Single Displacement Reactions

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Questions and Answers

Which of the following best describes a single displacement reaction?

  • A reaction where a compound breaks down into its elements.
  • A reaction where an element switches places with another element in a compound. (correct)
  • A reaction where two elements combine to form a compound.
  • A reaction where ions in two compounds exchange places.

What type of ions are involved in cation replacement reactions?

  • Positively charged ions (correct)
  • Both positively and negatively charged ions
  • Neutral ions
  • Negatively charged ions

In a single displacement reaction between iron and copper sulfate, what happens to the iron?

  • It displaces copper from the solution. (correct)
  • It remains unchanged.
  • It forms a new compound with sulfate.
  • It dissolves completely.

Which of the following statements is correct regarding the reactivity series of metals?

<p>Metals higher in the series can displace metals lower in the series. (C)</p> Signup and view all the answers

What is the key difference between a cation replacement reaction and an anion replacement reaction?

<p>Cation replacement involves positively charged ions, while anion replacement involves negatively charged ions. (A)</p> Signup and view all the answers

In the halogen activity series (F > Cl > Br > I), which halogen can displace bromine from a solution of sodium bromide?

<p>Fluorine (D)</p> Signup and view all the answers

Which of the following metals will NOT react with dilute hydrochloric acid (HCl) to produce hydrogen gas?

<p>Copper (D)</p> Signup and view all the answers

Why is it important to clean the iron nails with sandpaper before immersing them in copper sulphate solution in the experiment?

<p>To remove any oxide layer that may inhibit the reaction. (A)</p> Signup and view all the answers

If a piece of silver metal is placed in a solution of zinc nitrate, what would you expect to observe?

<p>No reaction will occur. (B)</p> Signup and view all the answers

Which of the following is an example of an anion displacement reaction?

<p>$Cl_2(g) + 2NaBr(aq) \rightarrow 2NaCl(aq) + Br_2(g)$ (C)</p> Signup and view all the answers

In the experimental setup with iron nails and copper sulfate solution, what visual evidence suggests that a single displacement reaction has occurred?

<p>The iron nail becomes coated with a reddish-brown solid. (D)</p> Signup and view all the answers

What is the purpose of keeping one iron nail in a Petri dish during the experiment with copper sulphate solution?

<p>To serve as a control for comparison. (C)</p> Signup and view all the answers

A student observes that when a zinc strip is placed in a lead(II) nitrate solution, lead metal precipitates out. What can be concluded from this observation?

<p>Zinc is more reactive than lead. (D)</p> Signup and view all the answers

Consider the reaction: $2AgNO_3(aq) + Cu(s) \rightarrow Cu(NO_3)_2(aq) + 2Ag(s)$. What type of reaction is this, and what does it indicate about the relative reactivity of copper and silver?

<p>Single displacement; copper is more reactive than silver. (C)</p> Signup and view all the answers

Which of the following is NOT a typical characteristic of single displacement reactions?

<p>No change is observed (D)</p> Signup and view all the answers

What outcome would one expect if a less reactive metal is introduced to a salt solution containing a more reactive metal?

<p>There no reaction will occur. (A)</p> Signup and view all the answers

You have a solution of $NiCl_2(aq)$ and a piece of solid zinc, $Zn(s)$. Will a single displacement reaction occur? If so, what will the products be?

<p>$ZnCl_2(aq) + Ni(s)$ (D)</p> Signup and view all the answers

Which of the following is the correct procedure for setting up the experiment with iron nails and copper sulphate to observe single displacement?

<p>Soak the iron nail in the copper sulfate solution and then compare it to another iron nail that has <em>not</em> been soaked in the solution. (A)</p> Signup and view all the answers

Given two unknown metals, X and Y, how could you experimentally determine their relative reactivity using single displacement reactions?

<p>Place metal X in a solution of Y's ions and metal Y in a solution of X's ions. Observe any reactions. (B)</p> Signup and view all the answers

A student performs a single displacement reaction using two unknown metals, A and B, and their respective nitrate solutions, $A(NO_3)_2(aq)$ and $B(NO_3)_2(aq)$. The student records their observations in the table below:

Experiment Reactants Observations
1 Metal A + $B(NO_3)_2(aq)$ No reaction
2 Metal B + $A(NO_3)_2(aq)$ Metal A deposits on Metal B

Based on these observations, which of the following statements is most accurate?

<p>Metal B is more reactive than Metal A, as it forms a deposit. (D)</p> Signup and view all the answers

Which of the following provides the most accurate explanation for why a metal's position in the electrochemical series dictates its ability to displace other metals?

