Soil Chemical Properties and pH
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Questions and Answers

What is active acidity in soil pH an indicator of?

Current soil conditions.

What is the role of reserve acidity in maintaining soil pH?

Reserve acidity releases hydrogen ions into the soil solution.

Name three major soil cations.

Calcium ($Ca^{2+}$), magnesium ($Mg^{2+}$), and potassium ($K^{+}$).

Define base saturation in the context of soil chemistry.

<p>The proportion of cation exchange sites occupied by base cations.</p> Signup and view all the answers

How is the percentage of base saturation calculated?

<p>Percent base saturation = [(K+ + Ca2+ + Mg2+ + Na+)/CEC] x 100.</p> Signup and view all the answers

What does a high soil sodium adsorption ratio (SAR) indicate?

<p>A high proportion of sodium relative to calcium and magnesium.</p> Signup and view all the answers

Describe one way soil organic matter contributes to soil fertility.

<p>Releases plant-available nutrients over time.</p> Signup and view all the answers

What is the formula for calculating exchangeable sodium percentage (ESP)?

<p>ESP = (exchangeable sodium/CEC) x 100.</p> Signup and view all the answers

Define soil pH and explain its significance in soil chemistry and nutrient reaction.

<p>Soil pH is the measure of acidity or alkalinity in soil, determined by the concentration of hydrogen (H+) and hydroxide (OH-) ions. It affects nutrient availability and reactions, influencing plant health.</p> Signup and view all the answers

What pH range is generally considered ideal for most plants, and why?

<p>A pH range between 5.5 and 6.5. This range allows for an optimal balance of major nutrients and trace elements available for plant uptake.</p> Signup and view all the answers

Describe what happens to aluminum (Al) at a soil pH below 4.8, and how does this affect plants?

<p>Below pH 4.8, aluminum can become toxic to plants. It can also combine with phosphorus, making phosphorus less available to plants.</p> Signup and view all the answers

Explain the impact of low pH on essential plant nutrients.

<p>At a low pH, elements like iron, aluminum, and manganese can become toxic to plants, while other nutrients become less available.</p> Signup and view all the answers

How does soil pH influence the availability of molybdenum (Mo)?

<p>Molybdenum is less available to plants at a low (acidic) pH.</p> Signup and view all the answers

Explain the difference between soil properties and soil processes.

<p>Soil properties are features of the soil like texture, depth, or organic matter. Soil processes are actions or reactions within the soil, like water percolation or organic matter breakdown.</p> Signup and view all the answers

How is soil pH measured, and what do the numbers on the pH scale indicate about the soil's acidity or alkalinity?

<p>Soil pH is measured by determining the concentration of hydrogen (H+) and hydroxyl (OH-) ions in the soil. A pH less than 7 is acidic, 7 is neutral, and greater than 7 is alkaline.</p> Signup and view all the answers

What is the significance of knowing soil chemical properties?

<p>Soil chemical properties reflect the influence between soil solution and exchange sites, impacting plant health, nutritional requirements, and the bioavailability of soil contaminants.</p> Signup and view all the answers

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Flashcards

Soil Chemical Properties

Properties that affect nutrient availability and plant health in soil.

Soil pH

A measure of soil acidity or alkalinity, ranging from 0 to 14.

Ideal pH range for plants

A pH range between 5.5 to 6.5 is optimal for most plants.

Acid soils and productivity

Soil pH below 5 negatively impacts plant growth and nutrient uptake.

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pH 6.5 implications

Close to neutral, optimal for acid-sensitive plants; some trace elements may be insufficient.

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Toxicity at low pH

At pH below 5, aluminum and manganese can become toxic to plants.

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Nutrient availability at low pH

At low pH, many nutrients are less available, while some become toxic.

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Soil bacterial activity

Soil pH influences microbial activity; it slows down at lower pH levels.

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High pH Effects

At high pH, calcium binds phosphorus, making it unavailable to plants.

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Buffer pH

Soil pH indicating current acidity due to hydrogen ions (H+).

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Reserve Acidity

Hydrogen ions in soil that can be released to neutralize acidity.

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Cation Exchange Capacity (CEC)

Measure of a soil’s ability to hold positively charged nutrients (cations).

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Base Saturation

Proportion of cation exchange sites occupied by base cations like K+, Ca2+, Mg2+, and Na+.

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Soil Sodium Adsorption Ratio (SAR)

Proportion of sodium (Na+) relative to calcium (Ca2+) and magnesium (Mg2+).

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Soil Organic Matter

Measurement of plant and animal residues in soil that benefits fertility.

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Exchangeable Sodium Percentage (ESP)

Percentage of soil exchange sites occupied by sodium (Na+) compared to CEC.

