Solid State Chemistry MCQs

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Questions and Answers

What type of structure do molecular solids have?

  • Crystalline structure (correct)
  • Polymeric structure
  • Ionic structure
  • Amorphous structure

In a body-centered cubic (BCC) crystal lattice, what is the coordination number?

  • 6
  • 4
  • 8 (correct)
  • 12

Which defect preserves overall electrical neutrality in the crystal lattice?

  • Frenkel defect (correct)
  • Stacking fault
  • Interstitial defect
  • Schottky defect

A compound forms hcp structure. Number of octahedral and tetrahedral voids in O.5 mole of substance is respectively

<p>3.011×1023, 6.022×1023 (A)</p> Signup and view all the answers

Pb has FCC structure with the edge length of unit cell 495 pm. Radius of Pb atom is

<p>175 pm (D)</p> Signup and view all the answers

An Ionic compound crystallizes in FCC type structure with 'A' ions at the centre of each face and 'B' ions occupying corners of the cube. The formula of the compound is

<p>A3B (B)</p> Signup and view all the answers

What is the relationship between the edge length (a) and atomic radius (r) in a simple cubic lattice?

<p>a=2r (C)</p> Signup and view all the answers

How many particles are present in a face-centered cubic (FCC) unit cell?

<p>4 (C)</p> Signup and view all the answers

The relation between radius of sphere and edge length in body centered cubic lattice is given by formula

<p>r=√3/4 x a (C)</p> Signup and view all the answers

Schottky defect is observed in which solid among

<p>Cesium chloride (B)</p> Signup and view all the answers

Flashcards

Molecular Solids

A crystalline solid where constituent particles are held together by weak intermolecular forces such as van der Waals forces or hydrogen bonds.

n-type semiconductor

A semiconductor material where the majority charge carriers are electrons, created by doping with an element having more valence electrons than the host.

Frenkel Defect

A point defect in a crystal lattice where an ion is displaced from its normal lattice site to an interstitial site, creating a vacancy.

Coordination Number

The number of nearest neighbor atoms surrounding a central atom in a crystal lattice.

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Hexagonal Close-Packed (HCP) Structure

A crystal structure where atoms are arranged in hexagonal layers, with each layer having two types of voids: octahedral and tetrahedral. In a hexagonal close-packed (HCP) structure, there are two tetrahedral voids for each atom and one octahedral void for every two atoms.

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Crystal Lattice

A crystal structure where atoms (or ions) are arranged in a regular, repeating pattern, forming a cubic lattice.

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Simple Cubic Lattice

A type of crystal structure where the atoms are arranged in a cubic lattice with one atom at each corner of the cube. The relationship between edge length 'a' and atomic radius 'r' is a = 2r.

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Body-Centered Cubic (BCC) Lattice

A crystal structure where the atoms (or ions) are arranged in a cubic lattice with one atom at each corner and one atom in the center of the cube.

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Face-Centered Cubic (FCC) Lattice

A type of crystal structure where the atoms are arranged in a cubic lattice with one atom at each corner and an atom at the center of each face of the cube. In an ionic compound, the cations (positive ions) usually occupy the corners while the anions (negative ions) occupy the faces.

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Schottky Defect

A point defect in a crystal lattice where an atom is missing from its usual lattice position, creating a vacant site.

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Study Notes

MCQ'S

  • Molecular solids are crystalline solids
  • n-type semiconductor: Si doped with As
  • Frenkel defect: preserves overall electrical neutrality
  • Coordination number of atoms in bcc crystal lattice is 8
  • A compound forms hep structures. Number of octahedral and tetrahedral voids in 0.5 mole of substance is 3.011 x 1023 (octahedral) and 6.022 x 1023 (tetrahedral)
  • Pb has FCC structure, edge length of unit cell is 495 pm, radius of Pb atom is 175 pm

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