \frac{A_x B_x + A_y B_y + A_z B_z}{|A||B|}$
Finding the Component of a Force Parallel to a Line
- $F' = F\cos(\theta) = F \cdot u$
- $F' = (F \cdot u)u$
Cross Product
- Magnitude of Cross Product: $A \times B = |A||B|\sin(\theta)$
- In terms of components: $$A \times B = \begin{vmatrix} i & j & k \ A_x & A_y & A_z \ B_x & B_y & B_z \end{vmatrix} = (A_yB_z - A_zB_y)i - (A_xB_z - A_zB_x)j + (A_xB_y - A_yB_x)k$$
Transformer
Overview
- The Transformer is a deep learning model proposed in 2017, widely used in machine translation and other NLP tasks.
- It has largely replaced RNNs in NLP due to its superior performance.
Overall Architecture
- The Transformer architecture consists of the input/output, encoder module, decoder module, residual connections, and layer normalization.
- Input is the word embeddings of the input words
- Output is the probability distribution of the output word predictions.
- The encoder and decoder modules are composed of N stacked encoder and decoder layers respectively.
Encoder Module
- The encoder is composed of multiple encoder layers stacked on top of each other.
- Each encoder layer primarily contains a multi-head self-attention mechanism and a feedforward neural network.
Multi-Head Self-Attention
- Multi-head self-attention computes the relationships between words in the input sentence.
- It comprises scaled dot-product attention and multiple heads which enable the model to learn information from different representation subspaces.
Scaled Dot-Product Attention
- Attention is calculated as $Attention(Q, K, V) = softmax(\frac{QK^T}{\sqrt{d_k}})V$
- Q refers to the Query matrix
- K is the Key matrix
- V is the Value matrix
- $d_k$ is the dimensionality of the keys.
Multi-Head
- The calculation is $MultiHead(Q, K, V) = Concat(head_1,..., head_h)W^O$
- Where $head_i = Attention(QW_i^Q, KW_i^K, VW_i^V)$
- $W_i^Q$, $W_i^K$, and $W_i^V$ are weight matrices for queries, keys and values.
- $W^O$ is the projection matrix.
FeedForward Neural Network
- The feed-forward network applies a non-linear transformation to the output of the attention layer
- The calculation is $FFN(x) = ReLU(xW_1 + b_1)W_2 + b_2$
Decoder Module
- The decoder module mirrors the encoder by consisting of N decoder layers.
- Each decoder layer contains masked multi-head self-attention, encoder-decoder attention, and a feedforward network.
Masked Attention
- Masking prevents the decoder from attending to future tokens, which is achieved by setting the corresponding values to $-\infty$ before applying the softmax function.
Encoder-Decoder Attention
- Encoder-decoder attention allows the decoder to focus on relevant parts of the input sequence from the encoder
Positional Encoding
- Since the Transformer lacks recurrence, positional encodings are added to the input embeddings.
- These are functions of sine and cosine:
- $PE_{(pos,2i)} = sin(pos/10000^{2i/d_{model}})$
- $PE_{(pos,2i+1)} = cos(pos/10000^{2i/d_{model}})$
- pos is the position
- i is the dimension
- $d_{model}$ is the dimension of the model.
Chemical Engineering Thermodynamics - Chapter 3: Volumetric Properties of Pure Fluids
Virial Equation of State
- $Z = 1 + \frac{B}{V} + \frac{C}{V^2} + \frac{D}{V^3}+...$
- Z = PV/RT, where Z is the compressibility factor
- Capital letters are virial coefficients
- Alternative form $Z = 1 + B'\rho + C'\rho^2 + D'\rho^3 +...$
- $\rho = 1/V$, where $\rho$ is density
- $B' = B, C' = (C-B^2), D' = (D-3BC+2B^3)$
Ideal Gas Model
- $PV = RT$
- V is volume per mole
- $R = 8.314 J/mol.K$
Van der Waals Equation of State
- $P = \frac{RT}{V-b} - \frac{a}{V^2}$
- Accounts for intermolecular forces
- $a = \frac{27(RT_c)^2}{64P_c}$
- $b = \frac{RT_c}{8P_c}$
Redlich/Kwong Equation of State
- $P = \frac{RT}{V-b} - \frac{a}{T^{1/2}V(V+b)}$
- $a = \frac{0.42748R^2T_c^{2.5}}{P_c}$
- $b = \frac{0.08664RT_c}{P_c}$
Soave/Redlich/Kwong Equation of State
- $P = \frac{RT}{V-b} - \frac{\alpha a}{V(V+b)}$
- $a = \frac{0.42748R^2T_c^2}{P_c}$