<p>Metals higher in the series have a greater tendency to lose electrons and form positive ions. (B)</p> Signup and view all the answers

In an experiment to study single displacement reactions, a student mixes zinc metal with hydrochloric acid and observes the evolution of a gas. The student collects the gas and tests it with a burning splint. The splint 'pops'. Which of the following statements is the BEST interpretation of this observation?

<p>The splint's 'popping' sound indicates that the gas produced is hydrogen, which is flammable. (D)</p> Signup and view all the answers

Consider the following single displacement reaction: $A + BX \rightarrow AX + B$. Under what conditions would _no_ reaction occur?

<p>When A is a metal and BX is a metal salt, and B is higher than A in the reactivity series. (A)</p> Signup and view all the answers

A student mixes aluminum metal with copper(II) chloride in an aqueous solution, aiming to perform a single displacement reaction. The balanced reaction is: $2Al(s) + 3CuCl_2(aq) \rightarrow 2AlCl_3(aq) + 3Cu(s)$. After some time, the student observes the formation of a reddish-brown solid and notices that the solution is changing color. Which of the following statements is the MOST reasonable inference based exclusively on principles from the single displacement reaction?

<p>The reddish-brown solid is primarily Copper metal that has been displaced, and the solution's changing color may be due to the resulting Aluminum Chloride in the solution. (A)</p> Signup and view all the answers

A scientist performs the reaction of Iron (Fe) and Hydrochloric Acid (HCl). She notices a gas is produced. When she performs the same reaction with Gold (Au) and Hydrochloric Acid, no gas is produced. What can you conclude about the relative reactivity of these two metals?

<p>Iron is more reactive with Hydrochloric Acid than Gold. (C)</p> Signup and view all the answers

Aqueous solutions of Silver Nitrate ($AgNO_3$), Copper(II) Sulfate ($CuSO_4$), and Zinc Chloride ($ZnCl_2$) are prepared. A piece of Nickel metal is dipped into each of the solutions. In which solution(s) would you expect Nickel to displace the metal ion?

<p>$AgNO_3$ and $CuSO_4$ only (D)</p> Signup and view all the answers

What is the purpose of the strand that connects the iron nail to the retort stand in the illustrated experiment?

<p>To suspend iron nail, allowing full contact with Copper Sulphate. (C)</p> Signup and view all the answers

How does understanding single displacement reactions help in industrial processes such as metal extraction?

<p>It allows for the selective extraction of metals from their ores by using a more reactive metal as a reducing agent. (A)</p> Signup and view all the answers

Balance the following reaction: $Al(s) + H_2SO_4(aq) \rightarrow Al_2(SO_4)_3(aq) + H_2(g)$. What is the coefficient for $H_2SO_4$ in the balanced equation?

<p>3 (C)</p> Signup and view all the answers

Which of the following is the most direct evidence of a chemical reaction, rather than a physical change, occurring during a single displacement reaction?

<p>The formation of a gas or a precipitate. (D)</p> Signup and view all the answers

How could you differentiate between a single displacement reaction and a double displacement reaction?

<p>Single displacement reactions involve one element replacing another in a compound, while double displacement reactions involve an exchange of ions between two compounds. (D)</p> Signup and view all the answers

In the context of the experiment with iron nails and copper sulphate, what would happen if the copper sulphate solution was replaced with iron(II) sulphate solution?

<p>No reaction would occur. (D)</p> Signup and view all the answers

A student accidentally uses a copper nail instead of an iron nail in the single displacement experiment. Considering copper's position in the reactivity series, what observation would the student likely make?

<p>No visible change would occur. (C)</p> Signup and view all the answers

Why are non-metals also able to participate in single displacement reactions?

<p>Non-metals can gain electrons to form anions, which can displace other anions. (A)</p> Signup and view all the answers

Consider the following scenario: A chemist adds chlorine gas ($Cl_2$) to a solution containing both bromide ($Br^$) and iodide ($I^$) ions. What would be the expected outcome based on the halogen activity series?

<p>Chlorine would displace both bromide and iodide ions. (B)</p> Signup and view all the answers

Given the following two half-reactions and their standard reduction potentials:

$Cu^{2+}(aq) + 2e^- \rightarrow Cu(s) \quad E^o = +0.34 V$ $Ag^{+}(aq) + e^- \rightarrow Ag(s) \quad E^o = +0.80 V$

What will happen if solid copper is added to a silver nitrate ($AgNO_3$) solution, and why?

