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Questions and Answers
What will be discussed in lecture eight of the solid state chemistry course?
What will be discussed in lecture eight of the solid state chemistry course?
Insulators have high conductance.
Insulators have high conductance.
False
What is the most common type of X-ray source mentioned in the lecture?
What is the most common type of X-ray source mentioned in the lecture?
X-ray anode
Electrons are accelerated towards the anode where they will hit a __________ material.
Electrons are accelerated towards the anode where they will hit a __________ material.
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Match the following materials with their electrical behavior:
Match the following materials with their electrical behavior:
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What theory will be introduced to understand the properties of solids?
What theory will be introduced to understand the properties of solids?
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The workshop sheet will be available one week before the workshop.
The workshop sheet will be available one week before the workshop.
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What does the linear combination of atomic orbitals help to extend into?
What does the linear combination of atomic orbitals help to extend into?
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Which type of compounds typically have very high melting temperatures?
Which type of compounds typically have very high melting temperatures?
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The first nano scale industry was pigmenting stained glass windows using gold nanoparticles.
The first nano scale industry was pigmenting stained glass windows using gold nanoparticles.
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What is the significance of optical properties in materials?
What is the significance of optical properties in materials?
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In addition to being transparent, materials for photovoltaics must also be _____ to make efficient solar cells.
In addition to being transparent, materials for photovoltaics must also be _____ to make efficient solar cells.
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Match the following types of materials with their properties:
Match the following types of materials with their properties:
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What type of light can synchrotron sources emit?
What type of light can synchrotron sources emit?
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What challenges are associated with creating materials that are both transparent and conducting?
What challenges are associated with creating materials that are both transparent and conducting?
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Synchrotron light sources operate by emitting light from atomic species only.
Synchrotron light sources operate by emitting light from atomic species only.
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Pigmentation has been a non-essential aspect of industries throughout history.
Pigmentation has been a non-essential aspect of industries throughout history.
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What is the typical speed range of electrons used in synchrotron light sources?
What is the typical speed range of electrons used in synchrotron light sources?
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Why is transparency important for mobile phone screens?
Why is transparency important for mobile phone screens?
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Synchrotron sources allow researchers to select the specific energy they want for their experiments by using ______.
Synchrotron sources allow researchers to select the specific energy they want for their experiments by using ______.
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Match the following materials with their characteristics:
Match the following materials with their characteristics:
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Which property is characteristic of covalent materials?
Which property is characteristic of covalent materials?
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What happens to the conductivity of semiconductors as temperature increases?
What happens to the conductivity of semiconductors as temperature increases?
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The use of diffraction materials is optional in synchrotron light sources for selecting energies.
The use of diffraction materials is optional in synchrotron light sources for selecting energies.
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Conductors have higher conductivity than insulators even at low temperatures.
Conductors have higher conductivity than insulators even at low temperatures.
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Describe the effect of the speed of electrons in synchrotron light sources on the light produced.
Describe the effect of the speed of electrons in synchrotron light sources on the light produced.
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What is the conductivity measure that indicates an insulator?
What is the conductivity measure that indicates an insulator?
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An insulator can be turned into a ________ by increasing the temperature.
An insulator can be turned into a ________ by increasing the temperature.
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Match the following terms with their definitions:
Match the following terms with their definitions:
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Which of the following statements is true about insulators?
Which of the following statements is true about insulators?
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Applying a bias to a semiconductor results in no electron movement.
Applying a bias to a semiconductor results in no electron movement.
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What is the term used for the electronic bands in solid materials?
What is the term used for the electronic bands in solid materials?
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What is the term for the maximum energy that an electron can have at zero Kelvin in a solid?
What is the term for the maximum energy that an electron can have at zero Kelvin in a solid?
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When bands are half-filled, they exhibit a higher density of states due to the spread over a larger energy range.
When bands are half-filled, they exhibit a higher density of states due to the spread over a larger energy range.
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What happens to the energy states and electron filling when new bands form from completely empty s orbitals?
What happens to the energy states and electron filling when new bands form from completely empty s orbitals?
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The energy states are bound or __________ from the ionic core.
The energy states are bound or __________ from the ionic core.
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At what temperature is the Fermi energy typically referenced?
At what temperature is the Fermi energy typically referenced?
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The Fermi level is often set to zero on the energy scale.
The Fermi level is often set to zero on the energy scale.
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Electrons fill the orbitals from the __________ energy upwards.
Electrons fill the orbitals from the __________ energy upwards.
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Which of the following materials is classified as an insulator?
Which of the following materials is classified as an insulator?
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Silicon and germanium each have six valence electrons.
Silicon and germanium each have six valence electrons.
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What is the typical band gap for semiconductors?
What is the typical band gap for semiconductors?
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In a covalent compound, the bonding orbitals are found in the __________ band.
In a covalent compound, the bonding orbitals are found in the __________ band.
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Match the following materials with their classification:
Match the following materials with their classification:
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What happens when the energy difference between the antibonding and bonding orbitals is large?
What happens when the energy difference between the antibonding and bonding orbitals is large?
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In semiconductors, the probability of an electron hopping across the band gap increases with increasing band gap size.
In semiconductors, the probability of an electron hopping across the band gap increases with increasing band gap size.
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What defines the difference between a semiconductor and an insulator?
What defines the difference between a semiconductor and an insulator?
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Study Notes
Workshop Announcements
- Tutorial workshop yesterday's lecture, online worksheet due next Wednesday
- Online workshop sheets for chemistry workshops in two weeks
- Thermodynamics workshop in two weeks' time
Lecture 8: Solid State Chemistry
- Electronic structure of materials discussed: conductance and resistance
- Band theory for understanding solids introduced
- Linear combination of atomic orbitals for solids
- Distinction between conductors, semiconductors, and insulators
- X-ray anode discussed as a common X-ray source in labs and airports
- Synchrotron light sources explained: far more intense light, wider range of experiment
- Monochromatic light selection using diffraction methods in synchrotons
- Electronic properties of materials discussed
Electronic Properties
- Resistivity and conductivity are material properties.
- Specific Materials have differing levels of resistivity and conductivity.
- Resistivity and conductivity are directly related and the inversely proportional to each other
- Length and cross-sectional area of a wire affect its resistance
- Resistence is measured in Ohms, while conductance is measured in Siemens
- Increasing temperature reduces conductivity in conductors
- Increasing temperature increases conductivity in semiconductors
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Description
Test your understanding of the electronic structure of materials covered in Lecture 8 of Solid State Chemistry. This quiz includes topics such as band theory, conductors, semiconductors, and insulators, as well as the practical applications of X-ray sources and synchrotron light. Challenge yourself and see how well you know these crucial concepts!