- $b = \frac{0.08664RT_c}{P_c}$
- $\alpha = [1 + m(1 - T_r^{0.5})]^2$
- $m = 0.480 + 1.574\omega - 0.176\omega^2$
- $T_r = \frac{T}{T_c}$
Peng Robinson
- $P = \frac{RT}{V-b} - \frac{a\alpha}{V^2 + 2bV - b^2}$
- $a = 0.45724\frac{R^2T_c^2}{P_c}$
- $b = 0.07780\frac{RT_c}{P_c}$
- $\alpha = [1 + m(1 - T_r^{0.5})]^2$
- $m = 0.37464 + 1.54226\omega - 0.26992\omega^2$
- $T_r = \frac{T}{T_c}$
Generalized Correlations for the Virial Coefficients
- $B = \frac{RT_c}{P_c}(B^0 + \omega B^1)$
- $B^0 = 0.083 - \frac{0.422}{T_r^{1.6}}$
- $B^1 = 0.139 - \frac{0.172}{T_r^{4.2}}$
Volume as a Function of T & P
- $dV = (\frac{\partial V}{\partial T})_pdT + (\frac{\partial V}{\partial P})_TdP$
Volume Expansivity
- $\beta = \frac{1}{V}(\frac{\partial V}{\partial T})_p$
Isothermal Compressibility
- $\kappa = -\frac{1}{V}(\frac{\partial V}{\partial P})_T$
Fonction et limites: Exercices
Limites
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Exercice 1: Calculation of various limits, including polynomial, rational, and radical functions.
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Exercice 2: Calculation of limits, focusing on indeterminate forms and trigonometric functions.
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Exercice 3: Evaluation of standard limits, like those with exponential, logarithmic, and inverse trigonometric functions.
Fonctions (Functions)
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Exercice 4: Study functions, including determining domain, derivative, variations, and limits.
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Exercice 5: Given $f(x) = \frac{x^2 - 1}{x^2 + 1}$, determination of the domain, calculation of the derivative, study of variations, determining the limits at the boundaries of its domain and graphing.
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Exercice 6: Given $f(x) = x + \sqrt{x^2 + 1}$, determination of the domain, calculation of the derivative, study of variations, determining the limits at the boundaries of its domain and proving $f$ is bijective from $\mathbb{R}$ to $\mathbb{R}$.
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Exercice 7: Given $f(x) = \frac{\cos(x)}{\sin(x)}$, determination of the domain, calculation of the derivative, study of variations on the interval $]0, \pi[$, determining limits at the boundaries of its domain and graphing.
Funciones vectoriales
Definition
- Vector function: a function whose domain is a subset of real numbers and whose range is a set of vectors.
- 2D Vector: $\vec{r}(t) = \langle f(t), g(t) \rangle = f(t) \hat{i} + g(t) \hat{j}$.
- 3D Vector: $\vec{r}(t) = \langle f(t), g(t), h(t) \rangle = f(t) \hat{i} + g(t) \hat{j} + h(t) \hat{k}$, where f,g, h are real-valued functions.
Limits and Continuity
- Limit of a vector function: $\lim_{t \to a} \vec{r}(t) = \langle \lim_{t \to a} f(t), \lim_{t \to a} g(t), \lim_{t \to a} h(t) \rangle$ (provided the limits exist).
- Vector function $\vec{r}(t)$ is continuous at $t = a$ if $\vec{r}(a)$ is defined, the limit exists, and $\lim_{t \to a} \vec{r}(t) = \vec{r}(a)$. Each component function must be continuous.
Derivatives
- Derivative of a vector function: $\frac{d\vec{r}}{dt} = \vec{r}'(t) = \lim_{\Delta t \to 0} \frac{\vec{r}(t + \Delta t) - \vec{r}(t)}{\Delta t}$.
- If $\vec{r}(t) = \langle f(t), g(t), h(t) \rangle$, then: $\vec{r}'(t) = \langle f'(t), g'(t), h'(t) \rangle$.
- $\vec{r}'(t)$ is a tangent vector provided it is nonzero and the derivative exists. The tangent line at $P$ (defined by $\vec{r}(t_0)$) is parallel to $\vec{r}'(t_0)$.
Differentiation Rules
- If $\vec{u}$ and $\vec{v}$ are differentiable vector functions, f is a differentiable scalar function, and c is a constant, then:
- $\frac{d}{dt} [\vec{c}] = \vec{0}$.
- $\frac{d}{dt} [c \vec{r}(t)] = c \vec{r}'(t)$.
- $\frac{d}{dt} [\vec{u}(t) + \vec{v}(t)] = \vec{u}'(t) + \vec{v}'(t)$.
- $\frac{d}{dt} [f(t) \vec{r}(t)] = f'(t) \vec{r}(t) + f(t) \vec{r}'(t)$.