<p>Copper will displace silver because Cu2+ has a lower reduction potential. (A)</p> Signup and view all the answers

A scientist tests single displacement reactions with hypothetical elements X, Y, and Z. They find that X displaces Y from its salt, but Z does not displace either X or Y from their salts. Arrange the elements in order of decreasing reactivity.

<p>X &gt; Y &gt; Z (B)</p> Signup and view all the answers

Consider a scenario using the single-displacement of silver by placing copper into silver nitrate solution ($Cu(s) + 2AgNO_3(aq) \rightarrow Cu(NO_3)_2(aq) + 2Ag(s)$).

If you start with 10.0 grams of copper, what mass of silver is produced?

<p>Approximately 34.06 grams of silver (B)</p> Signup and view all the answers

Which of the following is a reason single displacement reactions wouldn't occur?

<p>The less reactive metal cannot pull the electrons towards itself, preventing the more reactive metal to bond successfully. (B)</p> Signup and view all the answers

What type of chemical reaction is represented by a more reactive element displacing a less reactive element from its compound?

<p>Single displacement reaction (B)</p> Signup and view all the answers

What is the correct order of halogen reactivity, from most reactive to least reactive?

<p>F &gt; Cl &gt; Br &gt; I (C)</p> Signup and view all the answers

In the context of single displacement reactions, what is the role of the electrochemical series?

<p>To determine the relative reactivity of metals (D)</p> Signup and view all the answers

During a single displacement reaction, what observation would indicate that copper is being displaced from a copper sulfate solution?

<p>A reddish-brown solid forms (B)</p> Signup and view all the answers

Why is it important to rub the iron nails with sandpaper before using them in the copper sulfate experiment?

<p>To remove any coating of oxides or impurities from the surface, allowing the reaction to occur effectively (A)</p> Signup and view all the answers

In a single displacement reaction, what type of ion is replaced in a cation replacement reaction?

<p>Cation (D)</p> Signup and view all the answers

Which of the following is a characteristic of metals that can displace other metals from salt solutions?

<p>Greater reactivity (B)</p> Signup and view all the answers

In the reaction between zinc and dilute sulfuric acid, what gas is produced?

<p>Hydrogen (B)</p> Signup and view all the answers

What is the expected outcome if a small amount of silver metal is placed in a solution of copper(II) sulfate?

<p>No reaction will occur (D)</p> Signup and view all the answers

Why is the single displacement reaction $Zn + H_2SO_4 \rightarrow ZnSO_4 + H_2$ commonly used in laboratories?

<p>To generate hydrogen gas for experiments (A)</p> Signup and view all the answers

In the copper sulfate and iron nail experiment, what is the purpose of leaving one iron nail in a Petri dish?

<p>To serve as a control for comparison (D)</p> Signup and view all the answers

Which metal, when placed in hydrochloric acid (HCl), would likely produce hydrogen gas, and why?

<p>Magnesium, because it is more reactive than hydrogen (C)</p> Signup and view all the answers

In the reaction $Cl_2(g) + 2NaBr(aq) \rightarrow 2NaCl(aq) + Br_2(g)$, what is happening to the bromide ions ($Br^-$)?

<p>They are being oxidized to bromine gas (C)</p> Signup and view all the answers

Which of the following is a suitable method to increase the rate of displacement of copper ions from copper sulphate solution?

<p>Use powdered iron instead of iron nails (D)</p> Signup and view all the answers

How does the concentration of the copper sulfate solution affect the rate of reaction in the single displacement experiment with iron nails?

<p>Higher concentration increases the reaction rate. (B)</p> Signup and view all the answers

A student places a piece of zinc metal into a solution of $Mg(NO_3)_2(aq)$. What will likely happen?

<p>No reaction occurs because magnesium is more reactive than zinc. (B)</p> Signup and view all the answers

In a single displacement reaction involving halogens, which of the following statements is correct about their reactivity?

<p>The ability of a halogen to displace another halogen decreases as you move down the group in the periodic table. (A)</p> Signup and view all the answers

Consider the reaction: $2AgNO_3(aq) + Cu(s) \rightarrow Cu(NO_3)_2(aq) + 2Ag(s)$. Which statement accurately describes the roles of copper and silver in this reaction?

<p>Copper is oxidized, and silver is reduced. (D)</p> Signup and view all the answers

How can you determine the relative reactivity of two unknown metals, X and Y, using single displacement reactions?

