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Questions and Answers
Which factor does NOT significantly influence the solubility of solid substances in a liquid?
Which factor does NOT significantly influence the solubility of solid substances in a liquid?
- Inter-particle forces
- Pressure (correct)
- Temperature
- The type of solvent
How does the solubility of most solid substances change as temperature increases?
How does the solubility of most solid substances change as temperature increases?
- Solubility decreases
- Solubility is unpredictable
- Solubility generally increases (correct)
- Solubility remains constant
At approximately what temperature is the solubility of sodium sulfate ($Na_2SO_4$) at its maximum value according to the text?
At approximately what temperature is the solubility of sodium sulfate ($Na_2SO_4$) at its maximum value according to the text?
- 32.4°C (correct)
- 0°C
- 100°C
- 25°C
What happens to the solubility of gases in liquids as the temperature increases?
What happens to the solubility of gases in liquids as the temperature increases?
In the experiment for determining the solubility of NaCl, what is the purpose of adding sodium chloride to water until undissolved salt remains?
In the experiment for determining the solubility of NaCl, what is the purpose of adding sodium chloride to water until undissolved salt remains?
During the NaCl solubility experiment, what is assumed when transferring 50 mL of the saturated solution to the evaporating dish?
During the NaCl solubility experiment, what is assumed when transferring 50 mL of the saturated solution to the evaporating dish?
In experiment 2.3, after evaporation, the mass of the dry sodium chloride is determined. What does the mass represent?
In experiment 2.3, after evaporation, the mass of the dry sodium chloride is determined. What does the mass represent?
Which statement is correct regarding the solubility of NaCl?
Which statement is correct regarding the solubility of NaCl?
What is the molality of a solution formed by dissolving 32.0 g of $CaCl_2$ in 271 g of water?
What is the molality of a solution formed by dissolving 32.0 g of $CaCl_2$ in 271 g of water?
How many gram equivalents are present in 49 g of $H_2SO_4$?
How many gram equivalents are present in 49 g of $H_2SO_4$?
What is the number of equivalents in 0.25 mol of $H_3PO_4$ when it is completely neutralized to $PO_4^{3-}$?
What is the number of equivalents in 0.25 mol of $H_3PO_4$ when it is completely neutralized to $PO_4^{3-}$?
What is the normality of a solution containing 0.75 equivalents of solute in 250 mL of solution?
What is the normality of a solution containing 0.75 equivalents of solute in 250 mL of solution?
What mass of $Na_2CO_3$ is required to prepare 200 mL of a 0.2 N solution?
What mass of $Na_2CO_3$ is required to prepare 200 mL of a 0.2 N solution?
A 0.8 M solution of $H_3PO_4$ is prepared. Assuming complete dissociation, what is the normality of this solution?
A 0.8 M solution of $H_3PO_4$ is prepared. Assuming complete dissociation, what is the normality of this solution?
If 1 L of a solution contains 4 equivalents of solute, what is its normality?
If 1 L of a solution contains 4 equivalents of solute, what is its normality?
What is the 'z' value for $Al_2(SO_4)_3$ in a precipitation reaction?
What is the 'z' value for $Al_2(SO_4)_3$ in a precipitation reaction?
If 0.2 moles of $H_3PO_4$ is converted to $H_2PO_4^-$, how many equivalents are present?
If 0.2 moles of $H_3PO_4$ is converted to $H_2PO_4^-$, how many equivalents are present?
A solution has a normality of 0.48 N and contains $Al_2(SO_4)_3$. If the volume is 250 mL, what is the mass of $Al_2(SO_4)_3$?
A solution has a normality of 0.48 N and contains $Al_2(SO_4)_3$. If the volume is 250 mL, what is the mass of $Al_2(SO_4)_3$?
Why are gas molecules in the gaseous state far apart?
Why are gas molecules in the gaseous state far apart?
What effect does increasing external heat have on the solubility of a gas in a liquid?
What effect does increasing external heat have on the solubility of a gas in a liquid?
According to Henry’s Law, if the partial pressure of a gas above a solution increases, what happens to the solubility of the gas?
According to Henry’s Law, if the partial pressure of a gas above a solution increases, what happens to the solubility of the gas?
What is the unit of the Henry's law constant (k) when concentration is measured in molarity (M) and pressure in atmospheres (atm)?
What is the unit of the Henry's law constant (k) when concentration is measured in molarity (M) and pressure in atmospheres (atm)?
Which of the following best describes the relationship in the equation $C_1/P_1 = C_2/P_2$?
Which of the following best describes the relationship in the equation $C_1/P_1 = C_2/P_2$?
