Solid State Physics
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Questions and Answers

Which type of crystalline solid is characterized by a 'sea of electrons' surrounding a lattice of positive ions?

  • Metallic solid (correct)
  • Molecular solid
  • Covalent network solid
  • Ionic solid

Which of the following statements accurately describes the key difference between crystalline and amorphous solids?

  • Amorphous solids exhibit long-range order in their atomic arrangement, whereas crystalline solids do not.
  • Crystalline solids lack a defined melting point, while amorphous solids melt sharply at a specific temperature.
  • Crystalline solids are anisotropic, while amorphous solids are isotropic. (correct)
  • Amorphous solids are incompressible and rigid, while crystalline solids are compressible and flexible.

Which of the following defects involves an atom occupying a space outside of a regular lattice site?

  • Frenkel defect (correct)
  • Substitution impurity
  • Schottky defect
  • Vacancy defect

Doping a semiconductor with a group 13 element creates what type of semiconductor, and what are the charge carriers?

<p>p-type, holes (A)</p> Signup and view all the answers

Which of the following best describes the packing efficiency of a body-centered cubic (BCC) unit cell?

<p>68% (A)</p> Signup and view all the answers

According to Raoult's Law, what is the relationship between the vapor pressure of a solution and the mole fraction of the solvent?

<p>The vapor pressure of a solution is directly proportional to the mole fraction of the solvent. (B)</p> Signup and view all the answers

A solution exhibits a positive deviation from Raoult's law. What does this indicate about the vapor pressure of the solution compared to what is predicted, and what does this imply about the intermolecular forces?

<p>Higher than predicted; weaker solute-solvent interactions than solute-solute or solvent-solvent interactions. (D)</p> Signup and view all the answers

What characteristic defines an azeotrope?

<p>It is a liquid mixture that has the same composition in the liquid and vapor phases and boils at a constant temperature. (A)</p> Signup and view all the answers

In electrochemistry, what is the primary difference between a galvanic cell and an electrolytic cell?

<p>A galvanic cell converts chemical energy to electrical energy through spontaneous reactions, while an electrolytic cell uses electrical energy to drive non-spontaneous reactions. (B)</p> Signup and view all the answers

What information does the Nernst equation provide regarding electrochemical cells?

<p>It relates the cell potential to the standard cell potential and the reaction quotient under non-standard conditions. (A)</p> Signup and view all the answers

Which statement accurately differentiates between average and instantaneous reaction rates?

<p>Average rate is calculated over a defined time interval, whereas instantaneous rate is the rate at a particular point in time. (A)</p> Signup and view all the answers

Consider a reaction with the rate law: Rate = $k[A]^2[B]$. What is the overall order of this reaction?

<p>Third order (D)</p> Signup and view all the answers

How does a catalyst increase the rate of a chemical reaction?

<p>By providing an alternative reaction pathway with lower activation energy (B)</p> Signup and view all the answers

In the context of surface chemistry, what distinguishes physisorption from chemisorption?

<p>Physisorption involves weak van der Waals forces, while chemisorption involves chemical bond formation. (C)</p> Signup and view all the answers

Which of the following factors does NOT significantly affect the extent of adsorption of a gas on a solid?

<p>Volume of the adsorbent (C)</p> Signup and view all the answers

What is the fundamental difference between a sol and a gel?

<p>A sol is a solid dispersed in a liquid, while a gel is a liquid dispersed in a solid. (B)</p> Signup and view all the answers

Which method is most appropriate for concentrating sulfide ores?

<p>Froth floatation (D)</p> Signup and view all the answers

In the extraction of metals, what is the primary purpose of 'refining'?

<p>To remove impurities from the metal (A)</p> Signup and view all the answers

Why does nitrogen exist as a diatomic molecule, $N_2$, under normal conditions, while phosphorus exists as $P_4$?

<p>Nitrogen's smaller size allows for effective pπ-pπ multiple bonding, unlike phosphorus. (B)</p> Signup and view all the answers

What is the role of $V_2O_5$ in the Contact process for the manufacture of sulfuric acid?

<p>Catalyst (D)</p> Signup and view all the answers

Which property is NOT typically associated with transition elements?

<p>Formation of colorless compounds (A)</p> Signup and view all the answers

What is the primary cause of lanthanoid contraction?

<p>Poor shielding of nuclear charge by f-electrons (D)</p> Signup and view all the answers

According to Crystal Field Theory (CFT), how does the presence of ligands affect the d-orbitals of the central metal ion in a coordination complex?

<p>The d-orbitals split into different energy levels (C)</p> Signup and view all the answers

Which of the following best describes the SN1 reaction mechanism in haloalkanes?

<p>A two-step reaction involving a carbocation intermediate. (B)</p> Signup and view all the answers

What is the primary reason that phenols are more acidic than alcohols?

<p>The phenoxide ion is stabilized by resonance. (A)</p> Signup and view all the answers

Flashcards

Amorphous Solid

A solid lacking long-range order in its atomic structure. Properties are uniform in all directions.

Unit Cell

The smallest repeating unit of a crystal lattice that shows the pattern of the entire solid.

Coordination Number

The number of nearest neighboring atoms surrounding a particular atom in a crystal structure.

Vacancy Defect

A lattice site that is normally occupied but is missing an atom, creating a void in the structure.

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Interstitial Defect

An atom occupying a space between the regular lattice sites within the crystal structure.

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Solution

A homogeneous mixture of two or more substances, consisting of a solute and a solvent.

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Solute

The component present in a solution in a smaller amount, dissolved in the solvent.

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Solubility

The maximum amount of solute that can dissolve in a given amount of solvent at a specific temperature.

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Galvanic Cells

Electrochemical cells converting chemical energy into electrical energy through spontaneous reactions.

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Standard Electrode Potential

The electrode potential measured under standard conditions: 298 K and 1 M concentration.

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Batteries

Galvanic cells used to generate electrical energy.

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Corrosion

The degradation of a metal due to environmental reactions.

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Chemical Kinetics

Study of reaction rates and factors affecting them.

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Rate of Reaction

The change in concentration of reactant/product per unit time.

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Rate Law

Expresses the relationship between reaction rate and reactant concentrations.

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Half-life (t₁/₂)

Time for reactant concentration to halve.

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Activation Energy (Eₐ)

Minimum energy for a reaction to occur.

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Catalyst

Substance speeding up a reaction without being consumed.

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Adsorption

Accumulation of molecules at a surface.

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Physisorption

Weak van der Waals forces involved.

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Chemisorption

Involves chemical bond formation

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Minerals

Naturally occurring substances containing metals.

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Ores

Minerals from which metals can be economically extracted.

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d-Block Elements

Elements with variable oxidation states, forming colored compounds and complexes.

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Coordination Compounds

Contain a central metal ion surrounded by ligands.

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Study Notes

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Description

Learn properties and classifications of solids: crystalline vs. amorphous, molecular, ionic, metallic, and covalent networks. Explore unit cells, including simple cubic, FCC, and BCC structures. Understand the arrangement and forces within different solid types.

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