<p>By observing which metal can displace the other from its salt solution. (D)</p> Signup and view all the answers

If you place a piece of lead metal into a solution of $ZnCl_2$, will a single displacement reaction occur? Choose the correct explanation.

<p>No, zinc is more reactive than lead, so no reaction will occur (D)</p> Signup and view all the answers

What is the role of a metal's position in the electrochemical series, in the context of single displacement reactions?

<p>It reflects its capacity to displace other metals from their salt solutions (D)</p> Signup and view all the answers

Consider the displacement reaction between $Mg(s)$ and $CuSO_4(aq)$. What would be observed?

<p>The magnesium strip dissolves, and the solution turns from blue to colorless as copper deposits on the magnesium. (D)</p> Signup and view all the answers

Why can non-metals also participate in single displacement reactions?

<p>Non-metals can also form ions and have varying degrees of reactivity, similar to metals (C)</p> Signup and view all the answers

Which of the following is the most accurate description of a single displacement reaction's practical application in metal extraction?

<p>Using a more reactive metal to extract a less reactive metal from its ore (B)</p> Signup and view all the answers

Consider the reaction between Iron (Fe) and Hydrochloric Acid (HCl). Only Iron(II) Chloride ($FeCl_2$) can practically form, not Iron(III) Chloride ($FeCl_3$). What does the observation of gas production alongside the formation of Iron(II) Chloride suggest?

<p>Iron (Fe) is more reactive than Hydrogen (H) and can displace it, forming Hydrogen gas (A)</p> Signup and view all the answers

Consider a scenario where zinc is placed into Iron(II) sulfate. What visual evidence (if any) would indicate that a single displacement reaction occurred?

<p>Gradual fading of green solution with deposition of metallic iron (A)</p> Signup and view all the answers

A student combines $Ni(s)$ with Silver Nitrate ($AgNO_3$). What happens?

<p>Silver coats the Nickel (D)</p> Signup and view all the answers

A student mixes aluminum metal with copper(II) chloride in an aqueous solution, aiming to perform a single displacement reaction. The balanced reaction is: $2Al(s) + 3CuCl_2(aq) \rightarrow 2AlCl_3(aq) + 3Cu(s)$. What type of ion do you predict Aluminum to form?

<p>Aluminum forms a positive ion (A)</p> Signup and view all the answers

Consider the single-displacement of silver by placing copper into silver nitrate solution ($Cu(s) + 2AgNO_3(aq) \rightarrow Cu(NO_3)_2(aq) + 2Ag(s)$). You start with 10.0 grams of copper and have excess Silver Nitrate. What is the limiting reactant?

<p>Copper ($Cu$) (C)</p> Signup and view all the answers

The student accidentally uses a copper nail instead of an iron nail in the single displacement experiment. Noting that the student uses Ferrous Sulfate ($FeSO_4$) solution, what observation would the student likely make?

<p>Nothing. There is no reaction. (B)</p> Signup and view all the answers

In the single displacement reaction between Iron (Fe) and Copper(II) Sulfate ($CuSO_4$), which of the following changes would likely slow down the reaction?

<p>Not cleaning the Iron nail (C)</p> Signup and view all the answers

An experiment attempts to react Zinc and an acid, but no hydrogen gas is formed. Suggest a reason why.

<p>An alternative reaction is occurring (A)</p> Signup and view all the answers

Consider the single-displacement of silver by placing copper into silver nitrate solution ($Cu(s) + 2AgNO_3(aq) \rightarrow Cu(NO_3)_2(aq) + 2Ag(s)$). You start with 10.0 grams of copper. What mass of silver is produced?

<p>33.96 grams (C)</p> Signup and view all the answers

Let's say we performed the experiment on the International Space Station, in zero gravity. How would that affect the single replacement of Iron and Copper(II) Sulfate?

<p>There is lower contact with Iron and Copper(II) Sulfate, thus leading to lower reaction rates (D)</p> Signup and view all the answers

Flashcards

Displacement Reaction

A chemical reaction where a more reactive element replaces a less reactive one in a compound.

Reactivity Series

The arrangement of metals in order of their relative reactivity, determining which can displace others.

Cation Replacement

A reaction where one cation (positive ion) replaces another in a solution.

Anion Replacement

A reaction where one anion (negative ion) replaces another in a solution.

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Metal Displacement Rule

A metal higher in the reactivity series can replace a metal lower in the series from its aqueous salt solution.

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Displacement Reaction Rule

Elements that form cations can only displace cations, and elements that form anions can only displace anions.