Which gases do not generally follow Henry's law?
Which gases do not generally follow Henry's law?
A carbonated beverage is bottled under pressure. What happens when the bottle's cap is removed?
A carbonated beverage is bottled under pressure. What happens when the bottle's cap is removed?
If the solubility of nitrogen gas is $6.8 \times 10^{-4}$ mol/L at 1 atm, what would be its concentration at a partial pressure of 0.78 atm at the same temperature?
If the solubility of nitrogen gas is $6.8 \times 10^{-4}$ mol/L at 1 atm, what would be its concentration at a partial pressure of 0.78 atm at the same temperature?
A solution of carbon dioxide ($CO_2$) has a concentration of 0.032 M at 3.0 atm. If the pressure is increased to 5.0 atm at the same temperature, what is the new concentration of $CO_2$?
A solution of carbon dioxide ($CO_2$) has a concentration of 0.032 M at 3.0 atm. If the pressure is increased to 5.0 atm at the same temperature, what is the new concentration of $CO_2$?
According to Henry's Law, what happens to the concentration of a dissolved gas if the pressure above it is doubled?
According to Henry's Law, what happens to the concentration of a dissolved gas if the pressure above it is doubled?
Why does the solubility of solids or liquids in liquid solvents not change significantly with pressure?
Why does the solubility of solids or liquids in liquid solvents not change significantly with pressure?
What does the term 'molarity' represent?
What does the term 'molarity' represent?
What must be determined experimentally for each combination of gas, solvent, and temperature when applying Henry’s law?
What must be determined experimentally for each combination of gas, solvent, and temperature when applying Henry’s law?
If the temperature of a gas-liquid solution increases, what initially happens to the solubility of the gas?
If the temperature of a gas-liquid solution increases, what initially happens to the solubility of the gas?
Which of the following actions will not increase the solubility of a gas in a liquid?
Which of the following actions will not increase the solubility of a gas in a liquid?
What is the mass percentage of a solution prepared by dissolving 25 g of salt in 225 g of water?
What is the mass percentage of a solution prepared by dissolving 25 g of salt in 225 g of water?
A solution is made by mixing 40 mL of ethanol with 160 mL of water. What is the volume percent of ethanol in the solution?
A solution is made by mixing 40 mL of ethanol with 160 mL of water. What is the volume percent of ethanol in the solution?
If a solution contains 5 mg of a pollutant in 2 kg of water, what is the concentration of the pollutant in ppm?
If a solution contains 5 mg of a pollutant in 2 kg of water, what is the concentration of the pollutant in ppm?
A solution has a concentration of 8 ppm. If the solution is aqueous, what does this concentration mean in mg/L?
A solution has a concentration of 8 ppm. If the solution is aqueous, what does this concentration mean in mg/L?
What does a 75% (v/v) solution of glycerol in water mean?
What does a 75% (v/v) solution of glycerol in water mean?
A solution of sodium chloride (NaCl) in water is prepared. The mole fraction of NaCl is 0.30. What is the mole fraction of water?
A solution of sodium chloride (NaCl) in water is prepared. The mole fraction of NaCl is 0.30. What is the mole fraction of water?
What is the mass per cent of a solution if 15.0 g of a solute is dissolved in 135 g of water?
What is the mass per cent of a solution if 15.0 g of a solute is dissolved in 135 g of water?
A 100 mL solution contains 5 g of solute. What is the concentration in % (w/v)?
A 100 mL solution contains 5 g of solute. What is the concentration in % (w/v)?
If a water sample contains 3.0 ppb of a contaminant, what does this mean in terms of mass ratio?
If a water sample contains 3.0 ppb of a contaminant, what does this mean in terms of mass ratio?
What is the volume percent of a solution if 30 mL of a solute is diluted with 120 mL of solvent?
What is the volume percent of a solution if 30 mL of a solute is diluted with 120 mL of solvent?
How would you make a 25% (w/w) solution using 50 grams of a solute?
How would you make a 25% (w/w) solution using 50 grams of a solute?
If a solution contains 50 ppm of a metal ion, and the solution's volume is 2 liters, approximately how many mg of the metal ion are present?
If a solution contains 50 ppm of a metal ion, and the solution's volume is 2 liters, approximately how many mg of the metal ion are present?
A solution is made by dissolving 12g of solid in water to make 300 mL of final volume. What is the % (w/v) of the solution?
A solution is made by dissolving 12g of solid in water to make 300 mL of final volume. What is the % (w/v) of the solution?
Which scenario requires the use of parts per million (ppm) or parts per billion (ppb)?
Which scenario requires the use of parts per million (ppm) or parts per billion (ppb)?