- $\frac{d}{dt} [\vec{u}(t) \cdot \vec{v}(t)] = \vec{u}'(t) \cdot \vec{v}(t) + \vec{u}(t) \cdot \vec{v}'(t)$.
- $\frac{d}{dt} [\vec{u}(t) \times \vec{v}(t)] = \vec{u}'(t) \times \vec{v}(t) + \vec{u}(t) \times \vec{v}'(t)$.
- $\frac{d}{dt} [\vec{u}(f(t))] = f'(t) \vec{u}'(f(t))$.
Integrals
- Indefinite integral: $\int \vec{r}(t) dt = \langle \int f(t) dt, \int g(t) dt, \int h(t) dt \rangle$.
- Definite integral: $\int_a^b \vec{r}(t) dt = \langle \int_a^b f(t) dt, \int_a^b g(t) dt, \int_a^b h(t) dt \rangle$.
Statistical Inference
Introduction
- Statistical inference: Drawing conclusions about a population from a sample.
- Population: Entire group of interest.
- Sample: Subset of population.
- Parameter: Describes population.
- Statistic: Describes sample.
Point Estimation
- Single value estimate of a population parameter
- Method of Moments: Equating sample to population moments.
- Maximum Likelihood Estimation (MLE): Maximizing likelihood function.
Interval Estimation
- Range of values to estimate parameter.
- Confidence Interval (CI): $$ CI = [\hat{\theta} - z_{\alpha/2}SE(\hat{\theta}), \hat{\theta} + z_{\alpha/2}SE(\hat{\theta})] $$
Hypothesis Testing
- Procedure for decisions about parameters
- Null Hypothesis ($H_0$): Parameter statement assumed true unless proven otherwise
- Alternative Hypothesis ($H_1$ or $H_a$): Contradicts null hypothesis, accepted if null rejected
- Test Statistic: Value from sample data to assess evidence
- P-value: Probability of test statistic extreme or more, assuming $H_0$ is true.
- Significance level ($\alpha$): probability of rejecting null hypothesis when it is true (Type I error).
Regression Analysis
- Statistical technique to model relation
Simple Linear Regression
- Relationship w/ dependent variable using equation: $y = \beta_0 + \beta_1x + \epsilon$
Multiple Linear Regression
- Relationship w/ dependent variable using equation: $y = \beta_0 + \beta_1x_1 + \beta_2x_2 +... + \beta_px_p + \epsilon$
Analysis of Variance (ANOVA)
- Method for comparing the means of groups
One-Way ANOVA
- When independent variable has 1 factor
Two-Way ANOVA
- When independent variable has 2+ factors
Non-parametric Methods
- Does not assume a specific distribution
Chi-Square Test
- Used to the test the independence of categorical variables
Sign Test
- Used to text to median of a population
Bayesian Inference
- Combines prior beliefs with sample data
Bayes' Theorem :
- $P(A|B) = \frac{P(B|A)P(A)}{P(B)}$
Algèbre Linéaire et Géométrie Analytique I
Chapitre 1: Systèmes d'Équations Linéaires
1.1 Introduction
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Équation linéaire: $a_1x_1 + a_2x_2 +... + a_nx_n = b$, where $a_i$ and $b$ are real constants.
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Système d'équations linéaires: A set of linear equations with the same variables. Example:
- $a_{11}x_1 + a_{12}x_2 +... + a_{1n}x_n = b_1$
- $a_{21}x_1 + a_{22}x_2 +... + a_{2n}x_n = b_2$
- $...$
- $a_{m1}x_1 + a_{m2}x_2 +... + a_{mn}x_n = b_m$
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Solution: A list $s_1, s_2,..., s_n$ that satisfy each equation when $x_i = s_i$.
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Ensemble solution: The set of all possible solutions.
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Systèmes équivalents: Two systems with the same solution set.
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Possible solutions for systems of linear equation
- Exactly one solution (compatible system)
- Infinitely many solutions (compatible system)
- No solution (incompatible system)
1.2 Méthodes de Résolution
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Matrice: A rectangular array of numbers.
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Matrice augmentée: Matrix containing the coefficients and constants of a system.
-$\begin{bmatrix}
a_{11} & a_{12} &... & a_{1n} & b_1 \ a_{21} & a_{22} &... & a_{2n} & b_2 \... &... &... &... &... \ a_{m1} & a_{m2} &... & a_{mn} & b_m \end{bmatrix}$
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Opérations élémentaires sur les lignes:
- Multiply a row by a nonzero constant.
- Add a multiple of one row to another.
- Swap two rows.
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Théorème:* Equivalent matrices = equivalent system.
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Élimination de Gauss: Method to transform matrix into an echelon form.
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Élimination de Gauss-Jordan: Method to transform matrix into a reduced echelon form.
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