Solid State Chemistry Lecture 8 Quiz
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Questions and Answers

What will be discussed in lecture eight of the solid state chemistry course?

  • Molecular bonding principles
  • X-ray diffraction techniques
  • Electronic properties of materials (correct)
  • Thermodynamics and its applications
  • Insulators have high conductance.

    False

    What is the most common type of X-ray source mentioned in the lecture?

    X-ray anode

    Electrons are accelerated towards the anode where they will hit a __________ material.

    <p>target</p> Signup and view all the answers

    Match the following materials with their electrical behavior:

    <p>Conductors = High conductivity Semiconductors = Intermediate conductivity Insulators = Low conductivity</p> Signup and view all the answers

    What theory will be introduced to understand the properties of solids?

    <p>Band Theory</p> Signup and view all the answers

    The workshop sheet will be available one week before the workshop.

    <p>True</p> Signup and view all the answers

    What does the linear combination of atomic orbitals help to extend into?

    <p>solids</p> Signup and view all the answers

    Which type of compounds typically have very high melting temperatures?

    <p>Ionic compounds</p> Signup and view all the answers

    The first nano scale industry was pigmenting stained glass windows using gold nanoparticles.

    <p>True</p> Signup and view all the answers

    What is the significance of optical properties in materials?

    <p>Optical properties relate to electronic properties and are essential for applications like pigmentation.</p> Signup and view all the answers

    In addition to being transparent, materials for photovoltaics must also be _____ to make efficient solar cells.

    <p>conducting</p> Signup and view all the answers

    Match the following types of materials with their properties:

    <p>Ionic compounds = High melting temperatures Metallic compounds = Wide range of melting temperatures Covalent compounds = Also high melting temperatures Gold nanoparticles = Used in pigmentation</p> Signup and view all the answers

    What type of light can synchrotron sources emit?

    <p>Monochromatic light</p> Signup and view all the answers

    What challenges are associated with creating materials that are both transparent and conducting?

    <p>Developing these materials is technically challenging.</p> Signup and view all the answers

    Synchrotron light sources operate by emitting light from atomic species only.

    <p>False</p> Signup and view all the answers

    Pigmentation has been a non-essential aspect of industries throughout history.

    <p>False</p> Signup and view all the answers

    What is the typical speed range of electrons used in synchrotron light sources?

    <p>99.999% the speed of light</p> Signup and view all the answers

    Why is transparency important for mobile phone screens?

    <p>To allow users to see the display clearly while protecting it from the environment.</p> Signup and view all the answers

    Synchrotron sources allow researchers to select the specific energy they want for their experiments by using ______.

    <p>monochromators</p> Signup and view all the answers

    Match the following materials with their characteristics:

    <p>Metallic compounds = Malleable Ionic compounds = Stiff and fragile Covalent materials = Very hard Van der Waals materials = Flaky components</p> Signup and view all the answers

    Which property is characteristic of covalent materials?

    <p>Stiffness</p> Signup and view all the answers

    What happens to the conductivity of semiconductors as temperature increases?

    <p>It increases.</p> Signup and view all the answers

    The use of diffraction materials is optional in synchrotron light sources for selecting energies.

    <p>False</p> Signup and view all the answers

    Conductors have higher conductivity than insulators even at low temperatures.

    <p>True</p> Signup and view all the answers

    Describe the effect of the speed of electrons in synchrotron light sources on the light produced.

    <p>It generates far more intense and brilliant light.</p> Signup and view all the answers

    What is the conductivity measure that indicates an insulator?

    <p>Less than ten to the minus four Siemens per metre.</p> Signup and view all the answers

    An insulator can be turned into a ________ by increasing the temperature.

    <p>semiconductor</p> Signup and view all the answers

    Match the following terms with their definitions:

    <p>Conductor = Material with high conductivity at any temperature Insulator = Material with very low conductivity Semiconductor = Material that can conduct electricity under certain conditions Temperature effect = In semiconductors, conductivity increases with temperature</p> Signup and view all the answers

    Which of the following statements is true about insulators?

    <p>Their conductivity is almost immeasurable under normal conditions.</p> Signup and view all the answers

    Applying a bias to a semiconductor results in no electron movement.

    <p>False</p> Signup and view all the answers

    What is the term used for the electronic bands in solid materials?

    <p>Band theory.</p> Signup and view all the answers

    What is the term for the maximum energy that an electron can have at zero Kelvin in a solid?

    <p>Fermi energy</p> Signup and view all the answers

    When bands are half-filled, they exhibit a higher density of states due to the spread over a larger energy range.

    <p>False</p> Signup and view all the answers

    What happens to the energy states and electron filling when new bands form from completely empty s orbitals?

    <p>The newly forming s band will also be completely empty.</p> Signup and view all the answers

    The energy states are bound or __________ from the ionic core.

    <p>unbound</p> Signup and view all the answers

    At what temperature is the Fermi energy typically referenced?

    <p>Absolute zero (0 Kelvin)</p> Signup and view all the answers

    The Fermi level is often set to zero on the energy scale.

    <p>True</p> Signup and view all the answers

    Electrons fill the orbitals from the __________ energy upwards.

    <p>lowest</p> Signup and view all the answers

    Which of the following materials is classified as an insulator?

    <p>Diamond</p> Signup and view all the answers

    Silicon and germanium each have six valence electrons.

    <p>False</p> Signup and view all the answers

    What is the typical band gap for semiconductors?

    <p>Under about 1 eV</p> Signup and view all the answers

    In a covalent compound, the bonding orbitals are found in the __________ band.

    <p>valence</p> Signup and view all the answers

    Match the following materials with their classification:

    <p>Diamond = Insulator Silicon = Semiconductor Tin = Conductive material Germanium = Semiconductor</p> Signup and view all the answers

    What happens when the energy difference between the antibonding and bonding orbitals is large?

    <p>They result in a larger band gap.</p> Signup and view all the answers

    In semiconductors, the probability of an electron hopping across the band gap increases with increasing band gap size.

    <p>False</p> Signup and view all the answers

    What defines the difference between a semiconductor and an insulator?

    <p>The size of the band gap.</p> Signup and view all the answers

    Study Notes

    Workshop Announcements

    • Tutorial workshop yesterday's lecture, online worksheet due next Wednesday
    • Online workshop sheets for chemistry workshops in two weeks
    • Thermodynamics workshop in two weeks' time

    Lecture 8: Solid State Chemistry

    • Electronic structure of materials discussed: conductance and resistance
    • Band theory for understanding solids introduced
    • Linear combination of atomic orbitals for solids
    • Distinction between conductors, semiconductors, and insulators
    • X-ray anode discussed as a common X-ray source in labs and airports
    • Synchrotron light sources explained: far more intense light, wider range of experiment
    • Monochromatic light selection using diffraction methods in synchrotons
    • Electronic properties of materials discussed

    Electronic Properties

    • Resistivity and conductivity are material properties.
    • Specific Materials have differing levels of resistivity and conductivity.
    • Resistivity and conductivity are directly related and the inversely proportional to each other
    • Length and cross-sectional area of a wire affect its resistance
    • Resistence is measured in Ohms, while conductance is measured in Siemens
    • Increasing temperature reduces conductivity in conductors
    • Increasing temperature increases conductivity in semiconductors

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    Description

    Test your understanding of the electronic structure of materials covered in Lecture 8 of Solid State Chemistry. This quiz includes topics such as band theory, conductors, semiconductors, and insulators, as well as the practical applications of X-ray sources and synchrotron light. Challenge yourself and see how well you know these crucial concepts!

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