If a solution contains 0.05 moles of solute and 0.45 moles of solvent, what is the mole fraction of the solute?
If a solution contains 0.05 moles of solute and 0.45 moles of solvent, what is the mole fraction of the solute?
A solution contains 0.25 moles of solute and 2.5 moles of solvent. What is the mole fraction of the solute?
A solution contains 0.25 moles of solute and 2.5 moles of solvent. What is the mole fraction of the solute?
What is the mole percent of a solution containing 1 mole of solute and 3 moles of solvent?
What is the mole percent of a solution containing 1 mole of solute and 3 moles of solvent?
If 8 grams of a solute with a molar mass of 40 g/mol is dissolved in enough solvent to make 200 mL of solution, what is the molarity of the solution?
If 8 grams of a solute with a molar mass of 40 g/mol is dissolved in enough solvent to make 200 mL of solution, what is the molarity of the solution?
Which of the following is NOT a drawback of using molarity as a measure of concentration in precise work?
Which of the following is NOT a drawback of using molarity as a measure of concentration in precise work?
How many moles of NaCl are needed to prepare 500 mL of a 0.25 M solution?
How many moles of NaCl are needed to prepare 500 mL of a 0.25 M solution?
Which concentration unit is defined as the number of moles of solute per kilogram of solvent?
Which concentration unit is defined as the number of moles of solute per kilogram of solvent?
What is the molality of a solution prepared by dissolving 18 g of glucose (C6H12O6) in 200 g of water? (Molar mass of glucose = 180 g/mol)
What is the molality of a solution prepared by dissolving 18 g of glucose (C6H12O6) in 200 g of water? (Molar mass of glucose = 180 g/mol)
Which of the following remains constant with changes in temperature?
Which of the following remains constant with changes in temperature?
What information is required to calculate the normality of a solution?
What information is required to calculate the normality of a solution?
If a solution has a normality of 2 N, how many gram equivalents of solute are present in 500 mL of the solution?
If a solution has a normality of 2 N, how many gram equivalents of solute are present in 500 mL of the solution?
What does 'z' represent in the formula: equivalent weight = molar mass / z
What does 'z' represent in the formula: equivalent weight = molar mass / z
To prepare 1 liter of a 0.5 M solution of a substance with a molar mass of 100 g/mol, how many grams of the substance are required?
To prepare 1 liter of a 0.5 M solution of a substance with a molar mass of 100 g/mol, how many grams of the substance are required?
A 300 g solution contains 30 g of solute, what is the mass percent of the solute?
A 300 g solution contains 30 g of solute, what is the mass percent of the solute?
Which of the following concentration units is most affected by changes in temperature?
Which of the following concentration units is most affected by changes in temperature?
If 20g of a substance with a molar mass of 50g/mol is dissolved in 500g of solvent, what is the molality of the solution? (in mol/kg)
If 20g of a substance with a molar mass of 50g/mol is dissolved in 500g of solvent, what is the molality of the solution? (in mol/kg)
Flashcards
Solubility
Solubility
The amount of a substance that can dissolve in a given amount of solvent at a specific temperature.
Temperature Effect on Solid Solubility
Temperature Effect on Solid Solubility
The solubility of most solid substances increases as the temperature increases.
Saturated Solution
Saturated Solution
The process of dissolving a solid substance in a solvent until no more can dissolve, resulting in a saturated solution.
Temperature Effect on Gas Solubility
Temperature Effect on Gas Solubility
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Concentration
Concentration
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Evaporation
Evaporation
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Supernatant Solution
Supernatant Solution
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Solubility Determination
Solubility Determination
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Gas-Solvent Interactions
Gas-Solvent Interactions
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Why gases dissolve in liquids?
Why gases dissolve in liquids?
