Spectral Shifts: Lecture 2
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Questions and Answers

What does one absorbance unit correspond to in terms of transmittance?

  • 15% transmittance
  • 10% transmittance (correct)
  • 20% transmittance
  • 5% transmittance
  • According to Bouguer-Lambert's law, how does the intensity of light decrease in an absorbing medium?

  • Exponentially (correct)
  • Linearly
  • Quadratically
  • Logarithmically
  • What is the proportionality constant in the expression log Io / It = Kb?

  • Thickness (correct)
  • Concentration
  • Intensity
  • Absorbance
  • What does the term 'A' represent in Beer-Lambert's law A = abc?

    <p>Absorptivity</p> Signup and view all the answers

    If the unit of concentration is 1M, what is the absorptivity known as?

    <p>Molar absorptivity</p> Signup and view all the answers

    How can absorptivity be calculated from a plotted curve of A against C at fixed b?

    <p>From the slope</p> Signup and view all the answers

    What is the unit of molar absorptivity (ɛ) in Beer-Lambert's law?

    <p>$L mol^{-1} cm^{-1}$</p> Signup and view all the answers

    'A(1%, 1cm)' is a term related to what characteristic of a substance?

    <p>% Absorbance at 1cm thickness</p> Signup and view all the answers

    'log Io/It α C' is associated with which law?

    <p>$Beer's$ Law</p> Signup and view all the answers

    The spectrum of a substance in alkaline medium exhibits a hypsochromic shift and hyperchromic effect.

    <p>False</p> Signup and view all the answers

    At the isosbestic point, the absorbance of a substance is pH dependent.

    <p>False</p> Signup and view all the answers

    The oxidation of diphenylamine converts its quinonoid spectrum to the benzenoid spectrum.

    <p>False</p> Signup and view all the answers

    The change in spectrum of a substance upon dilution is an example of the effect of temperature.

    <p>False</p> Signup and view all the answers

    The same substance will have different spectra in polar and non-polar solvents.

    <p>True</p> Signup and view all the answers

    The isosbestic point represents the intersection of spectra at different pH values.

    <p>True</p> Signup and view all the answers

    Absorbance is not affected by changes in concentration at the isosbestic point.

    <p>True</p> Signup and view all the answers

    Effect of redox reaction can convert a quinonoid spectrum to a benzenoid spectrum.

    <p>True</p> Signup and view all the answers

    Dilution of a substance with water changes its benzenoid spectrum to a quinonoid spectrum.

    <p>True</p> Signup and view all the answers

    The effect of solvent on a substance's spectrum can be observed by comparing spectra in different solvent types.

    <p>True</p> Signup and view all the answers

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