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Iron and Copper Sulfate Reaction

Iron reacts with copper sulfate solution to form ferrous sulfate and copper.

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Halogens

Elements such as fluorine, chlorine, bromine and iodine.

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Iron nails Experiment

A reaction where iron nails are placed in copper sulphate solution.

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Activity Series and Displacement

Metals that are higher in the reactivity series can displace the metal that is lower in an aqueous solution.

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Halogen Activity Series

Arranges halogens in order of reactivity.

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Cation Definition

A positively charged ion or metal.

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Anion Definition

A negatively charged ion or non-metal.

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Metal + Dilute Acid

Reaction of metal with dilute acid produces metal salt and hydrogen gas

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Study Notes

  • Single displacement reactions involve a more reactive element displacing a less reactive one from its compound.
  • Students should gain an understanding of single displacement and cationic displacement reactions
  • Students will classify metals by their ability to displace others in salt solutions to demonstrate single displacement reactions with iron nails and copper sulfate, and distinguish them from other reactions.

Displacement Reactions

  • Metals and non-metals can participate in displacement reactions.
  • Iron nails reacting with copper sulfate solution exemplifies a displacement reaction.

Reactivity Series

  • Chemical reactivity is related to an element's position in the electrochemical series.
  • Metals that are higher in the activity series can displace metals lower in the series from aqueous salt solutions.
  • Non-metals, like halogens, also undergo displacement reactions, for example the activity series for halogens is: F > Cl > Br > I.
  • Elements forming cations can only displace cations, while elements forming anions can only displace anions.

Cation Replacement Reactions

  • In cation replacement, a cation is replaced by another from its solution, this type of reaction commonly involves metal displacement.
  • Magnesium displacing copper from copper sulfate solution is a notable example; the blue copper sulphate solution turns brown as the displaced cooper is deposited, the equation for this reaction is: Mg(s) + CuSO4(aq) → MgSO4(aq) + Cu(s).
  • Metals positioned above hydrogen in the reactivity series can displace hydrogen from dilute acids.
  • Potassium, sodium, and lithium react vigorously with dilute acids, forming metal salts and hydrogen gases.
  • Metals such as aluminum, zinc, magnesium, and iron react safely with dilute acids.
  • Zinc reacts with dilute sulfuric acid to produce hydrogen gas: Zn(s) + H2SO4(aq) → ZnSO4(aq) + H2(g).

Anion Replacement Reactions

  • Anion replacement involves one anion replacing another from its solution and typically features more reactive halogens displacing less reactive ones.
  • Chlorine displaces bromine from a sodium bromide solution, the equation for this is: Cl2(g) + 2NaBr(aq) → 2NaCl(aq) + Br2(g).
  • Bromine replaces iodine from potassium iodide solution, the equation for which is: Br2(g) + 2KI(aq) → 2KBr(aq) + I2(aq)
  • If a less reactive metal is added to a salt solution of a more reactive metal, no reaction occurs.

Materials Needed for Demonstration

  • The following materials are needed to demonstrate single displacement reactions; iron nails, sand paper, test tubes, copper sulphate solution, thread

Procedure

  • To perform the reaction:
    • Clean two iron nails with sandpaper until they appear grayish.
    • Place copper sulphate solution in two test tubes and clamp the test tubes to different stands.
    • Suspend one nail in one of the test tubes, keeping the other in a Petri dish for comparison.
    • Observe for 15 minutes ensuring the test tubes are undisturbed
    • Remove the immersed nail and place it in the Petri dish for comparison.

Experiment Guide Questions

  • What is the objective of this experiment involving iron nails and copper sulphate solution?
  • What chemical reaction is expected to occur during the experiment?
  • How does the appearance of the iron nails change after they are cleaned?
  • Describe the preparation of the copper sulphate solution for use in the experiment.
  • What concentration of copper sulphate solution is used, and why?
  • Explain the setup of the experimental apparatus involving test tubes, stands, and iron nails.
  • Why are the iron nails placed differently in the test tubes and Petri dish?
  • What changes, if any, are expected to occur during this observation period?
  • How does suspending the iron nail facilitate the observation of the reaction?
  • Why is another iron nail kept in the Petri dish for comparison after the experiment?
  • What differences are expected between the treated and untreated iron nails?
  • Describe the observations made during and after the experiment.
  • What evidence suggests that a chemical reaction has occurred between the iron nail and copper sulphate solution?
  • What is the significance of the changes observed in the iron nail and copper sulphate solution?
  • How do these observations align with the principles of single displacement reactions?

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