Solubility and Distribution Phenomena Quiz
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Questions and Answers

What is the quantitative definition of solubility?

  • The dissolved solute in a concentration below that necessary for complete saturation at a definite temperature
  • The concentration of solute in a saturated solution at a certain temperature (correct)
  • The solute in solution being in equilibrium with the solid phase
  • The spontaneous interaction of two or more substances to form a homogeneous molecular dispersion
  • What type of solution is one containing the dissolved solute in a concentration below that necessary for complete saturation at a definite temperature?

  • Subsaturated solution
  • Unsaturated solution (correct)
  • Supersaturated solution
  • Saturated solution
  • What happens if a mixture, initially containing 100 grams of dissolved glucose at 25 °C, is slowly cooled back to 25 °C?

  • Glucose precipitates after a long time (correct)
  • Glucose remains dissolved indefinitely
  • Glucose never precipitates
  • Glucose precipitates immediately
  • What effect does the addition of electrolytes and non-electrolytes have on gaseous solutions?

    <p>It increases the liberation of gases from the solutions due to reduced aqueous environment adjacent to the gas molecules.</p> Signup and view all the answers

    In which type of solution do the components obey Raoult's law and have adhesive forces equal to cohesive forces?

    <p>Ideal solution</p> Signup and view all the answers

    What is the characteristic of a negative deviated solution?

    <p>Adhesive forces are much greater than cohesive forces</p> Signup and view all the answers

    Under what conditions do liquid-liquid systems show complete miscibility?

    <p>When the liquids dissolve completely into each other</p> Signup and view all the answers

    Why is water able to dissolve NaCl but chloroform and benzene cannot?

    <p>Water has a high dielectric constant, reducing the force of attraction between oppositely charged ions.</p> Signup and view all the answers

    Why are non polar solvents like benzene unable to dissolve ionic compounds?

    <p>Non polar solvents have low dielectric constants, which cannot disrupt the ionic bonds.</p> Signup and view all the answers

    Why is water capable of dissolving phenols, alcohols, and other oxygen & nitrogen containing compounds?

    <p>Water can form hydrogen bonds with these compounds due to their ability to act as a polar solvent.</p> Signup and view all the answers

    Study Notes

    Solubility

    • Quantitative definition of solubility: Not explicitly stated, but implied to be the maximum amount of solute that can dissolve in a solvent at a given temperature.

    Types of Solutions

    • Solution containing dissolved solute in a concentration below that necessary for complete saturation at a definite temperature: Undersaturated solution.

    Solution Behavior

    • If a mixture, initially containing 100 grams of dissolved glucose at 25 °C, is slowly cooled back to 25 °C: Precipitation of glucose occurs, as the solubility of glucose decreases with decreasing temperature.

    Effects of Electrolytes and Non-Electrolytes

    • Addition of electrolytes and non-electrolytes to gaseous solutions: Increases the solubility of gases, particularly in aqueous solutions.

    Ideal Solutions

    • Components obey Raoult's law and have adhesive forces equal to cohesive forces: Ideal solutions, where the interactions between solute and solvent molecules are identical to those between solvent molecules.

    Negative Deviation

    • Characteristic of a negative deviated solution: Lower vapor pressure than expected, indicating stronger intermolecular forces between solute and solvent molecules.

    Liquid-Liquid Miscibility

    • Conditions for complete miscibility in liquid-liquid systems: Similar intermolecular forces between the two liquids.

    Solvent Properties

    • Water's ability to dissolve NaCl, but not chloroform and benzene: Polarity and high dielectric constant of water, allowing it to dissociate and solvate ionic compounds.
    • Non-polar solvents like benzene unable to dissolve ionic compounds: Lack of polarity and low dielectric constant, making them unable to dissociate and solvate ionic compounds.
    • Water's ability to dissolve phenols, alcohols, and other oxygen & nitrogen containing compounds: Hydrogen bonding between water molecules and the functional groups of these compounds.

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    Description

    Test your knowledge of solubility and distribution phenomena in physical pharmacy with this quiz. Explore concepts such as saturated solutions, spontaneous interactions, and molecular dispersion.

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