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Study Notes

Soil Chemical Properties

  • Soil properties are characteristics like texture, depth, and organic matter content.
  • Soil processes are a series of actions that result in changes in the soil, for example, water percolating into the soil affects water content and organic matter breakdown impacts microbial populations.
  • Soil chemical properties reflect the interaction between soil solution (water and nutrients), exchange sites (clay and organic matter), plant health, nutritional needs, and the presence of contaminants; all affecting uptake by plants.

Soil pH

  • Soil pH is a fundamental aspect of soil chemistry, the first factor considered when assessing soil quality.
  • Soil pH measures soil acidity or alkalinity.
  • It's a measure of hydrogen (H+) and hydroxyl (OH-) ion concentration.
  • The pH scale ranges from 0 to 14.
  • A neutral pH is 7, acidic pH is less than 7, and alkaline pH is greater than 7.
  • A neutral pH has equal hydrogen and hydroxide concentrations.

Soil pH Levels

  • A pH range between 5.5 and 6.5 is often ideal for most plants.
  • Soil pH significantly affects plant productivity when below 5.
  • pH 6.5 – close to neutral: Optimum for many acid-sensitive plants.
  • pH 5.5 – slightly acidic: Balance of major nutrients and trace elements available.
  • pH 5.0 – moderately acidic: Aluminium (Al) can become toxic to plants, depending on the soil type, affecting phosphorus availability.
  • pH 4.5 – strongly acidic: Aluminium and manganese become toxic to plants at higher concentrations, decreasing molybdenum and soil bacterial activity.

Influence of pH on Nutrient Availability

  • Soil pH affects both nutrient availability and nutrient interactions.
  • Low pH can reduce availability of some elements, while others become toxic to plants (e.g., iron, aluminium, and manganese).
  • Phosphorus is often less available in acidic soils due to bonding with aluminum.
  • High pH can also affect availability of specific nutrients and can make others toxic (e.g., boron, molybdenum).
  • pH levels influence the solubility of certain nutrients, affecting plant uptake.

Buffer pH

  • Buffer pH, sometimes called lime index, measures the concentration of hydrogen ions in the soil solution, indicating current soil conditions (active acidity).
  • Reserve soil acidity exists to replenish hydrogen ions after neutralization by lime.

Cation Exchange Capacity (CEC)

  • CEC is a measure of a soil's ability to hold positively charged nutrients (cations).
  • Major soil cations include calcium (Ca2+), magnesium (Mg2+), potassium (K+), sodium (Na+), hydrogen (H+), ammonium (NH4+), and aluminum (Al3+).
  • CEC is measured in centimoles of positive charge per kilogram of soil (cmol/kg) or milliequivalents per 100 grams of soil (meq/100g).

Base Saturation

  • Base saturation is the proportion of cation exchange sites occupied by various base cations (potassium, calcium, magnesium, and sodium).
  • Soil sodium adsorption ratio (SAR) expresses the proportion of sodium relative to calcium and magnesium, calculated from soil test data.
  • Soil pH is directly related to base saturation; as saturation increases, pH rises.

Soil Organic Matter

  • Soil organic matter is the measure of plant and animal residue.
  • It's a vital component of soil fertility; organic matter acts as a nutrient bank releasing nutrients over an extended period.
  • Soil organic matter provides both macronutrients (nitrogen, phosphorus) and micronutrients (iron, copper, zinc) to the soil and plants.

Exchangeable Sodium Percentage (ESP)

  • ESP measures the percentage of soil exchange sites occupied by sodium (Na+).
  • ESP is calculated by dividing the concentration of sodium cations by the total cation exchange capacity.
  • ESP is expressed in milliequivalents per 100 grams of soil (meq/100 g).

Macronutrients

  • Macronutrients include nitrogen (N), phosphorus (P), potassium (K), sulphur (S), calcium (Ca), and magnesium (Mg), vital for plant growth.
  • Nitrogen, phosphorus, and potassium are “primary” macronutrients required in greater quantities than sulphur, calcium and magnesium.

Micronutrients

  • Micronutrients, including iron (Fe), manganese (Mn), copper (Cu), boron (B), zinc (Zn), nickel (Ni), chlorine (Cl), and molybdenum (Mo) are essential in small quantities.
  • Soil pH directly affects availability; high pH makes manganese and zinc inaccessible, while low pH can lead to boron and zinc shortages.

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Description

This quiz explores the chemical properties of soil, focusing on characteristics like texture, depth, and organic matter content. It also delves into the importance of soil pH as a measure of soil acidity or alkalinity, essential for assessing soil quality. Understanding these aspects is crucial for enhancing plant health and productivity.

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