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Effect of temperature on gas solubility
Effect of temperature on gas solubility
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Effect of pressure on gas solubility
Effect of pressure on gas solubility
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Henry's Law
Henry's Law
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Henry's Law Constant (k)
Henry's Law Constant (k)
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Molarity (M)
Molarity (M)
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Partial Pressure (P)
Partial Pressure (P)
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Concentration of dissolved gas (C)
Concentration of dissolved gas (C)
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Inverse Relationship between Gas Solubility and Temperature
Inverse Relationship between Gas Solubility and Temperature
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Direct Relationship between Gas Solubility and Pressure
Direct Relationship between Gas Solubility and Pressure
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Mass Percentage
Mass Percentage
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Parts Per Million (ppm)
Parts Per Million (ppm)
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Percent by Mass (% w/w)
Percent by Mass (% w/w)
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Mass Percentage of Solute
Mass Percentage of Solute
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Volume Percent (% v/v)
Volume Percent (% v/v)
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Percent by Weight/Volume (% w/v)
Percent by Weight/Volume (% w/v)
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Mole Fraction (XA)
Mole Fraction (XA)
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Mole Fraction of a Component
Mole Fraction of a Component
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Total Mole Fraction
Total Mole Fraction
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Solute
Solute
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Solvent
Solvent
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Solution
Solution
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Mole fraction
Mole fraction
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Mole percent
Mole percent
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Normality (N)
Normality (N)
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Equivalent weight
Equivalent weight
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Z (Equivalence Factor)
Z (Equivalence Factor)
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Number of Gram Equivalents
Number of Gram Equivalents
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Gram Equivalent (eq)
Gram Equivalent (eq)
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Reaction-Dependent Concentration
Reaction-Dependent Concentration
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Relation Between Normality and Molarity
Relation Between Normality and Molarity
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Normality Formula
Normality Formula
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Equivalents per Liter (Eq/L)
Equivalents per Liter (Eq/L)
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Multi-Step Dissociation in Normality
Multi-Step Dissociation in Normality
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Study Notes
Factors Affecting Solubility
- Solubility of a substance in a solvent is influenced by inter-particle forces, temperature, and pressure (for gases only).
- Solid solutes generally increase in solubility with temperature. Sodium sulfate solubility increases significantly between 0°C and 32.4°C.
- For example, NaCl solubility is 36 g/100 mL of water at 25°C and 39 g/100 mL at 100°C.
- Gases decrease in solubility with increasing temperature. Heat breaks attractive forces between gas and solvent molecules.
Experiment: Determining Solubility of NaCl
- Objective: Determine the solubility of NaCl.
- Apparatus: Beaker, evaporating dish, measuring cylinder, glass rod, filter paper, analytical balance, Bunsen burner.
- Chemicals: Sodium chloride and water.
- Procedure:
- Weigh an empty evaporating dish.
- Add 100 mL water to a beaker and 20g of NaCl.
- Stir vigorously until no more NaCl dissolves, leaving undissolved solute at the bottom.
- Take 50 mL of the saturated solution.
- Evaporate the solution in an evaporating dish until dry.
- Cool the evaporating dish and re-weigh.
- Calculate solubility in grams of NaCl/100 g of water. Repeat with sugar.
Effect of Pressure on Gas Solubility (Henry's Law)
-
Pressure greatly affects the solubility of gases. Solids and liquids are not significantly affected by pressure.
-
Solubility of gases increases as the partial pressure of the gas above the solution increases.
-
Henry's Law:
C ∝ P
orC = kP
Where:C
is the concentration of dissolved gas at equilibrium.P
is the partial pressure of the gas.k
is the Henry's law constant (dependent on the specific gas, solvent, and temperature).
-
The constant, k, is experimentally determined and used to calculate solubility.
-
If partial pressure changes while temperature stays constant, then solubility changes proportionately:
C1/P1 = C2/P2
-
Gases with stronger intermolecular forces (like hydrogen bonding) or that react with water do not follow Henry's Law.
Examples of Henry's Law
-
Example 1: CO2 in cola
- Partial pressure of CO2 inside bottle = 4 atm.
- Henry's law constant for CO2 in water = 3.3 x 10⁻² mol/L.atm.
- Calculate CO2 solubility = 0.132 mol/L
-
Example 2: N2 solubility in water
- N2 partial pressure in the atmosphere = 0.78 atm.
- Solubility of nitrogen gas at 25°C and 1 atm = 6.8x10⁻⁴ mol/L.
- Calculate concentration of nitrogen in water under atmospheric conditions = 5.3 × 10⁻⁴ mol/L
Ways of Expressing Solution Concentration
- Percent by Mass (%w/w): (
mass of solute / mass of solution
) x 100% - Percent by Volume (%v/v): (
volume of solute / volume of solution
) x 100% - Percent by Mass/Volume (%w/v): (
mass of solute / volume of solution
) x 100% - Parts per Million (ppm): (
mass of solute / mass of solution
) x 10⁶ - Parts per Billion (ppb): (
mass of solute / mass of solution
) x 10⁹
Other Concentration Units
- Mole Fraction: Moles of a substance divided by total moles of solution. A mole fraction is the proportion of solute or solvent particles in the solution.
- Molarity (M): Moles of solute per liter of solution (
moles of solute/ lit of solution
) - Molality (m): Moles of solute per kilogram of solvent (
moles of solute/ kilogram of solvent
) - Normality (N): Gram equivalent weight of solute per liter of solution.
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